Nitrate nitrite

Class of chemical compounds

A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite (NO−2) and nitrate (NO−3) anions. They are mixed-anion compounds, and they are mixed-valence compounds. Some have third anions. Many nitrite nitrate compounds are coordination complexes of cobalt. Such a substance was discovered by Wolcott Gibbs and Frederick Genth in 1857.[citation needed]

## Production

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Mercury(II) nitrate and potassium nitrate in water solution produce the salt tripotassium tetranitratomercurate(II) nitrate K3[Hg(NO2)4]NO3.[1]

## Properties

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On heating, nitrate nitrites lose NO2 and NO and yield metal oxides.

## Related

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Other compounds having an element in two different anion states include the sulfate sulfites, the phosphate phosphites, arsenate arsenites and the selenate selenites.

## List

[edit]

name  | formula  | ratio

NO3:NO2

| mw | system  | space group | unit cell Å  | volume  | density  | properties  | references

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| [Cr(NH3)5(NO2)] ·(NO3)2 |  |  |  |  |  |  |  |  | [2]
trans-dinitrotetraamminecobalt(III) nitrate monohydrate  | [Co(NO2)2(NH3)4]NO3•H2O  | 1:2  |  | orthorhombic  | P212121 | a=10.02, b=6.02, c=16.84, Z=4  |  | 1.84  |  | [3]
cis-dinitrotetraamminecobalt(III) nitrate  | [Co(NO2)2(NH3)4]NO3 | 1:2  |  | orthorhombic  | P212121 | a=12.19, b=7.18, c=10.92, Z=4  |  | 1.95  |  | [4]
| [cis-β-Co(trien)(NO2)2]NO3 | 1:2  |  | monoclinic  | P21/n | a = 7.604, b = 13.019, c = 14.472, β = 98.13°, Z = 4  | 1418.26  | 1.682  | racemate  | [5]
| [cis-α-Co(tren)(NO2)2]NO3•13H2O  | 1:2  |  |  | P21/c |  |  |  |  | [6]
| trans-Co[(en2)(NO2)2]NO3 | 1:2  |  |  |  |  |  |  |  | [7]
| trans-[Co(2,3,2-tet)(NO2)2]NO3 | 1:2  | 373.21  |  | P21/n | a=8.490, b=8.884, c=18.580 and β=95.08°;, Z=4  | 1395.89  | 1.776  |  | [8]
| trans-[Co(2,3,2-tet)(NO2)2]NO3 |  | 373.21  |  | Pn  | a=6.493, b=11.731, c=9.325 β=100.13°; M.W.=373.21, Z=2)=  | 699.21  | 1.773  |  | [8]
| cis-[Co(Hao)2(NO2)2]NO3 (Hao = 3-amino-3-methyl-2-butanone oxime)  |  |  | monoclinic  | P21/n | a= 8.1 60, b= 17.250, c= 13.745, β= 104.77°  |  |  |  | [9]
| [Co(pic)2(NO2)2]NO3.½H2O pic=2-picolylamine  |  |  |  |  |  |  |  |  | [10]
| cis-[Co(phen)2(NO2)2]NO3 · 2 H2O phen=1,10-phenanthroline  |  |  |  |  |  |  |  |  | [11]
Sparteine copper(II) nitrate nitrite  | Cu(C15H26N2)(NO3)(NO2)  | 1:1  |  |  |  |  |  |  | green  | [12]
trans-diammine-cis-dinitratonitronitrosyl ruthenium(II)  | RuNO(NH3)2(NO3)2(NO2)  |  |  |  |  |  |  |  |  |
bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate  | [Pd(NO2)(NH3)3]2[Pd(NH3)4](NO3)4 | 4:1  | 829.20  | tetragonal  | I42m  | a=7.637 c=21.610 Z=2  |  | 2.18  | bright yellow  | [13]
bis(1,10-Phenanthroline)-(nitroso-O)-(nitrato-O,O')-cadmium(ii)  | Cd(phen)2(NO3)(NO2)  |  |  | monoclinic  | P21/c  | a 6.872 b 9.690 c 20.852 β 93.59°  |  |  |  | [14]
catena-((μ2-Nitroso-O,O')-aqua-(nitrato-O,O')-(1,10-phenanthroline)-cadmium(ii))  | [Cd(phen)(NO3)(NO2)(H2O)]n |  |  | monoclinic  | Cc | a 11.703Å b 15.242 c 13.451 β 106.321°  |  |  |  | [14]
| [NO2(NH3)2Pt(C5H4NO)2Pt(NH3)2NO2](NO3)2.H2O  |  |  |  |  |  |  |  | yellow  | [15]
| K3[Hg(NO2)4]NO3 | 1:4  |  | orthorhombic  | Pnma | a=12.12 b=10.58 c=9.28 Z=4  |  | 3.14  | pale yellow  | [1]
| Pb2(NO2)(NO3)(SeO3)  | 1:1  |  | orthorhombic  | Pmn21 | a=5.529, b=10.357, c=6.811, Z=2  | 390  |  | colourless  | [16]
| K2Pb(NO2)3(NO3)  | 1:3  | 503.4  | orthorhombic  | Pbca | a = 6.766, b = 11.999, c = 26.61, Z = 8  | 2160  | 3.095  | yellow orange  | [17]
| [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O  | 1:4  |  | orthorhombic  | Pbca | a = 8.9414, b = 14.5330, c = 24.9383, Z = 8  | 3240.6  |  |  |

## References

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1. ^ a b Hall, D.; Holland, R.V. (January 1969). "The crystal structure of K3[Hg(NO2)4]NO3". Inorganica Chimica Acta. 3: 235–238\. doi:10.1016/S0020-1693(00)92486-1.
2. ^ Shepard, Whiting N.; Forster, Leslie S. (1971). "The2 E?4 A 2 transition in tetragonal Cr3+ complexes". Theoretica Chimica Acta. 20 (2): 135–142\. doi:10.1007/BF00569260. ISSN 0040-5744. S2CID 95534463.
3. ^ Oonishi, Isao; Muto, Fumio; Komiyama, Yoshimichi (October 1969). "The Molecular and Crystal Structure of trans -Dinitrotetramminecobalt(III) Nitrate Monohydrate". Bulletin of the Chemical Society of Japan. 42 (10): 2791–2796\. doi:10.1246/bcsj.42.2791. ISSN 0009-2673.
4. ^ Oonishi, Isao; Fujimaki, Hiroto; Muto, Fumio; Komiyama, Yoshimichi (March 1970). "The Crystal Structure of cis -Dinitrotetraamminecobalt (III) Nitrate". Bulletin of the Chemical Society of Japan. 43 (3): 733–739\. doi:10.1246/bcsj.43.733. ISSN 0009-2673.
5. ^ Bernal, Ivan; Cetrullo, James (October 1986). "The phenomenon of conglomerate crystallization. VII. Clavic dissymmetry in coordination compounds.V. An investigation of the crystallization behavior of [cis-β-Co(triethylenetetramine)(NO2)2]X (X = I, NO3) and the crystal structure of racemic [cis-β-Co(trien)(NO2)2]NO3". Inorganica Chimica Acta. 120 (2): 109–117\. doi:10.1016/S0020-1693(00)86096-X.
6. ^ Bernal, Ivan; Cetrullo, James; Myrczek, Jozef (October 1993). "The phenomenon of conglomerate crystallization Part XXXI. The crystallization behavior of [cis-Co(en)2(NO2)2Br and of : counter-ion effects on crystallization pathway of racemate solutions". Materials Chemistry and Physics. 35 (3–4): 290–300\. doi:10.1016/0254-0584(93)90145-C.3–4&rft.pages=290-300&rft.date=1993-10&rft_id=info:doi/10.1016/0254-0584(93)90145-C&rft.aulast=Bernal&rft.aufirst=Ivan&rft.au=Cetrullo,+James&rft.au=Myrczek,+Jozef&rft_id=https://linkinghub.elsevier.com/retrieve/pii/025405849390145C&rfr_id=info:sid/en.wikipedia.org:Nitrate+nitrite" class="Z3988">
7. ^ Charpeutier, T.; Virlet, J. (October 1998). "Triple quantum MQMAS spectroscopy of (I=7/2) in Na3Co(NO2)6 and trans-Co[(en2)(NO2)2]NO3 interplay between the quadrupole coupling and anisotropic shielding tensors". Solid State Nuclear Magnetic Resonance. 12 (4): 227–242\. doi:10.1016/S0926-2040(98)00051-4. PMID 9800268.
8. ^ a b Bernal, Ivan; Somoza, Fernando; Chen, Ya-Chen; Massoud, Salah S. (April 1997). "The Phenomenon of Conglomerate Crystallization. Part 48. Two Polymorphs of Racemic Trans-[Co(2,3,2-Tet) (No2)2]No3(I and Ii)". Journal of Coordination Chemistry. 41 (3): 233–247\. doi:10.1080/00958979708023574. ISSN 0095-8972.
9. ^ Murray, Don E.; Schlemper, Elmer O.; Siripaisarnpipat, Sutatip; Murmann, R. Kent (1986). "A structural and isotopic NO 2 – exchange rate comparison of trans-[Co(ao–H–ao)(NO 2 ) 2 ] and cis-[Co(Hao) 2 (NO 2 ) 2 ]NO 3". J. Chem. Soc., Dalton Trans. (9): 1759–1765\. doi:10.1039/DT9860001759. ISSN 0300-9246.
10. ^ Sutton, Gj (1960). "Some Studies in Inorganic Complexes. VIII. Cobalt(II) and Cobalt(III) with 2-Picolylamine". Australian Journal of Chemistry. 13 (4): 473. doi:10.1071/CH9600473. ISSN 0004-9425.
11. ^ Ghaschghaie, Natascha (2010). "HETEROLEPTISCHE COBALT(III)-CHELATKOMPLEXE MIT BIOLIGANDEN" (PDF).
12. ^ Lee, Yong-Min; Kim, Yong-Kyu; Jung, Hee-Cheul; Kim, Young-Inn; Choi, Sung-Nak (2002-03-20). "Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes". Bulletin of the Korean Chemical Society. 23 (3): 404–412\. doi:10.5012/BKCS.2002.23.3.404.
13. ^ Boer, F. Peter; Carter, Virginia B.; Turley, June W. (April 1971). "Single-crystal x-ray and Raman studies of bis(nitrotriamminepalladium(II)) tetraamminepalladium(II) tetranitrate". Inorganic Chemistry. 10 (4): 651–661\. doi:10.1021/ic50098a001. ISSN 0020-1669.
14. ^ a b Fan, Ruiqing; Zhang, Yanjiao; Yin, Yanbin; Su, Qing; Yang, Yulin; Hasi, Wuliji (June 2009). "Syntheses, structures, and luminescent properties of cadmium (II) complexes: 3D supramolecular [Cd(phen)(NO3)(NO2)(H2O)]n and Cd(phen)2(NO3)(NO2) constructed by π–π stacking interactions". Synthetic Metals. 159 (11): 1106–1111\. doi:10.1016/j.synthmet.2009.04.007.
15. ^ Hollis, L. Steven; Lippard, Stephen J. (May 1982). "Effect of axial ligands on the platinum-platinum bond in binuclear .alpha.-pyridonate-bridged platinum(III) complexes. Structures of [X(NH3)2Pt(C5H4NO)2Pt(NH3)2X](NO3)2.H2O, X = NO3, NO2". Inorganic Chemistry. 21 (5): 2116–2117\. doi:10.1021/ic00135a087. ISSN 0020-1669.
16. ^ Effenberger, Herta (February 1987). "Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3)". Monatshefte für Chemie. 118 (2): 211–216\. doi:10.1007/BF00810054. S2CID 101945551.
17. ^ Nardelli, Mario; Pelizzi, Giancarlo (January 1980). "Crystal structure of K2Pb(NO2)3(NO3)·H2O". Inorganica Chimica Acta. 38: 15–19\. doi:10.1016/S0020-1693(00)91928-5.

* v
* t
* e

Salts and covalent derivatives of the nitrate ion

| HNO3 |  |  |  | He

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LiNO3 | Be(NO3)2 | B(NO3)−4 | RONO2
+CO3
+C2O4 | NO3−
NH4NO3 | HOONO2 | FNO3
+F | Ne
NaNO3 | Mg(NO3)2 | Al(NO3)3
Al(NO3)−4 | Si  | P  | +SO4 | ClONO2
+Cl | Ar
KNO3 | Ca(NO3)2 |  | Sc(NO3)3 | Ti(NO3)4 | VO(NO3)3 | Cr(NO3)3 | Mn(NO3)2 | Fe(NO3)2
Fe(NO3)3 | Co(NO3)2
Co(NO3)3 | Ni(NO3)2 | CuNO3
Cu(NO3)2 | Zn(NO3)2 | Ga(NO3)3 | Ge  | As  | +SeO3 | BrNO3
+Br | Kr
RbNO3 | Sr(NO3)2 |  | Y(NO3)3 | Zr(NO3)4 | NbO(NO3)3 | MoO2(NO3)2 | Tc  | Ru  | Rh(NO3)3 | Pd(NO3)2 | AgNO3 | Cd(NO3)2 | In(NO3)3 | Sn(NO3)4 | Sb4O4(OH)2(NO3)2 | Te  | INO3
+IO3 | Xe(NO3)2
CsNO3 | Ba(NO3)2 | *  | Lu(NO3)3 | Hf(NO3)4 | TaO(NO3)3 | WO2(NO3)2 | ReO3NO3 | Os  | Ir3O(NO3)10 | Pt  | Au(NO3)−4 | Hg2(NO3)2
Hg(NO3)2 | TlNO3
Tl(NO3)3 | Pb(NO3)2 | Bi(NO3)3
BiO(NO3) | Po(NO3)4 | At  | Rn
FrNO3 | Ra(NO3)2 | **  | Lr  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og

*  | La(NO3)3 | Ce(NO3)3
Ce(NO3)4 | Pr(NO3)3 | Nd(NO3)3 | Pm(NO3)3 | Sm(NO3)3 | Eu(NO3)3 | Gd(NO3)3 | Tb(NO3)3 | Dy(NO3)3 | Ho(NO3)3 | Er(NO3)3 | Tm(NO3)3 | Yb(NO3)3
**  | Ac(NO3)3 | Th(NO3)4 | PaO(NO3)3 | UO2(NO3)2 | Np(NO3)4 | Pu(NO3)4 | Am(NO3)3 | Cm(NO3)3 | Bk(NO3)3 | Cf(NO3)3 | Es  | Fm  | Md  | No

* v
* t
* e

Salts and covalent derivatives of the nitrite ion

| HNO2 |  |  |  | He

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LiNO2 | Be(NO2)2 | B  | C(NO2)4
CH(NO2)3
CH2(NO2)2
CH3(NO2) |

* HNO2
* N(NO2)3
* H2NNO2
* -NO3, -NO2

| N2O3 | NO2F | Ne
NaNO2 | Mg(NO2)2 | Al(NO2)3 | Si  | P  | S  | NO2Cl | Ar
KNO2 | Ca(NO2)2 |  | Sc(NO2)3 | Ti  | VO(NO2)3 | Cr(NO2)3 | Mn(NO2)2 | Fe(NO2)3 | Co(NO2)2
Co(NO2)3 | Ni(NO2)2 | Cu(NO2)2 | Zn(NO2)2 | Ga(NO2)3 | Ge  | As  | Se  | NO2Br | Kr
RbNO2 | Sr(NO2)2 |  | Y(NO2)3 | Zr  | Nb  | Mo  | Tc  | Ru  | Rh  | Pd(NO2)2 | AgNO2 | Cd(NO2)2 | In  | Sn  | Sb  | Te  | NO2I | Xe
CsNO2 | Ba(NO2)2 | *  | Lu  | Hf  | Ta  | W  | Re  | Os  | Ir  | Pt(NO2)2
[Pt(NO2)4]2− | Au  | Hg2(NO2)2
Hg(NO2)2 | TlNO2 | Pb(NO2)2 | Bi(NO2)3
BiO(NO2) | Po  | At  | Rn
Fr  | Ra  | **  | Lr  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og

*  | La(NO2)3 | Ce(NO2)3 | Pr(NO2)3 | Nd(NO2)3 | Pm  | Sm(NO2)3 | Eu(NO2)2 | Gd(NO2)3 | Tb  | Dy  | Ho  | Er  | Tm  | Yb
**  | Ac  | Th  | Pa  | UO2(NO2)2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No
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