Cyclohexanol

Cyclohexanol[1] |

|

Names
Preferred IUPAC name

Cyclohexanol

Other names

Cyclohexyl Alcohol,
hexahydrophenol,
hydrophenol,
hydroxycyclohexane,
Naxol
Hexalin
Hydralin
HOCy

Identifiers

CAS Number

* 108-93-0 Y

3D model (JSmol)

* Interactive image

3DMet  |

* B00190

ChEBI |

* CHEBI:18099 Y

ChEMBL |

* ChEMBL32010 Y

ChemSpider |

* 7678 Y

DrugBank |

* DB03703 Y

ECHA InfoCard | 100.003.301
EC Number |

* 203-630-6

KEGG |

* C00854 Y

PubChem CID

* 7966

RTECS number |

* GV7875000

UNII |

* 8E7S519M3P Y

CompTox Dashboard (EPA)

* DTXSID4021894

InChI

* InChI=1S/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2 Y

Key: HPXRVTGHNJAIIH-UHFFFAOYSA-N Y

* InChI=1/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2

Key: HPXRVTGHNJAIIH-UHFFFAOYAN

SMILES

* C1CCCCC1O

Properties

Chemical formula

| C6H12O
Molar mass | 100.158 g/mol
Appearance  | Colorless, viscous liquid.
Hygroscopic
Odor | camphor-like
Density | 0.9624 g/mL, liquid
Melting point | 25.93 °C (78.67 °F; 299.08 K)
Boiling point | 161.84 °C (323.31 °F; 434.99 K)

Solubility in water

| 3.60 g/100 mL (20 °C)
4.3 g/100 mL (30 °C)
Solubility | soluble in ethanol, ethyl ether, acetone, chloroform
miscible with ethyl acetate, linseed oil, benzene
Vapor pressure | 1 mmHg (20°C)[2]

Henry's law
constant (kH)

| 4.40 x 10−6 atm-cu m/mol
Acidity (pKa)  | 16

Magnetic susceptibility (χ)

| -73.40·10−6 cm3/mol

Refractive index (nD)

| 1.4641
Viscosity | 41.07 mPa·s (30 °C)
Hazards
Occupational safety and health (OHS/OSH):

Main hazards

| Flammable, skin irritant
Reacts violently with oxidizing agents
GHS labelling:

Pictograms

Signal word

| Warning

Hazard statements

| H302, H315, H332, H335

Precautionary statements

| P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P312, P321, P330, P332+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)  |

Flash point | 67 °C (153 °F; 340 K)

Autoignition
temperature

| 300 °C (572 °F; 573 K)
Explosive limits | 2.7-12%
Lethal dose or concentration (LD, LC):

LD50 (median dose)

| 2060 mg/kg (oral, rat)
2200-2600 mg/kg (oral, rabbit)[3]
NIOSH (US health exposure limits):

PEL (Permissible)

| TWA 50 ppm (200 mg/m3)[2]

REL (Recommended)

| TWA 50 ppm (200 mg/m3)[2]

IDLH (Immediate danger)

| 400 ppm[2]
Safety data sheet (SDS)  | MSDS for cyclohexanol

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Y verify (what is YN ?)

Infobox references

Chemical compound

Cyclohexanol is the organic compound with the formula HOCH(CH2)5. The molecule is related to cyclohexane by replacement of one hydrogen atom by a hydroxyl group.[4] This compound exists as a deliquescent colorless solid with a camphor-like odor, which, when very pure, melts near room temperature. Millions of tonnes are produced annually, mainly as a precursor to nylon.[5]

## Production[edit]

Cyclohexanol is produced by the oxidation of cyclohexane in air, typically using cobalt catalysts:[5]

2 C6H12 \+ O2 → 2 C6H11OH

This process coforms cyclohexanone, and this mixture ("KA oil" for ketone-alcohol oil) is the main feedstock for the production of adipic acid. The oxidation involves radicals and the intermediacy of the hydroperoxide C6H11O2H. Alternatively, cyclohexanol can be produced by the hydrogenation of phenol:

C6H5OH + 3 H2 → C6H11OH

This process can also be adjusted to favor the formation of cyclohexanone.

## Basic reactions[edit]

Cyclohexanol undergoes the main reactions expected for a secondary alcohol. Oxidation gives cyclohexanone, which is converted on a large scale in industry to the oxime, a precursor to caprolactam. As a laboratory exercise, this oxidation can be effected with chromic acid. Esterification affords the commercially useful derivatives dicyclohexyladipate and dicyclohexylphthalate, which are used as plasticizers. Heating in the presence of acid catalysts converts cyclohexanol to cyclohexene.[5][6]

## Structure[edit]

Cyclohexanol has at least two solid phases. One of them is a plastic crystal.

## Applications[edit]

As indicated above, cyclohexanol is an important feedstock in the polymer industry, firstly as a precursor to nylons, but also to various plasticizers. Small amounts are used as a solvent.

## Safety[edit]

Cyclohexanol is moderately toxic: the Threshold Limit Value for the vapor for 8 h is 50 ppm.[5] The IDLH concentration is set at 400 ppm, based on studies on the acute oral toxicity in animals.[7] Few studies have been done on its carcinogenicity, but one study on rats found it to have co-carcinogenic effects.[8]

## References[edit]

1. ^ Merck Index, 11th Edition, 2731.
2. ^ a b c d NIOSH Pocket Guide to Chemical Hazards. "#0165". National Institute for Occupational Safety and Health (NIOSH).
3. ^ "Cyclohexanol". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
4. ^ Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
5. ^ a b c d Michael Tuttle Musser "Cyclohexanol and Cyclohexanone" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005.
6. ^ G. H. Coleman, H. F. Johnstone (1925). "Cyclohexene". Organic Syntheses. 5: 33. doi:10.15227/orgsyn.005.0033.
7. ^ CDC - NIOSH Pocket Guide to Chemical Hazards
8. ^ [1] Lucrecia Márquez-Rosado, Cristina Trejo-Solís 2, María del Pilar Cabrales-Romero, Evelia Arce-Popoca, Adolfo Sierra-Santoyo, Leticia Alemán-Lazarini, Samia Fatel-Fazenda, Claudia E. Carrasco-Legleu, Saúl Villa-Treviño, "Co-carcinogenic effect of cyclohexanol on the development of preneoplastic lesions in a rat hepatocarcinogenesis model", Molecular Carcinogenesis, Vol. 46, No. 7, Pages 524 - 533, March 2007.

* v
* t
* e

Alcohols

By consumption|

| Alcohols found in
alcoholic drinks|

* 1-Propanol
* 2-Methyl-1-butanol
* Ethanol
* Isoamyl alcohol
* Isobutanol
* Phenethyl alcohol
* tert-Amyl alcohol
* tert-Butyl alcohol
* Tryptophol

|

Medical alcohol|

* Ethchlorvynol
* Methylpentynol
* Methanol poisoning
* Ethanol

Toxic alcohols|

* Isopropyl alcohol
* Methanol

Primary
alcohols (1°)|

| Methanol|

* 4-Methylcyclohexanemethanol
* Aminomethanol
* Cyclohexylmethanol
* Methoxymethanol
* Methylazoxymethanol
* Trifluoromethanol

|

Ethanol|

* 1-Aminoethanol
* 2,2,2-Trichloroethanol
* 2,2,2-Trifluoroethanol
* 2-(2-Ethoxyethoxy)ethanol
* 2-(2-Methoxyethoxy)ethanol
* 2-(2-Methoxyethoxy)ethanol
* 2-Butoxyethanol
* 2-Chloroethanol
* 2-Ethoxyethanol
* 2-Fluoroethanol
* 2-Mercaptoethanol
* 2-Methoxyethanol
* Aminoethylethanolamine
* Diethylethanolamine
* Dimethylethanolamine
* Ethanol
* Ethanolamine
* N,N-Diisopropylaminoethanol
* N-Methylethanolamine
* Phenoxyethanol
* Tribromoethanol

Butanol|

* 2-Methyl-1-butanol
* Isobutanol
* n-Butanol

Straight-chain
saturated
C1 — C9|

* Methanol
* Ethanol
* 1-Propanol
* 1-Butanol
* 1-Pentanol
* 1-Hexanol
* 1-Heptanol
* 1-Octanol (capryl)
* 1-Nonanol (pelargonic)

Straight-chain
saturated
C10 — C19|

* 1-Decanol (capric)
* 1-Undecanol (hendecyl)
* 1-Dodecanol (lauryl)
* 1-Tridecanol
* 1-Tetradecanol (myristyl)
* 1-Pentadecanol
* 1-Hexadecanol (cetyl / palmityl)
* 1-Heptadecanol
* 1-Octadecanol (stearyl)
* 1-Nonadecanol

Straight-chain
saturated
C20 — C29|

* 1-Icosanol (arachidyl)
* 1-Heneicosanol
* 1-Docosanol (behenyl)
* 1-Tricosanol
* 1-Tetracosanol (lignoceryl)
* 1-Pentacosanol
* 1-Hexacosanol (ceryl)
* 1-Heptacosanol
* 1-Octacosanol (cluytyl / montanyl)
* 1-Nonacosanol

Straight-chain
saturated
C30 — C39|

* 1-Triacontanol (melissyl / myricyl)
* 1-Hentriacontanol
* 1-Dotriacontanol (lacceryl)
* 1-Tritriacontanol
* 1-Tetratriacontanol (geddyl)
* 1-Pentatriacontanol
* 1-Hexatriacontanol
* 1-Heptatriacontanol
* 1-Octatriacontanol
* 1-Nonatriacontanol

Straight-chain
saturated
C40 — C49|

* 1-Tetracontanol
* 1-Hentetracontanol
* 1-Dotetracontanol
* 1-Tritetracontanol
* 1-Tetratetracontanol
* 1-Pentatetracontanol
* 1-Hexatetracontanol
* 1-Heptatetracontanol
* 1-Octatetracontanol
* 1-Nonatetracontanol

* 2-Ethylhexanol
* Allyl alcohol
* Anisyl alcohol
* Benzyl alcohol
* Cinnamyl alcohol
* Crotyl alcohol
* Furfuryl alcohol
* Isoamyl alcohol
* Neopentyl alcohol
* Nicotinyl alcohol
* Perillyl alcohol
* Phenethyl alcohol
* Prenol
* Propargyl alcohol
* Salicyl alcohol
* Tryptophol
* Vanillyl alcohol
* Veratrole alcohol

Secondary
alcohols (2°)|

* 1-Phenylethanol
* 2-Butanol
* 2-Deoxyerythritol
* 2-Heptanol
* 3-Heptanol
* 2-Hexanol
* 3-Hexanol
* 3-Methyl-2-butanol
* 2-Nonanol
* 2-Octanol
* 2-Pentanol
* 3-Pentanol
* Cyclohexanol
* Cyclopentanol
* Cyclopropanol
* Diphenylmethanol
* Isopropanol
* Pinacolyl alcohol
* Pirkle's alcohol
* Propylene glycol methyl ether

Tertiary
alcohols (3°)|

* 2-Methyl-2-pentanol
* 2-Methylheptan-2-ol
* 2-Methylhexan-2-ol
* 3-Methyl-3-pentanol
* 3-Methyloctan-3-ol
* Diacetone alcohol
* Ethchlorvynol
* Methylpentynol
* Nonafluoro-tert-butyl alcohol
* tert-Amyl alcohol
* tert-Butyl alcohol
* Triphenylethanol
* Triphenylmethanol

Hydric alcohols|

| Monohydric alcohols|

* Methanol
* Ethanol
* Isopropanol

|

Dihydric alcohols|

* Ethylene glycol
* Propylene glycol

Trihydric alcohols|

* Glycerol

Polyhydric alcohols|

* Pentaerythritol

Amyl alcohols|

* 2,2-Dimethylpropan-1-ol
* 2-Methylbutan-1-ol
* 2-Methylbutan-2-ol
* 3-Methylbutan-1-ol
* 3-Methylbutan-2-ol
* Pentan-1-ol
* Pentan-2-ol
* Pentan-3-ol

Aromatic alcohols|

* Benzyl alcohol
* 2,4-Dichlorobenzyl alcohol
* 3-Nitrobenzyl alcohol

Saturated
fatty alcohols|

* Cetostearyl alcohol
* Decanol
* Lauryl alcohol
* Myristyl alcohol
* Nonanol
* Octanol
* Tridecanol
* Undecanol

Branched and
unsaturated
fatty alcohols|

* 3-Methyl-3-pentanol
* Erucyl alcohol
* Linolenyl alcohol
* Linoleyl alcohol
* Oleyl alcohol
* Palmitoleyl alcohol
* tert-Amyl alcohol
* tert-Butyl alcohol

Sugar alcohols|

| C1 — C7|

* Methylene glycol (C1)
* Ethylene glycol (C2)
* Glycerol (C3)
* Erythritol (C4)
* Threitol (C4)
* Arabitol (C5)
* Ribitol (C5)
* Xylitol (C5)
* Mannitol (C6)
* Sorbitol (C6)
* Galactitol (C6)
* Iditol (C6)
* Volemitol (C7)

|

Deoxy sugar
alcohols|

* Fucitol

Cyclic sugar
alcohols|

* Inositol

Glycylglycitols|

* Maltitol
* Lactitol
* Isomalt
* Maltotriitol
* Maltotetraitol
* Polyglycitol

Terpene alcohols|

| Monoterpene
alcohols|

* Borneol
* Citronellol
* Geraniol
* Linalool
* Menthol
* Nerol
* Rhodinol
* Terpineol

|

Sesquiterpene
alcohols|

* Bisabolol
* Farnesol
* Nerolidol
* Patchoulol

Diterpene
alcohols|

* Phytol

Dialcohols|

* 1,4-Butanediol
* 1,5-Pentanediol
* 2-Methyl-2-propyl-1,3-propanediol
* Diethylpropanediol
* Ethylene glycol

Trialcohols|

* Glycerol

Sterols|

* Cholesterol
* Ergosterol
* Lanosterol
* β-Sitosterol
* Stigmasterol

Fluoroalcohols|

* 1,3-Difluoro-2-propanol
* 2,2,2-Trifluoroethanol
* 2-Fluoroethanol
* Nonafluoro-tert-butyl alcohol
* Trifluoromethanol

Preparations|

* Substitution of haloalkane
* Carbonyl reduction
* Ether cleavage
* Hydrolysis of epoxide
* Hydration of alkene
* Ziegler process

Reactions|

* Deprotonation
* Protonation
* Alcohol oxidation
* Glycol cleavage
* Nucleophilic substitution
* Fischer–Speier esterification
* Williamson ether synthesis
* Elimination reaction
* Nucleophilic substitution of carbonyl group
* Friedel-Crafts alkylation
* Nucleophilic conjugate addition
* Transesterification

* Category

* v
* t
* e

* Agents used in chemical warfare
* incapacitation
* riot control

Blood agents|

* Cyanogen
* Cyanogen bromide
* Cyanogen chloride (CK)
* Hydrogen cyanide (AC)
* Arsine
* Cacodyl cyanide
* Cacodyl oxide
* Hydrogen sulfide
* Phosphine
* Carbon monoxide
* Phosphorus trifluoride
* Methyl cyanoformate
* Iron pentacarbonyl
* Nickel tetracarbonyl
* 2,3,7,8-Tetrachlorodibenzodioxin
* Glycolonitrile
* Lactonitrile
* Acetone cyanohydrin
* Stibine
* Chloral cyanohydrin

Blister agents|

| Arsenicals|

* Ethyldichloroarsine (ED)
* Methyldichloroarsine (MD)
* Phenyldichloroarsine (PD)
* Lewisite (L)
* Lewisite 2 (L2)
* Lewisite 3 (L3)

|

Sulfur mustards|

* Levinstein mustard (EA-229)
* T
* Q
* CEES

Nitrogen mustards|

* HN1
* HN2
* HN3
* TL-301

Other|

* KB-16
* Dibutylchloromethyltin chloride
* Selenium oxychloride

Nerve agents|

| G-agents|

* Tabun (GA)
* Sarin (GB)
* Chlorosarin (ClGB)
* Thiosarin (SGB)
* Soman (GD)
* Chlorosoman (ClGD)
* Ethylsarin (GE)
* GH
* Cyclosarin (GF)
* GP
* Fluorotabun
* EA-1356
* EA-4352
* Crotylsarin

|

V-agents|

* EA-2192
* EA-3148
* VE
* VG
* VM
* VP
* VR
* VS
* VX
* EA-1763
* Chinese VX
* V-sub x (GD-7)

GV agents|

* GV (EA-5365)

Novichok agents|

* A-208
* A-232
* A-234
* A-242
* A-262
* C01-A035
* C01-A039
* C01-A042

Carbamates|

* Dimethylcarbamoyl fluoride
* EA-3887
* EA-3887A
* EA-3966
* EA-3990
* EA-4056
* T-1123
* T-1152
* Octamethylene-bis(5-dimethylcarbamoxyisoquinolinium bromide)
* TL-599
* TL-1238
* TL-1299
* TL-1317
* Miotine (AR-28/T-1843)
* 3152 CT
* 4-686-293-01 (Agent 1-10)

Other|

* Diisopropyl fluorophosphate
* EA-2012
* EA-2054
* EA-2098
* EA-2613
* 2-Ethoxycarbonyl-1-methylvinyl cyclohexyl methylphosphonate
* Neopentylene fluorophosphate
* Selenophos
* Phospholine
* R-16661
* Ro 3-0422
* Methanesulfonyl fluoride
* Dimefox (TL-792)

Precursors|

* Acetonitrile
* AT
* ATO
* A.P.C. complex
* Chlorosarin
* Chlorosoman
* Cyclohexanol
* 1,8-Dibromooctane
* N,N-Diisopropylaminoethanol (KB)
* EA-1250
* DIHP
* ZS
* DEHP
* EA-1224
* Dimethylamidophosphoric dichloride
* Dimethylamidophosphoric dicyanide
* DMHP
* Ethylphosphonoselenoic dichloride
* Formaldoxime
* Nital
* 4-Hydroxycoumarin
* Isopropyl alcohol (TB)
* Methyldichlorophosphine (SW)
* Methylphosphonyl difluoride (difluoro) (DF)
* Methylphosphonyl dichloride (dichloro)
* Nitromethane
* OPA mixture
* Phosphoryl chloride
* Phosphorus pentachloride
* Phosphorus trichloride (TH)
* Pinacolone
* Pinacolyl alcohol
* Phenacyl chloride
* QL
* 2,4,5-Trichlorophenol
* 3,3,5-Trimethylcyclohexanol
* Triethyl phosphite
* Trimethyl phosphite
* TC
* TG

Neurotoxins|

* Anatoxin-a
* Saxitoxin (TZ)
* Bungarotoxin
* Botulinum toxin (BTX)
* Tetanospasmin (TeNT)
* Ryanodine
* Ciguatoxin (CTX)
* Guanitoxin (GTX)
* Chlorophenylsilatrane
* Palytoxin (PTX)
* Maitotoxin (MTX)
* Tetrodotoxin
* Aconitine
* Brevetoxin (PbTX)
* Strychnine
* Antillatoxin (ATX)
* Tetraethyllead
* Dimethylmercury
* HN1 hydrochloride
* HN2 hydrochloride
* HN3 hydrochloride
* A-8564
* Sulfuryl fluoride
* Tremorine
* Oxotremorine
* Batrachotoxin
* Tetramethylenedisulfotetramine (TETS)
* Bicyclic phosphates
* IPTBO
* TBPO
* TBPS
* Cloflubicyne
* Trimethylolpropane phosphite
* Domoic acid

Nettle agents|

* Phosgene oxime (CX)

Pulmonary/
choking agents|

* Chlorine
* Bromine
* Phosgene (CG)
* Fluorine
* Perfluoroisobutene
* Chloropicrin (PS)
* Dimethyl(trifluoromethylthio)arsine
* Diphosgene (DP)
* Disulfur decafluoride (Z)
* Acrolein
* Ethyl bromoacetate
* Perchloromethyl mercaptan
* Phenylcarbylamine chloride
* Tetranitromethane
* Tetrachlorodinitroethane
* Chlorine trifluoride
* Perchloryl fluoride
* Cadmium oxide
* Cadmium chloride
* Mercuric chloride
* Selenium dioxide
* Selenoyl fluoride
* Trifluoronitrosomethane
* Trichloronitrosomethane
* Nitric oxide
* Nitrogen dioxide
* Dinitrogen tetroxide
* Sulfur dioxide
* Phosphorus trichloride
* Methyl isocyanate
* Ethenone
* Methyl vinyl ketone
* Trifluoroacetyl chloride
* Salcomine
* Fluomine
* Uranium hexafluoride
* Diborane
* Green Cross

Vomiting agents|

* Adamsite (DM)
* Chloropicrin
* Diphenylchlorarsine
* Diphenylcyanoarsine
* Cacodyl cyanide
* o-Dianisidine

Incapacitating
agents|

* BZ (CS-4030)
* Apomorphine
* Butyrophenone
* EA-4941 (CS-4640)
* Etorphine
* EA-2092
* CS-4297
* Etoxadrol
* Dimethylheptylpyran (DMHP)
* EA-2148
* EA-3167
* EA-3443
* Pethidine
* EA-3580
* EA-3834
* Kolokol-1
* LSD-25
* PAVA spray
* Psilocybin
* Sleeping gas
* Carfentanil
* JB-318
* JB-336
* CS-27349
* CAR-226,086
* CAR-301,060
* CAR-302,196
* CAR-302,282
* CAR-302,668
* Benperidol
* Desflurane
* Enflurane
* Isoflurane
* Halothane
* Sevoflurane
* Pentazocine
* Procarbazine
* Fluphenazine
* Chlorpromazine

Lachrymatory
agents|

* Xylyl bromide
* Pepper spray (OC)
* Mace (spray)
* CN
* CS
* CR
* CNS
* Benzyl chloride
* Benzyl bromide
* Benzyl iodide
* Bromobenzyl cyanide
* Thiophosgene
* Chloroacetone
* Bromoacetone
* Bromomethyl ethyl ketone
* Acrolein
* Phenacyl bromide
* Chloroacetophenone oxime
* Ethyl bromoacetate
* Ethyl iodoacetate
* Iodoacetone
* Allyl isothiocyanate
* Hexamethylene diisocyanate
* Crotonaldehyde

Malodorant agents|

* Thioacetone
* Allicin
* Skatole
* Cadaverine
* Putrescine

Cornea-clouding agents|

* Lewisite
* CX
* KB-16
* Methyl cyanoacrylate
* N-Methylmorpholine
* Allyl alcohol

Biological toxins|

* Abrin
* Aconitine
* Aflatoxins
* Anatoxin-a
* Batrachotoxin
* Botulinum toxin
* Brevetoxin
* Ciguatoxin
* Domoic acid
* Enterotoxin type B
* Guanitoxin
* Maitotoxin
* Modeccin
* Palytoxin
* Ricin
* Saxitoxin
* Shiga toxin
* T-2 mycotoxin
* Tetanospasmin
* Tetrodotoxin
* Volkensin

Other|

* Methyl fluoroacetate
* Napalm (variants and mixtures)
* Fluoroethyl fluoroacetate
* Depleted uranium
* post-combustion uranium oxides
* Plutonium and its compounds
* Polonium
* White phosphorus

* List of chemical warfare agents
* CB military symbol

*[CID]: Compound ID
*[EPA]: U.S. Environmental Protection Agency
*[H302]: H302: Harmful if swallowed
*[H315]: H315: Causes skin irritation
*[H332]: H332: Harmful if inhaled
*[H335]: H335: May cause respiratory irritation
*[P261]: P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
*[P264]: P264: Wash ... thoroughly after handling.
*[P270]: P270: Do not eat, drink or smoke when using this product.
*[P271]: P271: Use only outdoors or in a well-ventilated area.
*[P280]: P280: Wear protective gloves/protective clothing/eye protection/face protection.
*[P301+P312]: P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
*[P302+P352]: P302+P352: IF ON SKIN: Wash with soap and water.
*[P304+P312]: P304+P312: IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
*[P304+P340]: P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
*[P312]: P312: Call a POISON CENTER or doctor/physician if you feel unwell.
*[P321]: P321: Specific treatment (see ... on this label).
*[P330]: P330: Rinse mouth.
*[P332+P313]: P332+P313: If skin irritation occurs: Get medical advice/attention.
*[P362]: P362: Take off contaminated clothing.
*[P403+P233]: P403+P233: Store in a well ventilated place. Keep container tightly closed.
*[P405]: P405: Store locked up.
*[P501]: P501: Dispose of contents/container to ...
*[v]: View this template
*[t]: Discuss this template
*[e]: Edit this template