Plutonium pentafluoride

Names
Other names

plutonium(V) fluoride

Identifiers

CAS Number

* 31479-19-3

3D model (JSmol)

* Interactive image

ChemSpider |

* 124961

PubChem CID

* 141636

CompTox Dashboard (EPA)

* 30185379

InChI

* InChI=1S/5FH.Pu/h5*1H;/q;;;;;+5/p-5

Key: SZQALXDXHXGSHK-UHFFFAOYSA-I

SMILES

* F[Pu](F)(F)(F)F

Properties

Chemical formula

| F5Pu
Molar mass | 339 g·mol−1
Appearance  | white solid
Structure

Crystal structure

| tetragonal
Related compounds

Related compounds

| Uranium pentafluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Chemical compound

Plutonium pentafluoride is a binary inorganic compound of plutonium and fluorine with the chemical formula PuF5.[1][2][3]

## Synthesis

[edit]

Photodissociation of gaseous plutonium hexafluoride to plutonium pentafluoride and fluorine.[4]

## Physical properties

[edit]

Plutonium pentafluoride forms a white solid.[4]

## Hazards

[edit]

Plutonium pentafluoride is toxic and radioactive.[5]

## References

[edit]

1. ^ "Plutonium pentafluoride". NIST. Retrieved 6 April 2023.
2. ^ Morss, L. R.; Edelstein, Norman M.; Fuger, Jean (31 December 2007). The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5). Springer Science & Business Media. p. 1079\. ISBN 978-1-4020-3598-2. Retrieved 6 April 2023.
3. ^ Meyer, G.; Morss, L. R. (6 December 2012). Synthesis of Lanthanide and Actinide Compounds. Springer Science & Business Media. p. 80\. ISBN 978-94-011-3758-4. Retrieved 6 April 2023.
4. ^ a b "US4670239A Photochemical preparation of plutonium pentafluoride". worldwide.espacenet.com. Retrieved 6 April 2023.
5. ^ "Plutonium pentafluoride". haz-map.com. Retrieved 6 April 2023.

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Plutonium compounds

Plutonium(II)|

* [K(2.2.2-crypt)][PuCp'3]

Plutonium(III)|

* PuAs
* PuB
* PuH3
* PuP
* PuPO4
* PuF3
* PuCl3
* PuBr3
* PuI3
* PuN
* PuH2
* Pu2O3
* PuS
* Pu2S3
* PuS2
* Pu2O2S
* PuSe
* PuOBr
* PuOCl
* PuOF
* PuOI
* PuSi

Plutonium(III,IV)|

* Pu4O4S3

Plutonium(IV)|

* PuB2
* PuC
* Pu(NO3)4
* PuF4
* PuO2
* Pu(IO3)4
* Pu(SO4)2
* Pu(C8H8)2
* PuOS
* Pu2O2S3

Plutonium(V)|

* PuF5
* XePuF6

Plutonium(VI)|

* PuF6

Plutonium(VIII)|

* PuO4?

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Salts and covalent derivatives of the fluoride ion

| HF |  |  |  | ?HeF2

|
|
|
|

LiF | BeF2 | BF
BF3
B2F4
+BO3 | CF4
CxFy
+CO3 | NF3
FN3
N2F2

N2F4
NF2
?NF5

+NO3 | OF2
O2F2

O3F2
O4F2
?OF4 | F2 | Ne
NaF | MgF2 | AlF
AlF3 | SiF4 | P2F4
PF3
PF5
+PO4 | S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4 | ClF
ClF3
ClF5 | ?ArF2
?ArF4
KF | CaF
CaF2 |  | ScF3 | TiF2
TiF3
TiF4 | VF2
VF3
VF4
VF5 | CrF2
CrF3
CrF4
CrF5
?CrF6 | MnF2
MnF3
MnF4
?MnF5 | FeF2
FeF3
FeF4 | CoF2
CoF3
CoF4 | NiF2
NiF3
NiF4 | CuF
CuF2
?CuF3 | ZnF2 | GaF2
GaF3 | GeF2
GeF4 | AsF3
AsF5 | Se2F2
SeF4
SeF6
+SeO3 | BrF
BrF3
BrF5 | KrF2
?KrF4
?KrF6
RbF | SrF
SrF2 |  | YF3 | ZrF2
ZrF3
ZrF4 | NbF4
NbF5 | MoF4
MoF5
MoF6 | TcF4
TcF

TcF6 | RuF3
RuF

RuF5
RuF6 | RhF3
RhF4
RhF5
RhF6 | PdF2
Pd[PdF6]
PdF4
?PdF6 | Ag2F
AgF
AgF2
AgF3 | CdF2 | InF
InF3 | SnF2
SnF4 | SbF3
SbF5 | TeF4
?Te2F10
TeF6
+TeO3 | IF
IF3
IF5
IF7
+IO3 | XeF2
XeF4
XeF6
?XeF8
CsF | BaF2 |  | LuF3 | HfF4 | TaF5 | WF4
WF5
WF6 | ReF4
ReF5
ReF6
ReF7 | OsF4
OsF5
OsF6
?OsF

?OsF
8 | IrF2
IrF3
IrF4
IrF5
IrF6 | PtF2
Pt[PtF6]
PtF4
PtF5
PtF6 | AuF
AuF3
Au2F10
?AuF6
AuF5•F2 | Hg2F2
HgF2
?HgF4 | TlF
TlF3 | PbF2
PbF4 | BiF3
BiF5 | PoF2
PoF4
PoF6 | AtF
?AtF3
?AtF5 | RnF2
?RnF

?RnF

FrF  | RaF2 |  | LrF3 | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og
| ↓  |  |
| LaF3 | CeF3
CeF4 | PrF3
PrF4 | NdF2
NdF3
NdF4 | PmF3 | SmF
SmF2
SmF3 | EuF2
EuF3 | GdF3 | TbF3
TbF4 | DyF2
DyF3
DyF4 | HoF3 | ErF3 | TmF2
TmF3 | YbF2
YbF3
AcF3 | ThF2
ThF3
ThF4 | PaF4
PaF5 | UF3
UF4
UF5
UF6 | NpF3
NpF4
NpF5
NpF6 | PuF3
PuF4
PuF5
PuF6 | AmF2
AmF3
AmF4
?AmF6 | CmF3
CmF4
?CmF6 | BkF3
BkF
4 | CfF3
CfF4 | EsF3
EsF4
?EsF6 | Fm  | MdF3 | No

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Halides of actinides

|  | Ac | Th | Pa | U | Np | Pu | Am | Cm | Bk | Cf | Es | Fm

|
|
|
|
|
|
|
|
|
|
|
|

+6  |  |  |  | UF6
UCl6 | NpF6 | PuF6 | AmF6 | CmF6 |  |  | EsF6 |
+5  |  |  | PaF5
PaCl5
PaBr5
PaI5 | UF5
UCl5
UBr5 | NpF5 | PuF5 |  |  |  |  |  |
+4  |  | ThF4
ThCl4
ThBr4
ThI4 | PaF4
PaCl4
PaBr4
PaI4 | UF4
UCl4
UBr4
UI4 | NpF4
NpCl4
NpBr4 | PuF4 | AmF4 | CmF4 | BkF4 | CfF4 | EsF4 |
+3  | AcF3
AcCl3
AcBr3
AcI3 | ThF3
ThCl3
ThI3 |  | UF3
UCl3
UBr3
UI3 | NpF3
NpCl3
NpBr3
NpI3 | PuF3
PuCl3
PuBr3
PuI3 | AmF3
AmCl3
AmBr3
AmI3 | CmF3
CmCl3
CmBr3
CmI3 | BkF3
BkCl3
BkBr3
BkI3 | CfF3
CfCl3
CfBr3
CfI3 | EsF3
EsCl3
EsBr3
EsI3 | FmCl3
+2  |  | ThF2
ThI2
ThCl2 |  |  |  |  | AmF2
AmCl2
AmBr2
AmI2 |  |  | CfI2
CfCl2 | EsCl2
EsBr2
EsI2 | FmCl2

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