Caesium cadmium chloride

Caesium cadmium chloride
Names
	IUPAC name Caesium cadmium chloride
	Other names Caesium trichlorocadmate; Caesium chlorocadmate; Caesium trichlorocadmate(II);
Identifiers
CAS Number	13845-08-4;
3D model (JSmol)	Interactive image;
PubChem CID	159356594;
	InChI InChI=1S/Cd.3ClH.Cs/h;3*1H;/q+2;;;;+1/p-3 Key: LHZPOBUPLFKLBV-UHFFFAOYSA-K;
	SMILES [Cd+2]([Cl-])([Cl-])[Cl-].[Cs+]; [Cs+].[Cl-] [Cd+2]([Cl-])[Cl-];
Properties
Chemical formula	Cs Cd Cl3
Molar mass	351.675 g/mol
Appearance	White or colourless solid
Structure
Crystal structure	hexagonal
Space group	P63/mmc
Lattice constant	a = 7.403, c = 18.406
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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	Infobox references

Caesium cadmium chloride (CsCdCl₃) is a synthetic crystalline material. It belongs to the AMX₃ group (where A=alkali metal, M=bivalent metal, X=halogen ions). It crystallizes in a hexagonal space group P6₃/mmc with unit cell lengths a = 7.403 Å and c = 18.406 Å, with one cadmium ion having D_3d symmetry and the other having C_3v symmetry.^[1]

It is formed when an aqueous solution of hydrochloric acid containing an equimolar solution of caesium chloride and cadmium chloride.^[2]

References

↑ Chang, Jin Rong.; McPherson, Gary L.; Atwood, Jerry L. (December 1975). "Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride". Inorganic Chemistry 14 (12): 3079–3085. doi:10.1021/ic50154a044.
↑ Electron paramagnetic spectrum of manganese(II)-manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5-) dimer Gary L. McPherson, and Jin Rong Chang, Inorg. Chem., 1976, 15 (5), 1018-1022. doi:10.1021/ic50159a006

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[1] Chang, Jin Rong.; McPherson, Gary L.; Atwood, Jerry L. (December 1975). "Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride". Inorganic Chemistry 14 (12): 3079–3085. doi:10.1021/ic50154a044.

[2] Electron paramagnetic spectrum of manganese(II)-manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5-) dimer Gary L. McPherson, and Jin Rong Chang, Inorg. Chem., 1976, 15 (5), 1018-1022. doi:10.1021/ic50159a006

[1]

[2]

v t e Cadmium compounds
Cadmium(I)	Cd₂(AlCl₄)₂
Cadmium(II)	Cd(BF₄)₂ CdF₂ CdCl₂ CdBr₂ CdI₂ Cd(CN)₂ CdH₂ CdO CdS CdSe CdTe Cd(OH)₂ Cd(NO₃)₂ CdSO₄ CdWO₄ Cd₃As₂ CsCdCl₃ CsCdBr₃

Names
IUPAC name Caesium cadmium chloride
Other names Caesium trichlorocadmate Caesium chlorocadmate Caesium trichlorocadmate(II)
Identifiers
CAS Number	13845-08-4
3D model (JSmol)	Interactive image
PubChem CID	159356594
InChI InChI=1S/Cd.3ClH.Cs/h;3*1H;/q+2;;;;+1/p-3 Key: LHZPOBUPLFKLBV-UHFFFAOYSA-K
SMILES [Cd+2]([Cl-])([Cl-])[Cl-].[Cs+] [Cs+].[Cl-] [Cd+2]([Cl-])[Cl-]
Properties
Chemical formula	Cs Cd Cl₃
Molar mass	351.675 g/mol
Appearance	White or colourless solid
Structure
Crystal structure	hexagonal
Space group	P6₃/mmc
Lattice constant	a = 7.403, c = 18.406
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is ^YN ?)
Infobox references

Caesium cadmium chloride

Topic: Chemistry

References