Telluride bromide

Class of chemical compounds

The telluride bromides are chemical compounds that contain both telluride ions (Te2−) and bromide ions (Br−). They are in the class of mixed anion compounds or chalcogenide halides.[1]

In many tellurium bromide compounds, tellurium atoms link up in a helix, similar to pure tellurium structure. In Rhenium compounds tellurium atoms form a cluster with rhenium atoms. In some materials, tellurium forms a honeycomb like structure containing tubes filled with bromine and the other elements.

## List

[edit]

name  | formula  | system  | space group  | unit cell Å  | volume  | density  | properties  | ref

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| Sb2Te2BrAlCl4 | monoclinic  | C2/c |  |  |  |  | [1]
copper telluride bromide  | CuBrTe  | tetragonal  | I41/amd | a = 16.417 c = 4.711 Z = 16  | 1269.7  | 5.67  | black  | [2]
| MoTe4Br  |  |  |  |  |  | silver  | [3]
| Mo4Te7Br8 |  |  |  |  |  | black semiconductor  | [3]
| MoTe6Br3 |  |  |  |  |  | silver  | [3]
| [Mo3Se7(TeBr3)Br2]2[Te2Br10]  | triclinic  | P1 | a=10.1638 b=11.0241 c=12.5200 α =85.461 β =85.529 γ =76.410°; Z =1  | 1358.94  | 4.631  |  | [1][4]
| NbOTe7Br5 |  |  |  |  |  |  | [3]
decasilver tetratelluride tribromide  | Ag10Te4Br3 | hexagonal *2

orthorhombic*2

| P6/mmm

P63/mmc

Cmc21

|  |  |  | Ag+ conductor  | [5]
| Ag10Te4Br3 | orthorhombic  | Cmcm | a=15.381 b=15.765 c=13.726  | 3328.2  |  | Ag ion conductor  | [6]
| Ag23Te12Br  | orthorhombic  | Pnnm |  |  |  | honeycomb Te; Ag ion conductor  | [1]
| Ag19Te6Br7 | trigonal

monoclinic

| R3m  |  |  |  |  | [1]
| Ag19Te6Br5.4I1.6 | orthorhombic  | Pnma |  |  |  | electric conductor  | [1]
| Ag19Te5SeBr7 | orthorhombic  | Pbam |  |  |  |  | [1]
| La3Te4Br  | orthorhombic  | Pnma | a = 16.343 b = 4.350 c = 14.266 Z = 4  | 1014.1  |  |  | [1][7]
| W2O2Te4Br5 |  |  |  |  |  |  |
| Re4Te8Br16 |  | I4 | a=11.202 c=13.935  | 1748.6  |  |  | [8]

[Re2Br4(Te2)(TeBr)2(TeBr2)2]

|  |  |  |  |  |  | [1]
| [Re6Te8(TeBr2)6]Br2 |  |  |  |  |  |  | [1]
| Pd4Br4Te3 | triclinic  | P1 | a =8.425 b =8.450 c =8.648; α =82.55 β =73.36 γ =88.80°; Z =2  |  |  | semiconductor  | [9]
| AuBrTe2 | orthorhombic  |  | a=4.033 b=12.375 c=8.942  |  | 7.89  | silvery white, metallic melt 457 C  | [2][10]
| Hg3Te2Br2 |  |  |  |  |  | yellow  | [1][11]
| Hg3Te2BrI  | monoclinic  | C2  | 18.376 b=9.587 c=10.575 β=100.11°  |  |  |  | [11][12]
| Tl5Te2Br  |  |  |  |  |  |  | [13]
| BiTeBr  | trigonal  | P3m1  | a = 4.2662 c = 6.487  |  |  | melt 526  | [14]
| Bi2Te2BrAlCl4 | monoclinic  | C2/c |  |  |  |  | [1]

## References

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1. ^ a b c d e f g h i j k l Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews. 347: 23–47\. doi:10.1016/j.ccr.2017.06.010.
2. ^ a b Carkner, Philip M.; Haendler, Helmut M. (June 1976). "The crystal structure of copper bromide telluride". Journal of Solid State Chemistry. 18 (2): 183–189\. Bibcode:1976JSSCh..18..183C. doi:10.1016/0022-4596(76)90094-3.
3. ^ a b c d Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides". Angewandte Chemie International Edition in English. 33 (2): 163–172\. doi:10.1002/anie.199401631. ISSN 0570-0833.
4. ^ Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †". Inorganic Chemistry. 46 (11): 4677–4682\. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.
5. ^ Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials. 18 (10): 2538–2544\. doi:10.1021/cm060226m.
6. ^ Giller, Malte; Bawohl, Melanie; Gerstle, Alexandra P.; Nilges, Tom (November 2013). "Copper Substitution and Mixed Cation Effect in Ag 10 Te 4 Br 3: Copper Substitution and Mixed Cation Effect in Ag 10 Te 4 Br 3". Zeitschrift für anorganische und allgemeine Chemie. 639 (14): 2379–2381\. doi:10.1002/zaac.201300309.
7. ^ Larres, Markus; Mudring, Anja-Verena; Meyer, Gerd (2011-03-21). "The First Lanthanide Telluride-Bromide: La3Te4Br, a Valence Compound". Crystals. 1 (1): 15–21\. doi:10.3390/cryst1010015. ISSN 2073-4352.
8. ^ Mironov, Yu. V.; Fedorov, V. E. (2002). "Tetranuclear rhenium chalcogenide cluster complexes with a cubane core. Synthesis, structures, and properties". Russian Chemical Bulletin. 51 (4): 569–580\. doi:10.1023/A:1015843529164. S2CID 92252272.
9. ^ Janetzky, Manuel; Rödel, Eva; Pietzonka, Clemens; Müller, Ulrich; Ressler, Thorsten; Harbrecht, Bernd (2007-09-18). "The Valence Problem of Pd4Br4Te3". Chemistry - A European Journal. 13 (35): 9882–9891\. doi:10.1002/chem.200700658. hdl:11858/00-001M-0000-0010-FF49-A. PMID 17879245.
10. ^ Rabenau, A.; Rau, H.; Rosenstein, G. (August 1970). "Telluride halides of gold". Journal of the Less Common Metals. 21 (4): 395–401\. doi:10.1016/0022-5088(70)90043-3.
11. ^ a b Kozin, L. F.; Hansen, Steve C. (2013-10-11). Mercury Handbook: Chemistry, Applications and Environmental Impact. Royal Society of Chemistry. p. 294\. ISBN 978-1-84973-515-5.
12. ^ Minets, Yu.V; Voroshilov, Yu.V; Pan’ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2". Journal of Alloys and Compounds. 367 (1–2): 109–114\. doi:10.1016/j.jallcom.2003.08.020.1–2&rft.pages=109-114&rft.date=2004-03&rft_id=info:doi/10.1016/j.jallcom.2003.08.020&rft.aulast=Minets&rft.aufirst=Yu.V&rft.au=Voroshilov,+Yu.V&rft.au=Pan’ko,+V.V&rfr_id=info:sid/en.wikipedia.org:Telluride+bromide" class="Z3988">
13. ^ Babanly, D. M.; Babanly, M. B. (October 2010). "Phase equilibria in the Tl-TlBr-Te system and thermodynamic properties of the compound Tl5Te2Br". Russian Journal of Inorganic Chemistry. 55 (10): 1620–1629\. doi:10.1134/S0036023610100219. ISSN 0036-0236. S2CID 189795948.
14. ^ Petasch, U.; Oppermann, H. (1999-04-01). "Untersuchungen zum quasibinären System Bi2Te3/BiBr3 / Investigations on the Pseudobinary System Bi2Te3/BiBr3". Zeitschrift für Naturforschung B. 54 (4): 487–490\. doi:10.1515/znb-1999-0412. ISSN 1865-7117. S2CID 201643367.

* v
* t
* e

Salts and covalent derivatives of the bromide ion

| HBr |  |  |  | He

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LiBr | BeBr2 | BBr3
+BO3 | CBr4
+C | NBr3
BrN3
NH4Br
NOBr
+N | Br2O
BrO2
Br2O3
Br2O5 | BrF
BrF3
BrF5 | Ne
NaBr | MgBr2 | AlBr
AlBr3 | SiBr4 | PBr3
PBr5
PBr7
+P | S2Br2
SBr2 | BrCl | Ar
KBr | CaBr2
|  | ScBr3 | TiBr2
TiBr3
TiBr4 | VBr2
VBr3 | CrBr2
CrBr3
CrBr4 | MnBr2 | FeBr2
FeBr3 | CoBr2 | NiBr2 | CuBr
CuBr2 | ZnBr2 | GaBr3 | GeBr2
GeBr4 | AsBr3
+As
+AsO3 | SeBr2
SeBr4 | Br2 | Kr
RbBr | SrBr2 |  | YBr3 | ZrBr2
ZrBr3
ZrBr4 | NbBr5 | MoBr2
MoBr3
MoBr4 | TcBr3
TcBr4 | RuBr3 | RhBr3 | PdBr2 | AgBr | CdBr2 | InBr
InBr3 | SnBr2
SnBr4 | SbBr3
+Sb
-Sb | Te2Br
TeBr4
+Te | IBr
IBr3 | XeBr2
CsBr | BaBr2 | *  | LuBr3 | HfBr4 | TaBr5 | WBr5
WBr6 | ReBr3 | OsBr3
OsBr4 | IrBr3
IrBr
4 | PtBr2
PtBr4 | AuBr
AuBr3 | Hg2Br2
HgBr2 | TlBr | PbBr2 | BiBr3 | PoBr2
PoBr4 | AtBr | Rn
FrBr | RaBr2 | **  | Lr  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og

*  | LaBr3 | CeBr3 | PrBr3 | NdBr2
NdBr3 | PmBr3 | SmBr2
SmBr3 | EuBr2
EuBr3 | GdBr3 | TbBr3 | DyBr3 | HoBr3 | ErBr3 | TmBr2
TmBr3 | YbBr2
YbBr3
**  | AcBr3 | ThBr4 | PaBr4
PaBr5 | UBr4
UBr5 | NpBr3
NpBr4 | PuBr3 | AmBr2
AmBr3 | CmBr3 | BkBr3 | CfBr3 | EsBr2
EsBr3 | Fm  | Md  | No

* v
* t
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Salts and covalent derivatives of the telluride ion

| H2Te
-TeH |  |  |  | He

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Li2Te | BeTe | B  | CTe2
(CH3)2Te | (NH4)2Te | O  | F  | Ne
Na2Te | MgTe | Al2Te3 | Si  | P0.8Te0.2 | S  | Cl  | Ar
K2Te | CaTe |  | Sc2Te3 | Ti  | VTe2 | CrTe
Cr2Te3 | MnTe
MnTe2 | FeTe | CoTe | NiTe | Cu2Te
CuTe
CuTe2 | ZnTe | GaTe
Ga2Te3
-Ga | GeTe
-Ge | As2Te3
As4Te3
+As | Se  | +Br | Kr
Rb2Te | SrTe |  | Y2Te3 | ZrTe5 | NbTe2 | MoTe2 | Tc  | Ru  | Rh  | Pd  | Ag2Te | CdTe | In2Te3 | SnTe
SnTe2 | Sb2Te3 | Te2-
Te2-
n | I  | Xe
Cs2Te | BaTe | *  | LuTe
Lu2Te3 | HfTe5 | TaTe2 | WTe2
WTe3 | ReTe2 | Os  | Ir  | Pt  | AuxTey | HgTe | Tl2Te | PbTe | Bi2Te3 | Po  | At  | Rn
Fr  | RaTe | **  | Lr  | Rf  | Db  | Sg  | Bh  | Hs  | Mt  | Ds  | Rg  | Cn  | Nh  | Fl  | Mc  | Lv  | Ts  | Og

*  | LaTe
La2Te3 | CeTe
Ce2Te3 | PrTe
Pr2Te3 | NdTe
Nd2Te3 | Pm  | SmTe
Sm2Te3 | EuTe
Eu2Te3 | GdTe
Gd2Te3 | TbTe
Tb2Te3 | DyTe
Dy2Te3 | HoTe
Ho2Te3 | ErTe
Er2Te3 | TmTe
Tm2Te3 | YbTe
Yb2Te3
**  | Ac  | ThTe2 | Pa  | UTe2 | Np  | Pu  | Am  | Cm  | Bk  | Cf  | Es  | Fm  | Md  | No
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