Rhodium(III) sulfide

Names
IUPAC name

Rhodium(III) sulfide

Other names

Rhodium sesquisulfide

Identifiers

CAS Number

* 12067-06-0

3D model (JSmol)

* Interactive image

ChemSpider |

* 23349348

ECHA InfoCard | 100.031.874
EC Number |

* 235-075-0

PubChem CID

* 54672740

CompTox Dashboard (EPA)

* DTXSID301014316

InChI

* Key: ILLXJAWVPNCIFC-UHFFFAOYSA-N

* InChI=1S/2Rh.3S

SMILES

* S=[Rh]S[Rh]=S

Properties

Chemical formula

| Rh2S3
Molar mass | 301.99 g·mol−1
Appearance  | black solid
Density | 6.46 g/cm−3

Solubility in water

| insoluble

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references

Chemical compound

Rhodium(III) sulfide is the inorganic compound with the formula Rh2S3. It is an insoluble black solid, prepared by the heating a mixture of elemental rhodium and sulfur. Crystals can be grown by chemical vapor transport using bromine as the transporting agent. The structure consists of octahedral and tetrahedral Rh and S centers, respectively. No close Rh-Rh contacts are observed.[1] Rh2Se3 and Ir2S3 adopt the same structure as Rh2S3.

## References

[edit]

1. ^ Parthé, Erwin; Hohnke, Dieter K.; Hulliger, Fritz (1967). "New Structure Type with Octahedron Pairs for Rhodium(III) Sulfide, Rhodium(III) Selenide, and Iridium(III) Sulfide". Acta Crystallographica. 23: 832–40. doi:10.1107/S0365110X67003767.

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Rhodium compounds

Rh(0)|

| Organorhodium(0) compounds|

* Rh4(CO)12
* Rh6(CO)16

|

Rh(I)|

* RhCl(P(C6H5)3)3

| Organorhodium(I) compounds|

* ((C2H4)2RhCl)2
* ((C8H12)RhCl)2
* ((C8H14)2RhCl)2
* ((CO)2RhCl)2
* HRh(P(C6H5)3)4
* HRh(CO)(P(C6H5)3)3

|

Rh(II)|

* Rh2(CH3CO2)4

| Organorhodium(II) compunds|

* Rh(C5H5)2

|

Rh(III)|

* RhBr3
* Rh(C5H5N)4Cl3
* RhCl3
* Rh(ClO4)3
* RhF3
* Rh(OH)3
* RhI3
* Rh(NH3)5ClCl2
* Rh(NO3)3
* Rh2O3
* Rh2S3
* Rh2(SO4)3
* YbRh2Si2

| Organorhodium(III) compunds|

* ((CH3)5C5RhCl2)2
* Rh(O2C5H7)3

|

Rh(IV)|

* RhO2
* RhF4

Rh(V)|

* RhF5
* XeRhF6

Rh(VI)|

* RhF6

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Sulfides (S2−)

| H2S |  |  |  | He

|
|
|
|

Li2S | BeS | B2S3
+BO3 | CS2
COS | (NH4)SH | O  | F  | Ne
Na2S | MgS | Al2S3 | SiS
SiS2
-Si | PxSy
-P | -S2−
2 | Cl  | Ar
K2S | CaS |  | ScS
Sc2S3 | TiS
TiS2
Ti2S3
TiS3 | VS
VS2
V2S3 | CrS
Cr2S3 | MnS
MnS2 | FeS
Fe3S4 | CoxSy | NixSy | Cu2S
CuS | ZnS | GaS
Ga2S3 | GeS
GeS2
-Ge | As2S3
As4S3
-As | SeS2
+Se | Br  | Kr
Rb2S | SrS |  | Y2S3 | ZrS2 | NbS2 | MoS2
MoS3 | TcS2
Tc2S7 | Ru  | Rh2S3 | PdS | Ag2S | CdS | In2S3 | SnS
SnS2
-Sn | Sb2S3
Sb2S5
-Sb | TeS2 | I  | Xe
Cs2S | BaS | *  | LuS
Lu2S3 | HfS2 | TaS2 | WS2
WS3 | ReS2
Re2S7 | OsS
4 | Ir2S3
IrS2 | PtS
PtS2 | Au2S
Au2S3 | HgS | Tl2S | PbS
PbS2 | Bi2S3 | PoS | At  | Rn
Fr  | Ra  | **  | Lr  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og

*  | LaS
La2S3 | CeS
Ce2S3 | PrS
Pr2S3 | NdS
Nd2S3 | PmS
Pm2S3 | SmS
Sm2S3 | EuS
Eu2S3 | GdS
Gd2S3 | TbS
Tb2S3 | DyS
Dy2S3 | HoS
Ho2S3 | ErS
Er2S3 | TmS
Tm2S3 | YbS
Yb2S3
**  | Ac2S3 | ThS2 | Pa  | US
US2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No
*[CID]: Compound ID
*[EPA]: U.S. Environmental Protection Agency
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