Tufa

Short description: Porous limestone rock formed when carbonate minerals precipitate out of ambient temperature water

Tufa columns at Mono Lake, California

Tufa is a variety of limestone formed when carbonate minerals precipitate out of ambient temperature water. Geothermally heated hot springs sometimes produce similar (but less porous) carbonate deposits, which are known as travertine. Tufa is sometimes referred to as (meteogene) travertine.[1] It should not be confused with hot spring (thermogene) travertine. Tufa, which is calcareous, should not be confused with tuff, a porous volcanic rock with a similar etymology that is sometimes also called "tufa".

## Contents

* 1 Classification and features
* 1.1 Fluvial deposits
* 1.2 Lacustrine deposits
* 1.3 Other deposits
* 1.3.1 Calcareous sinter
* 1.3.2 Speleothems
* 1.3.3 Tufa columns
* 2 Biology
* 3 Geochemistry
* 4 Occurrence
* 5 Uses
* 6 See also
* 7 References
* 8 External links

## Classification and features

Modern and fossil tufa deposits abound with wetland plants;[2] as such, many tufa deposits are characterised by their large macrobiological component, and are highly porous. Tufa forms either in fluvial channels or in lacustrine environments. Ford and Pedley (1996)[3] provide a review of tufa systems worldwide.

Barrage Tufa at Cwm Nash, South Wales

### Fluvial deposits

Deposits can be classified by their depositional environment (or otherwise by vegetation or petrographically). Pedley (1990)[4] provides an extensive classification system, which includes the following classes of fluvial tufa:

* Spring – Deposits form on emergence from a spring/seep. Morphology can vary from mineratrophic wetlands to spring aprons (see calcareous sinter)
* Braided channel – Deposits form within a fluvial channel, dominated by oncoids (see oncolite)
* Cascade – Deposits form at waterfalls, deposition is focused here due to accelerated flow (see Geochemistry)
* Barrage – Deposits form as a series of phytoherm barrages across a channel, which may grow up to several metres in height. Barrages often contain a significant detrital component, composed of organic material (leaf litter, branches etc.).

Rubaksa tufa plug, after drying of the river, in Ethiopia

### Lacustrine deposits

Lacustrine tufas are generally formed at the periphery of lakes and built-up phytoherms (freshwater reefs), and on stromatolites. Oncoids are also common in these environments.

### Other deposits

While fluvial and lacustrine systems make up the bulk of tufa systems worldwide, there are several other important tufa environments.

#### Calcareous sinter

Although sometimes regarded as a distinct carbonate deposit, calcareous sinter formed from ambient temperature water can be considered a sub-type of tufa.

#### Speleothems

Calcareous speleothems may be regarded as a form of calcareous sinter. They lack any significant macrophyte component due to the absence of light, and for this reason they are often morphologically closer to travertine or calcareous sinter.

Tufa at Trona Pinnacles, California

#### Tufa columns

Tufa columns are an unusual form of tufa typically associated with saline lakes. They are distinct from most tufa deposits in that they lack any significant macrophyte component, due to the salinity excluding mesophilic organisms.[3] Some tufa columns may actually form from hot-springs, and may therefore constitute a form of travertine. It is generally thought that such features form from CaCO3 precipitated when carbonate rich source waters emerge into alkaline soda lakes. They have also been found in marine settings in the Ikka fjord of Greenland where the Ikaite columns can reach up to 18 m (59 ft) in height.[5]

## Biology

Tufa deposits form an important habitat for a diverse flora. Bryophytes (mosses, liverworts etc.) and diatoms are well represented. The porosity of the deposits creates a wet habitat ideal for these plants.

The Pyramid and Domes tufa rock structures, Pyramid Lake, Nevada

## Geochemistry

Modern tufa is formed from alkaline waters, supersaturated with calcite. On emergence, waters degas CO2 due to the lower atmospheric pCO2 (see partial pressure), resulting in an increase in pH. Since carbonate solubility decreases with increased pH,[6] precipitation is induced. Supersaturation may be enhanced by factors leading to a reduction in pCO2, for example increased air-water interactions at waterfalls may be important,[7] as may photosynthesis.[8]

Recently it has been demonstrated that microbially induced precipitation may be more important than physico-chemical precipitation. Pedley et al. (2009)[9] showed with flume experiments that precipitation does not occur unless a biofilm is present, despite supersaturation.

Calcite is the dominant mineral precipitate found; however, the polymorph aragonite is also found.

Tufa dam in Chelekwot, Ethiopia

## Occurrence

Tufa is common in many parts of the world. Some notable deposits include:

* Pyramid Lake, Nevada, US – tufa formations
* Big Soda Lake, Nevada, US – tufa formations only a century old
* Mono Lake, California, US – tufa columns
* Trona Pinnacles, California, US – tufa columns
* Matlock Bath, Derbyshire, United Kingdom
* North Dock Tufa, United Kingdom
* Plitvice Lakes National Park, Croatia
* Basturs Lakes, Pallars Jussà, Catalonia - tufa mounds
* Various parts of Armenia, such as Artik
* The southwestern coastline of Western Australia
* Near Groot Marico in the North West Province, South Africa
* The Kadishi Tufa, Blyde River Canyon, Mpumalanga Province, South Africa

Some sources suggest that "tufa" was used as the primary building material for most of the châteaux of the Loire Valley, France. This results from a mis-translation of the terms "tuffeau jaune" and "tuffeau blanc", which are porous varieties of the Late Cretaceous marine limestone known as chalk.[10][need quotation to verify][11][failed verification]

## Uses

Tufa is today occasionally shaped into a planter. Its porous consistency makes tufa ideal for alpine gardens. A concrete mixture called hypertufa is used for similar purposes.

## See also

## References

1. ↑ Pentecost, A. (2005). Travertine. Dordrecht, Netherlands: Kluwer Academic Publishers Group. ISBN 1-4020-3523-3.
2. ↑ Koban, C.G.; Schweigert, G. (1993). "Microbial origin of travertine fabrics - two examples from Southern Germany (Pleistocene Stuttgart travertines and Miocene riedöschingen Travertine).". Facies 29: 251–263. doi:10.1007/BF02536931.
3. ↑ 3.0 3.1 Ford, T.D.; Pedley, H.M. (1996). "A review of tufa and travertine deposits of the world". Earth-Science Reviews 41 (3–4): 117–175. doi:10.1016/S0012-8252(96)00030-X. Bibcode: 1996ESRv...41..117F.
4. ↑ Pedley, H.M. (1990). "Classification and environmental models of cool freshwater tufas". Sedimentary Geology 68: 143–154. doi:10.1016/0037-0738(90)90124-C. Bibcode: 1990SedG...68..143P.
5. ↑ Buchardt, B.; Israelson, C.; Seaman, P.; Stockmann, G. (2001). "Ikaite tufa towers in ikka fjord, southwest Greenland: their formation by mixing of seawater and alkaline spring water". Journal of Sedimentary Research 71 (1): 176–189. doi:10.1306/042800710176. Bibcode: 2001JSedR..71..176B.
6. ↑ Bialkowski, S.E. 2004. "Use of Acid Distributions in Solubility Problems". Archived from the original on 2009-02-28. https://web.archive.org/web/20090228004440/http://www.chem.usu.edu/~sbialkow/Classes/3600/alpha/alpha3.html.
7. ↑ Zhang, D.; Zhang, Y; Zhu, A.; Cheng, X (2001). "Physical mechanisms of river waterfall tufa (travertine) formation". Journal of Sedimentary Research 71 (1): 205–216. doi:10.1306/061600710205. Bibcode: 2001JSedR..71..205Z.
8. ↑ Riding, R. (2000). "Microbial carbonates: the geological record of calcified bacterial-algal mats and biofilms". Sedimentology 47: 179–214. doi:10.1046/j.1365-3091.2000.00003.x.
9. ↑ Pedley, M.; Rogerson, M.; Middleton, R. (2009). "Freshwater calcite precipitates from in vitro mesocosm flume experiments: a case for biomediation of tufas". Sedimentology 56 (2): 511–527. doi:10.1111/j.1365-3091.2008.00983.x. Bibcode: 2009Sedim..56..511P.
10. ↑ Forster, A.; Forster, S.C. (1996). "Troglodyte dwellings of the Loire Valley, France". Quarterly Journal of Engineering Geology and Hydrogeology 29 (3): 193–197. doi:10.1144/GSL.QJEGH.1996.029.P3.01.
11. ↑ "Au Turonien" (in French). Une histoire de la Touraine à travers ses roches. http://dominique.millet2.free.fr/histouraine5.html. Retrieved 2010-10-01.

## External links

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