Bis(acetonitrile)palladium dichloride

Names
Other names

palladium dichloride bis(acetonitrile), bis(acetonitrile)dichloropalladium

Identifiers

CAS Number

* 14592-56-4 Y

3D model (JSmol)

* ionic form: Interactive image
* coordination form: Interactive image

ChemSpider |

* 76265

ECHA InfoCard | 100.035.110
EC Number |

* 238-637-3

PubChem CID

* 6093782

CompTox Dashboard (EPA)

* DTXSID80932719

InChI

* InChI=1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2

Key: RBYGDVHOECIAFC-UHFFFAOYSA-L

SMILES

* ionic form: CC#N.CC#N.Cl[Pd]Cl

* coordination form: Cl[Pd-2](Cl)([N+]#CC)[N+]#CC

Properties

Chemical formula

| C4H6Cl2N2Pd
Molar mass | 259.43 g·mol−1
Appearance  | yellow-brown
Melting point | 129–131 °C (264–268 °F; 402–404 K)
Hazards
GHS labelling:[1]

Pictograms

Signal word

| Danger

Hazard statements

| H301, H311, H330

Precautionary statements

| P260, P261, P264, P270, P271, P273, P280, P284, P301+P310, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P310, P311, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Chemical compound

Bis(acetonitrile)palladium dichloride is the coordination complex with the formula PdCl2(NCCH3)2. It is the adduct of two acetonitrile ligands with palladium(II) chloride. It is a yellow-brown solid that is soluble in organic solvents. The compound is a reagent and a catalyst for reactions that require soluble Pd(II).[1] The compound is similar to bis(benzonitrile)palladium dichloride. It reacts with 1,5-cyclooctadiene to give dichloro(1,5-cyclooctadiene)palladium.

## References

[edit]

1. ^ Carretero, Juan Carlos; Arrayas, Ramon Gomez (2008). "Dichloro bis(acetonitrile) palladium". e-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn00908. ISBN 978-0471936237.

This catalysis article is a stub. You can help Wikipedia by expanding it.

|

* v
* t
* e

*[CID]: Compound ID
*[EPA]: U.S. Environmental Protection Agency
*[H301]: H301: Toxic if swallowed
*[H311]: H311: Toxic in contact with skin
*[H330]: H330: Fatal if inhaled
*[P260]: P260: Do not breathe dust/fume/gas/mist/vapours/spray.
*[P261]: P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
*[P264]: P264: Wash ... thoroughly after handling.
*[P270]: P270: Do not eat, drink or smoke when using this product.
*[P271]: P271: Use only outdoors or in a well-ventilated area.
*[P273]: P273: Avoid release to the environment.
*[P280]: P280: Wear protective gloves/protective clothing/eye protection/face protection.
*[P284]: P284: Wear respiratory protection.
*[P301+P310]: P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
*[P301+P312]: P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
*[P302+P352]: P302+P352: IF ON SKIN: Wash with soap and water.
*[P304+P312]: P304+P312: IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
*[P304+P340]: P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
*[P305+P351+P338]: P305+P351+P338: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
*[P310]: P310: Immediately call a POISON CENTER or doctor/physician.
*[P311]: P311: Call a POISON CENTER or doctor/physician.
*[P312]: P312: Call a POISON CENTER or doctor/physician if you feel unwell.
*[P320]: P320: Specific treatment is urgent (see ... on this label).
*[P321]: P321: Specific treatment (see ... on this label).
*[P322]: P322: Specific measures (see ... on this label).
*[P330]: P330: Rinse mouth.
*[P332+P313]: P332+P313: If skin irritation occurs: Get medical advice/attention.
*[P337+P313]: P337+P313: If eye irritation persists: Get medical advice/attention.
*[P361]: P361: Remove/Take off immediately all contaminated clothing.
*[P362]: P362: Take off contaminated clothing.
*[P363]: P363: Wash contaminated clothing before reuse.
*[P403+P233]: P403+P233: Store in a well ventilated place. Keep container tightly closed.
*[P405]: P405: Store locked up.
*[P501]: P501: Dispose of contents/container to ...
*[v]: View this template
*[t]: Discuss this template
*[e]: Edit this template