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Carbonate nitrate

Topic: Chemistry

 From HandWiki - Reading time: 6 min

Short description: Class of chemical compounds

Carbonate nitrates are mixed anion compounds containing both carbonate and nitrate ions.

Hydrotalcite can contain carbonate and nitrate ions between its layers. Magnesium can be substituted by nickel, cobalt or copper.[1]

Oxycarbonitrates containing an alkaline earth metal and cuprate and nitrate and carbonate anions in layers, form a family of superconducting materials.[2]

List

name formula ratio formula

weight

crystal

system

space

group

unit cell Å volume density comment ref
Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate (Co(NH3)5(CO3))(NO3)·H2O 1:1 monoclinic P21/c a = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4 931.2 [3]
(Co(NH3)4CO3)(NO3)·(H2O)0.5 1:1 monoclinic P21/n a=7.4319 b=22.647 c=10.4103 β=92.052° Z=8 1756 1.95 violet-red; loses water at 125°C [4][5]
(Co(NH3)4(CO3)(NO3))2·H2O 1:1 monoclinic P21/n a=7.4960 b=22.673 c=10.513 β=91.41° Z=4 1786.12 1.915 [6]
[Co(NH3)5CO3]NO3·1/2H2O 1:1 monoclinic P21/m a=7.6661 b=9.6212 c=7.0725 β=106.261° Z=2 500.78 1.82 pink [7]
[Co(NH3)5CO3]NO3·H2O 1:1 monoclinic P21 a = 7.6733 b = 9.6398 c = 7.0852 β = 106.195° 1.87 pink [8]
Tetraammine(carbonato-κ2O,O′)cobalt(III) nitrate (Co(CO3)(NH3)4)(NO3) 1:1 monoclinic P21/c a = 7.8520 b = 6.7922 c = 17.5394 β = 95.440° Z = 4 931.2 pink [9]
[(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3][NO3]2·H2O 1:2 triclinic P1 a=7.7038 b=9.672 c=10.861 α=104.826° β=109.405° γ=91.553° [10]
cis-(Carbonato-O,O')-bis(2,2'-bipyridine)-cobalt(iii) nitrate pentahydrate [Co(C10H8N2)2(CO3)]NO3·5H2O monoclinic C2/c a=10.931 b=16.039 c=14.435β=101.94° Z=4 2476 [11]
Na3Rb6(CO3)3(NO3)2Cl·(H2O)6 3:2 1029.39 hexagonal P63/mcm a = 9.5732 c = 15.820 Z=2 1255.6 2.723 UV cut off 231 nm;

(-) uniaxial;

birefringence 0.14 @ 546 nm

[12]
Na3Rb6(CO3)3(NO3)2Br·6H2O 3:2 hexagonal P63/mcm a=9.6086 c=15.864 Z=2 [13]
N0.2C0.8Sr3Cu2O7.0 [2]
C0.8N0.2Sr2CuO5.3
N0.5C0.5Sr3Cu2O7.4 Tc=33 [2]
N0.5C0.5Sr2CaCu2O7.45 Tc=91 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.5 Tc=91 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.8 Tc=101 [2]
N0.5C0.5Sr2.7Ca1.3Cu3O9.85 Tc=101 [2]
N0.5C0.5Sr2Ca2Cu3O10.0 [2]
N0.5C0.5Sr2Ca3Cu4O10.0 [2]
N0.5C0.5Sr2Ca3Cu4O11.8 Tc=99K [2]
N0.5C0.5Sr2Ca3Cu4O11.9 Tc=101K [2]
N0.5C0.5Sr3.4Ca1.6Cu4O12.0 Tc=105K [2]
YCaBa4Cu5(NO3)0.3(CO3)0.7O11 superconductor Tc=82k [14]
hexakis(μ4-(R)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-diaqua-pentakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate tetrahydrate monoclinic P21 a=15.6719 b=25.570 c=16.472 β=101.838° colourless [15]
hexakis(μ4-(S)-N2-(2-Oxybenzyl)asparaginato)-(μ3-carbonato-O,O,O',O',O'',O'')-heptakis(methanol)-methoxy-hexakis(nitrato-O,O')-hepta-lanthanum(iii) methanol solvate pentahydrate monoclinic P21 a=15.662 b=25.624 c=16.460 β=101.924° [15]
pentakis(μ3-Glycine hydroxamato)-tetraaqua-(nitrato-O)-(nitrato-O,O')-penta-copper(ii)-europium(iii) tetrahydrate [EuCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2O triclinic P1 a=11.163 b=11.524 c=13.323 α=93.85° β=94.79° γ=107.14° Z=2 1624 2.425 [16]
pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-gadolinium(iii) hydrate [GdCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.5H2O triclinic P1 a=11.206 b=11.505 c=13.298 α=94.026° β=94.942° γ=107.558° Z=2 1620.2 2.440 dark blue [16]
pentakis(μ-2-amino-N-oxidoethanimidato)-(carbonato)-nitrato-penta-aqua-penta-copper(ii)-dysprosium(iii) hydrate [DyCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.28H2O triclinic P1 a=11.1083 b=11.4991 c=13.2894 α=93.923° β=94.771° γ=107.147° Z=2 1608.7 2.460 dark blue [16]
[HoCu5(GlyHA)5(CO3)(NO3)(H2O)5]·3.445H2O triclinic P1 a=11.2027 b=11.4955 c=13.247 α=94.001° β=94.784° γ=107.518° Z=2 1613.0 2.467 dark blue [16]
bis(μ4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II))

tetranitrate trihydrate

((Pt(NH3)2)4(CO3)2)(NO3)4·(H2O)3 2:4 triclinic P1 a=11.324 b=12.151 c=10.926 α=103.792° β=111.266° γ=75.845° blue [17]
(Tl5/6Cr1/6)Sr4Cu2(CO3)1/2(NO3)1/2O7 tetragonal a = 3.8320 c = 16.4112 [18]
[Pb6O4](OH)(NO3)(CO3) 1:1 orthorhombic Pnma a=30.557 b=5.809 c=7.183 Z=4 1274.9 [19]

References

  1. ↑ Chmielarz, Lucjan; Kuśtrowski, Piotr; Rafalska-Łasocha, Alicja; Dziembaj, Roman (2002). "Influence of Cu, Co and Ni cations incorporated in brucite-type layers on thermal behaviour of hydrotalcites and reducibility of the derived mixed oxide systems". Thermochimica Acta 395 (1–2): 225–236. doi:10.1016/S0040-6031(02)00214-9. Bibcode: 2002TcAc..395..225C. 
  2. ↑ 2.00 2.01 2.02 2.03 2.04 2.05 2.06 2.07 2.08 2.09 2.10 2.11 Zhigadlo, N D; Matveev, A T; Anan, Y; Asaka, T; Kimoto, K; Matsui, Y; Takayama-Muromachi, E (2000-08-01). "High-pressure synthesis and properties of a new oxycarbonitrate superconductors in the Sr-Ca-Cu-N-C-O system". Superconductor Science and Technology 13 (8): 1246–1251. doi:10.1088/0953-2048/13/8/322. ISSN 0953-2048. Bibcode: 2000SuScT..13.1246Z. https://iopscience.iop.org/article/10.1088/0953-2048/13/8/322. 
  3. ↑ Le Bail, Armel (2013-07-15). "Tetraammine(carbonato-κ 2 O , O ′)cobalt(III) nitrate: a powder X-ray diffraction study". Acta Crystallographica Section E: Structure Reports Online 69 (7): i42–i43. doi:10.1107/S1600536813017522. ISSN 1600-5368. PMID 24046543. PMC 3772400. https://scripts.iucr.org/cgi-bin/paper?S1600536813017522. 
  4. ↑ Christensen, A. Nørlund; Hazell, R. G.; Larsen, Mogens; Thorup, Niels; Lönnberg, Harri; Yan, Shi-Ping; Wang, Geng-Lin; Yao, Xin-Kan et al. (1999). "X-Ray Crystallographic Study and Thermogravimetric Analysis of Tetrammine-Carbonatocobalt(III) Nitrate Hemihydrate, [Co(NH3)4CO3]NO3.0.5H2O." (in en). Acta Chemica Scandinavica 53: 399–402. doi:10.3891/acta.chem.scand.53-0399. ISSN 0904-213X. 
  5. ↑ Schlessinger, G.; Simmons, John W.; Jabs, Gerhardt; Chamberlain, Mark M. (January 1960). "Carbonatotetramminecobalt(III) Nitrate" (in en). Inorganic Syntheses. 6. Wiley. pp. 173–175. doi:10.1002/9780470132371.ch55. ISBN 978-0-470-13165-7. 
  6. ↑ Bernal, Ivan; Cetrullo, James (1990). "The phenomenon of conglomerate crystallization. XVIII. Clavic dissymmetry in coordination compounds. XVI: The crystal structure of racemic {[Co(NH3)4(CO3)NO3}2•H2O"] (in en). Structural Chemistry 1 (2–3): 227–234. doi:10.1007/BF00674266. ISSN 1040-0400. http://link.springer.com/10.1007/BF00674266. 
  7. ↑ Wu, Hongxiang; Zhu, Jianghai; Ma, Lidun; Shen, Xiaoliang; Shi, Guoshun (March 1998). "Powder diffraction of [ Co ( NH 3 ) 5 CO 3 NO 3 ·1/2 H 2 O and [ Co ( NH 3 ) 4 CO 3 ] NO 3 ·1/2 H 2 O"] (in en). Powder Diffraction 13 (1): 32–34. doi:10.1017/S0885715600009726. ISSN 0885-7156. https://www.cambridge.org/core/product/identifier/S0885715600009726/type/journal_article. 
  8. ↑ Zhu, J.H.; Wu, H.X.; Le Bail, A. (January 1999). "Structure of [Co(NH3)5CO3NO3·H2O"] (in en). Solid State Sciences 1 (1): 55–62. doi:10.1016/S1293-2558(00)80064-3. https://linkinghub.elsevier.com/retrieve/pii/S1293255800800643. 
  9. ↑ Le Bail, Armel (2013-07-15). "Tetraammine(carbonato-κ 2 O , O ′)cobalt(III) nitrate: a powder X-ray diffraction study". Acta Crystallographica Section E: Structure Reports Online 69 (7): i42–i43. doi:10.1107/S1600536813017522. ISSN 1600-5368. PMID 24046543. PMC 3772400. https://scripts.iucr.org/cgi-bin/paper?S1600536813017522. 
  10. ↑ Junk, Peter C.; Steed, Jonathan W. (December 1999). "Syntheses and X-ray crystal structures of [Co(η2-CO3)(NH3)4(NO3)·0.5H2O and [(NH3)3Co(μ-OH)2(μ-CO3)Co(NH3)3][NO3]2·H2O"] (in en). Polyhedron 18 (27): 3593–3597. doi:10.1016/S0277-5387(99)00293-4. https://linkinghub.elsevier.com/retrieve/pii/S0277538799002934. 
  11. ↑ Niederhoffer, Eric C.; Martell, Arthur E.; Rudolf, Phil; Clearfield, Abraham (October 1982). "Structures of (carbonato)bis(2,2'-bipyridine)cobalt(III) and (carbonato)bis(1,10-phenanthroline)cobalt(III) complexes" (in en). Inorganic Chemistry 21 (10): 3734–3741. doi:10.1021/ic00140a028. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00140a028. 
  12. ↑ Cheng, Meng; Jin, Wenqi; Yang, Zhihua; Pan, Shilie (2022). "Large optical anisotropy-oriented construction of a carbonate-nitrate chloride compound as a potential ultraviolet birefringent material" (in en). Chemical Science 13 (45): 13482–13488. doi:10.1039/D2SC03771H. ISSN 2041-6520. PMID 36507155. 
  13. ↑ Hu, Zhaowei; Liu, Lili; Zhang, Ruixin; Jing, Qun; Wang, Huan; Tian, Jindan; Xu, Jiayue; Halasyamani, P. Shiv (2023). "An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 2− and [NO 3 ] − triangles"] (in en). Journal of Materials Chemistry C 11 (9): 3325–3333. doi:10.1039/D2TC05374H. ISSN 2050-7526. http://xlink.rsc.org/?DOI=D2TC05374H. 
  14. ↑ Hervieu, M.; Michel, C.; Raveau, B. (1993-08-01). "New extended defects in the superconductive "123" yttrium calcium barium copper oxycarbonitrate YCaBa4Cu5(NO3)x(CO3)1-xO11: HREM study" (in en). Chemistry of Materials 5 (8): 1126–1132. doi:10.1021/cm00032a016. ISSN 0897-4756. https://pubs.acs.org/doi/abs/10.1021/cm00032a016. 
  15. ↑ 15.0 15.1 Tang, Xiao-Liang; Wang, Wen-Hua; Dou, Wei; Jiang, Jie; Liu, Wei-Sheng; Qin, Wen-Wu; Zhang, Guo-Lin; Zhang, Hong-Rui et al. (2009-04-27). "Olive-Shaped Chiral Supramolecules: Simultaneous Self-Assembly of Heptameric Lanthanum Clusters and Carbon Dioxide Fixation" (in en). Angewandte Chemie International Edition 48 (19): 3499–3502. doi:10.1002/anie.200900838. ISSN 1433-7851. PMID 19353611. https://onlinelibrary.wiley.com/doi/10.1002/anie.200900838. 
  16. ↑ 16.0 16.1 16.2 16.3 Pavlishchuk, A.; Naumova, D.; Zeller, M.; Calderon Cazorla, S.; Addison, A. W. (2019-08-01). "The crystal structures of {LnCu5}3+ (Ln = Gd, Dy and Ho) 15-metallacrown-5 complexes and a reevaluation of the isotypic EuIII analogue" (in en). Acta Crystallographica Section E: Crystallographic Communications 75 (8): 1215–1223. doi:10.1107/S205698901900999X. ISSN 2056-9890. PMID 31417795. PMC 6690475. https://journals.iucr.org/e/issues/2019/08/00/cq2031/. 
  17. ↑ Mahtani, Hans K.; Chang, Shih Chi; Ruble, John R.; Black, Iona N. L.; Stein, Paul B. (October 1993). "Novel crystal structure of a tetranuclear platinum complex: bis(.mu.4-carbonato-O,O,O',O')-tetrakis(diammineplatinum(II)) tetranitrate trihydrate" (in en). Inorganic Chemistry 32 (22): 4976–4978. doi:10.1021/ic00074a053. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00074a053. 
  18. ↑ Barnabé, A.; Letouzé, F.; Pelloquin, D.; Maignan, A.; Hervieu, M.; Raveau, B. (1997-10-01). "A New Superconducting Oxycarbonitrate: (Tl 5/6 Cr 1/6 )Sr 4 Cu 2 (CO 3 ) 1/2 (NO 3 ) 1/2 O 7" (in en). Chemistry of Materials 9 (10): 2205–2211. doi:10.1021/cm970370v. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm970370v. 
  19. ↑ Li, Yaping; Krivovichev, Sergey V.; Burns, Peter C. (2000-09-01). "Crystal Chemistry of Lead Oxide Hydroxide Nitrates I. The Crystal Structure of [Pb6O4(OH)(NO3)(CO3)"]. Journal of Solid State Chemistry 153 (2): 365–370. doi:10.1006/jssc.2000.8784. ISSN 0022-4596. https://www.sciencedirect.com/science/article/pii/S002245960098784X. 


Carbonates
H2CO3 He
Li2CO3,
LiHCO3 		BeCO3 B C (NH4)2CO3,
NH4HCO3 		O F Ne
Na2CO3,
NaHCO3,
Na3H(CO3)2 		MgCO3,
Mg(HCO3)2 		Al2(CO3)3 Si P S Cl Ar
K2CO3,
KHCO3 		CaCO3,
Ca(HCO3)2 		Sc Ti V Cr MnCO3 FeCO3 CoCO3 NiCO3 CuCO3 ZnCO3 Ga Ge As Se Br Kr
Rb2CO3 SrCO3 Y Zr Nb Mo Tc Ru Rh Pd Ag2CO3 CdCO3 In Sn Sb Te I Xe
Cs2CO3,
CsHCO3 		BaCO3   Hf Ta W Re Os Ir Pt Au Hg Tl2CO3 PbCO3 (BiO)2CO3 Po At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La2(CO3)3 Ce2(CO3)3 Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UO2CO3 Np Pu Am Cm Bk Cf Es Fm Md No Lr
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 C NO−3,
NH4NO3 		O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3,
Fe(NO3)2 		Co(NO3)2,
Co(NO3)3 		Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb(NO3)3 Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2 		Tl(NO3)3,
TlNO3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po At Rn
FrNO3 Ra(NO3)2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3,
Ce(NO3)4 		Pr Nd(NO3)3 Pm Sm Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy Ho Er Tm Yb Lu
Ac(NO3)3 Th(NO3)4 Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr



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