Telluride oxide

Class of chemical compounds

The telluride oxides or oxytellurides are double salts that contain both telluride and oxide anions (Te2− and O2−). They are in the class of mixed anion compounds.

Compounds that can be mistakenly called "telluride oxides" are tellurium dioxide and tellurite.

Some of these are under investigation as photovoltaic materials, e.g. oxygen doped zinc telluride.[1]

## Structure

[edit]

Due to the different size and chemical nature of Te2− and O2− the ions occupy different positions in the crystal structure. Some of these structures are layered.[2]

Many of the crystal systems are tetragonal. One unusual structure has stacked tubes made from tellurium, with nested tubes of antimony oxide, which contain alkali metal.[3]

## List

[edit]

name  | formula  | MW  | ratio

Te:O

| system  | space group  | unit cell

| volume  | density  | optical  | band gap  |  | CAS  | references

|
|
|
|
|
|
|
|
|
|
|
|
|

| V2Te2O  |  | 2:1  | tetragonal  |  | a = 3.9282 and c = 13.277  |  |  |  |  |  |  | [4]
| KV3Te3O0.42 |  |  | hexagonal  | P63/m  | a=9.62, c=4.48  | 359  |  |  |  |  |  | [5]
| Rb0.8V2Te2O  |  | 2:1  |  |  |  |  |  |  |  |  |  | [6]
| Sr2MnO2Cu1.82Te2 |  |  |  | I4/mmm | a=4.200933 c=19.28303  | 340.304  |  |  |  |  |  | [2]
| Sr2CoO2Cu2Te2 |  |  |  | I4/mmm | a=4.152337 c=19.54645  | 337.018  |  |  |  |  |  | [2]
oxygen doped zinc telluride  | ZnTe1−xOx |  |  |  |  |  |  |  |  |  |  |  |
| Ga2O2.95Te0.05 |  |  |  |  |  |  |  |  |  |  |  | [7]
Tetragadolinium bis[tetraoxidosilicate(IV)] oxide telluride  | Gd4(SiO4)2OTe  | 956.78  |  | orthorhombic  | Pnma | a=12.495 b=10.8683 c=6.8075 Z=4  | 924.5  | 6.874  | colourless  |  |  |  | [8]
Niobium iodide oxide telluride  | Nb4I4Te9O  |  |  |  |  |  |  |  |  |  |  |  |
Antimony copper oxide telluride  | CuSbTeO  |  |  |  |  |  |  |  |  |  |  |  |
dibarium cobalt disilver dioxide ditelluride  | Ba2CoO2Ag2Te2 | 836.52  | 2:2  | tetragonal  | I4/mmm |  |  |  |  |  |  |  | [9]
| Be3Cd4Ge3O12Te  |  |  |  |  |  |  |  |  |  |  | 12449-27-3  |
SBC-1  | (K6(H2O)6Sb12O18)3Te36 |  |  |  |  | tellurium tubes  |  |  |  |  |  |  | [3][10]
RB-CTH-1  | Rb18Sb36O54(SbTe3)2(Te2)6 |  |  |  |  | tellurium tubes  |  |  |  |  |  |  | [11][12]
| Ba2TeO  |  | 1:1  | tetragonal  | P4/nmm | a=5.0337, c=9.9437, Z=2  |  |  | semiconductor  | 2.93  |  |  | [13]
| LaCuOTe  |  | 1:1  | tetragonal  | P4/nmm | a = 4.1775, c = 9.326  | 162.75  |  |  | 2.31  |  |  | [14]
| CeCuOTe  |  | 1:1  | tetragonal  | P4/nmm | a = 4.1497, c = 9.309  | 160.30  |  |  |  |  |  | [14]
| La2O2Te  |  | 1:2  | tetragonal  | I4/mmm | a=4.1231 c=13.096 Z=2  |  | 6.525  |  |  |  |  | [15]
| Ce2O2Te  |  | 1:2  | tetragonal  | I4/mmm | a=4.0817 c=12.947 Z=2  |  | 6.772  |  |  |  |  | [15]
| CeOCuTe  |  |  |  |  |  |  | 7.39  |  |  |  |  |
| Pr2O2Te  |  | 1:2  |  | I4/mmm | a=4.0562 c=12.858  | 211.5  | 6.930  |  |  |  |  | [15]
| PrOCuTe  |  |  |  |  |  |  | 7.32  |  |  |  |  |
| NdCuOTe  |  | 1:1  | tetragonal  | P4/nmm | a = 4.1056, c = 9.332  | 157.30  |  |  | 2.26  |  |  | [14]
| Nd2O2Te  |  | 1:2  | tetragonal  | I4/mmm | a=4.0308 c=12.771  |  | 7.172  |  |  |  |  | [15]
samarium(III) oxide telluride  | Sm2TeO2 |  | 1:2  | tetragonal  | I4/mmm | a=3.9983 c=12.655  |  | 7.556  |  |  |  |  | [16][15]
| Eu2TeO2 |  | 1:2  | tetragonal  | I4/mmm | a=3.9756 c=12.579 Z=2  |  | 7.743  |  |  |  |  | [15]
| Gd2TeO2 |  | 1:2  | tetragonal  | I4/mmm | a=3.9620 c=12.532 Z=2  |  | 8.004  |  |  |  |  | [15]
| Tb2TeO2 |  | 1:2  | tetragonal  | I4/mmm | a=3.9389 c=12.454 Z=2  |  | 8.206  |  |  |  | 89800-88-4  | [15]
| Dy2TeO2 |  | 1:2  | tetragonal  | I4/mmm | a=3.9234 c=12.403 Z=2  |  | 8.430  |  |  |  |  | [15]
| Ho2TeO2 |  |  | orthorhombic  | Cmc21  | a=3.8505 b=12.9004 c=4.0521 Z=2  |  | 8.075  |  |  |  |  | [15]
| Er2TeO2 |  |  | orthorhombic  | Cmc21  | a=3.8263 b=12.8297 c=4.0240 Z=2  |  | 8.307  |  |  |  |  | [15]
| BiOCuTe  |  | 1:1  | tetragonal  | P4/nmm  | a=4.04200 c=9.5234  |  |  |  |  |  |  | [17]
| Bi2O2Te  |  | 1:2  | tetragonal  | I4/mmm | a=3.98025 c=12.7039  |  |  | semiconductor  | 0.23  |  |  | [18]
thorium oxytelluride  | ThOTe  | 375.64  | 1:1  | tetragonal  | P4/nmm | a=4.1173 c=7.5289 Z=2  | 127.63  | 9.775  | black  | 1.45  |  |  | [19]
| UOTe  |  | 1:1  | tetragonal  | P4/nmm | a=4.004 c=7.491  |  |  |  |  |  |  | [20][21]
| U4O4Te3 |  | 3:4  | tetragonal  | I4/mmm | a=4.010 c=27.54 Z=2  |  |  |  |  |  |  | [20]
| U2O2Te  |  | 1:2  |  |  |  |  |  |  |  |  |  | [20]
neptunium oxide telluride  | Np2TeO2 |  | 1:2  | Tetragonal  | I4/mmm | a=4.003 c=12.73 Z=2  |  |  |  |  |  |  | [22]
| Pu2TeO2 |  | 1:2  | tetragonal  | I4/mmm | a = 4.008, c = 12.659 Z=2  | 203.4  | 10.58  |  | 0.65  |  |  | [23]
| Am2TeO2 |  |  | tetragonal  | I4/mmm | a=3.994 c=12.72  |  |  |  |  |  |  |
| Cm2TeO2 |  |  |  | I4/mmm | a=3.98 c=12.58  |  |  |  |  |  |  | [24]

## References

[edit]

1. ^ Tanaka, Tooru; Saito, Katsuhiko; Guo, Qixin; Yu, Kin Man; Walukiewicz, Wladek (2020-03-05). "Intermediate band solar cells based on highly mismatched II-VI oxide semiconductors". In Teherani, Ferechteh H.; Look, David C.; Rogers, David J. (eds.). Oxide-based Materials and Devices XI. Vol. 11281\. San Francisco, United States: SPIE. p. 60\. Bibcode:2020SPIE11281E..1UT. doi:10.1117/12.2550950. ISBN 978-1-5106-3325-4. S2CID 215790057.
2. ^ a b c Blandy, Jack N.; Parker, Dinah R.; Cassidy, Simon J.; Woodruff, Daniel N.; Xu, Xiaoyu; Clarke, Simon J. (2019-06-17). "Synthesis, Structure, and Compositional Tuning of the Layered Oxide Tellurides Sr 2 MnO 2 Cu 2– x Te 2 and Sr 2 CoO 2 Cu 2 Te 2". Inorganic Chemistry. 58 (12): 8140–8150\. doi:10.1021/acs.inorgchem.9b00919. ISSN 0020-1669. PMC 7007212. PMID 31185546.
3. ^ a b Palmqvist, Anders E. C.; Iversen, Bo B.; Zanghellini, Ezio; Behm, Mårten; Stucky, Galen D. (2004-01-30). "A Crystalline Microporous Narrow-Bandgap Semiconductor". Angewandte Chemie International Edition. 43 (6): 700–704\. doi:10.1002/anie.200351284. ISSN 1433-7851. PMID 14755696.
4. ^ Ablimit, Abduweli; Sun, Yun-Lei; Cheng, Er-Jian; Liu, Ya-Bin; Wu, Si-Qi; Jiang, Hao; Ren, Zhi; Li, Shiyan; Cao, Guang-Han (2018-12-03). "V 2 Te 2 O: A Two-Dimensional van der Waals Correlated Metal". Inorganic Chemistry. 57 (23): 14617–14623\. doi:10.1021/acs.inorgchem.8b02280. ISSN 0020-1669. PMID 30450892. S2CID 53951139.
5. ^ Wu, Eric J.; Pell, Michael A.; Genin, Hugh S.; Ibers, James A. (August 1998). "Synthesis, characterization, and electronic structure of KV3Te3O0.42". Journal of Alloys and Compounds. 278 (1–2): 123–129\. doi:10.1016/S0925-8388(98)00585-4.1–2&rft.pages=123-129&rft.date=1998-08&rft_id=info:doi/10.1016/S0925-8388(98)00585-4&rft.aulast=Wu&rft.aufirst=Eric+J.&rft.au=Pell,+Michael+A.&rft.au=Genin,+Hugh+S.&rft.au=Ibers,+James+A.&rfr_id=info:sid/en.wikipedia.org:Telluride+oxide" class="Z3988">
6. ^ Ablimit, Abduweli; Sun, Yun-Lei; Jiang, Hao; Wu, Si-Qi; Liu, Ya-Bin; Cao, Guang-Han (2018-06-20). "Weak metal-metal transition in the vanadium oxytelluride Rb 1 − δ V 2 Te 2 O". Physical Review B. 97 (21): 214517. arXiv:1803.01605. doi:10.1103/PhysRevB.97.214517. ISSN 2469-9950. S2CID 119080272.
7. ^ Kim, J. S.; Lee, S. B.; Bahng, J. H.; Choi, J. C.; Park, H. L.; Mho, S. I.; Kim, T. W.; Whang, Y. H.; Kim, G. C. (2001). "Optical Characteristics of Emission from β-Ga2O3 with Group-VIb Ions". Physica Status Solidi A. 187 (2): 569–573\. doi:10.1002/1521-396X(200110)187:2<569::AID-PSSA569>3.0.CO;2-R. ISSN 1521-396X.
8. ^ Daszkiewicz, Marek; Gulay, Lubomir D. (2015-07-01). "Accidental formation of Gd 4 (SiO 4 ) 2 OTe: crystal structure and spectroscopic properties". Acta Crystallographica Section C. 71 (7): 598–601\. doi:10.1107/S2053229615011651. ISSN 2053-2296. PMID 26146399.
9. ^ Matsumoto, Yuki; Nambu, Yusuke; Honda, Takashi; Ikeda, Kazutaka; Otomo, Toshiya; Kageyama, Hiroshi (21 May 2020). "High-pressure Synthesis of Ba2CoO2Ag2Te2 with Extended CoO2 Planes". Inorganic Chemistry. 59 (12): 8121–8126\. doi:10.1021/acs.inorgchem.0c00429. PMID 32437136. S2CID 218835678.
10. ^ Liebau, F. (May 2004). "Microporous materials of the nth-order: new classes of poroates". Microporous and Mesoporous Materials. 70 (1–3): 103–108\. Bibcode:2004MicMM..70..103L. doi:10.1016/j.micromeso.2004.02.006.1–3&rft.pages=103-108&rft.date=2004-05&rft_id=info:doi/10.1016/j.micromeso.2004.02.006&rft_id=info:bibcode/2004MicMM..70..103L&rft.aulast=Liebau&rft.aufirst=F.&rfr_id=info:sid/en.wikipedia.org:Telluride+oxide" class="Z3988">
11. ^ Shulman, Alexander; Palmqvist, Anders E. C. (2007-01-22). "A Crystalline, Large-Pore, Microporous Semiconductor". Angewandte Chemie (in German). 119 (5): 732–736\. Bibcode:2007AngCh.119..732S. doi:10.1002/ange.200603075. PMID 17154204.
12. ^ Shulman, Alexander; Zanghellini, Ezio; Palmqvist, Anders E.C. (September 2010). "Reversible sorption in the crystalline microporous semiconductor Rb-CTH-1". Journal of Solid State Chemistry. 183 (9): 1912–1916\. Bibcode:2010JSSCh.183.1912S. doi:10.1016/j.jssc.2010.06.012.
13. ^ Besara, T.; Ramirez, D.; Sun, J.; Whalen, J.B.; Tokumoto, T.D.; McGill, S.A.; Singh, D.J.; Siegrist, T. (February 2015). "Ba2TeO: A new layered oxytelluride". Journal of Solid State Chemistry. 222: 60–65\. Bibcode:2015JSSCh.222...60B. doi:10.1016/j.jssc.2014.11.003.
14. ^ a b c Liu, Min Ling; Wu, Li Bin; Huang, Fu Qiang; Chen, Li Dong; Ibers, James A. (January 2007). "Syntheses, crystal and electronic structure, and some optical and transport properties of LnCuOTe (Ln=La, Ce, Nd)". Journal of Solid State Chemistry. 180 (1): 62–69\. Bibcode:2007JSSCh.180...62L. doi:10.1016/j.jssc.2006.09.014.
15. ^ a b c d e f g h i j k Weber, Frank (1999). Präparative Studien in den Mehrstoffsystemen Selten-Erd-Metall - Selen bzw. Tellur und Sauerstoff (doctoralThesis) (in German). Universität Stuttgart, Universität Stuttgart. doi:10.18419/OPUS-668.
16. ^ Petzel, T.; Ludwigs, J. (February 1987). "The thermodynamics of vaporization and formation of samarium(III) oxide telluride". Journal of the Less Common Metals. 128: 241–247\. doi:10.1016/0022-5088(87)90211-6.
17. ^ Vaqueiro, Paz; Guélou, Gabin; Stec, Maria; Guilmeau, Emmanuel; Powell, Anthony V. (2013). "A copper-containing oxytelluride as a promising thermoelectric material for waste heat recovery". J. Mater. Chem. A. 1 (3): 520–523\. doi:10.1039/C2TA00878E. ISSN 2050-7488. S2CID 53996626.
18. ^ Luu, Son D.N.; Vaqueiro, Paz (March 2015). "Synthesis, characterisation and thermoelectric properties of the oxytelluride Bi2O2Te" (PDF). Journal of Solid State Chemistry. 226: 219–223\. Bibcode:2015JSSCh.226..219L. doi:10.1016/j.jssc.2015.02.026. S2CID 95377359.
19. ^ Koscielski, Lukasz A.; Ringe, Emilie; Van Duyne, Richard P.; Ellis, Donald E.; Ibers, James A. (2012-08-06). "Single-Crystal Structures, Optical Absorptions, and Electronic Distributions of Thorium Oxychalcogenides ThOQ (Q = S, Se, Te)". Inorganic Chemistry. 51 (15): 8112–8118\. doi:10.1021/ic300510x. ISSN 0020-1669. PMID 22799890.
20. ^ a b c Noël, H.; Potel, M.; Shlyk, L.; Kaczorowski, D.; Troć, R. (January 1995). "Synthesis and crystal structure of a novel uranium oxytelluride U4O4Te3". Journal of Alloys and Compounds. 217 (1): 94–96\. doi:10.1016/0925-8388(94)01301-W.
21. ^ Klein Haneveld, A.J.; Jellinek, F. (June 1964). "Uranium oxide telluride". Journal of Inorganic and Nuclear Chemistry. 26 (6): 1127–1128\. doi:10.1016/0022-1902(64)80277-3.
22. ^ Thévenin, T.; Jové, J.; Pagès, M. (September 1985). "Tetragonal neptunium oxide telluride Np2O2Te : Crystallographic and 237Np mössbauer studies". Materials Research Bulletin. 20 (9): 1075–1080\. doi:10.1016/0025-5408(85)90207-7.
23. ^ Costantini, J.M.; Damien, D.; de Novion, C.H.; Blaise, A.; Cousson, A.; Abazli, H.; Pagès, M. (April 1983). "Crystal chemistry, magnetic, and electrical properties of the tetragonal plutonium oxide telluride Pu2O2Te". Journal of Solid State Chemistry. 47 (2): 219–224\. Bibcode:1983JSSCh..47..219C. doi:10.1016/0022-4596(83)90010-5.
24. ^ Morss, L. R.; Edelstein, Norman M.; Fuger, Jean (2010-10-21). The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6): Volumes 1-6. Springer Science & Business Media. p. 1421\. ISBN 978-94-007-0211-0.