Deuterated DMF

{{chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 399893060 | ImageFile = DMF-d7.png | ImageFile_Ref = | ImageSize = 100 | ImageName = Skeletal formula of deuterated DMF | ImageFileL1 = DMF-3D-balls.png | ImageFileL1_Ref = | ImageNameL1 = Ball and stick model of deuterated DMF | ImageFileR1 = DMF-3D-vdW.png | ImageFileR1_Ref = | ImageNameR1 = Spacefill model of deuterated DMF

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Dimethylformamide-d₇^{[citation needed]}
N,N-Dimethylformamide-d₇
Heptadeutero-N,N-dimethylformamide^{[citation needed]}

Deuterated dimethylformamide ((CD₃)₂NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH₃)₂NCOH) in which the hydrogen atom ("H") is replaced with a deuterium isotope ("D"). Deuterated DMF is a relatively uncommon solvent used in NMR spectroscopy.^[1]^[2]

References

↑ Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation" (in en). Macromolecules 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297. https://pubs.acs.org/doi/10.1021/ma951127p.
↑ Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution" (in en). New Journal of Chemistry 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. https://pubs.rsc.org/en/content/articlelanding/2019/nj/c9nj00899c.

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[1] Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation" (in en). Macromolecules 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297. https://pubs.acs.org/doi/10.1021/ma951127p.

[2] Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution" (in en). New Journal of Chemistry 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. https://pubs.rsc.org/en/content/articlelanding/2019/nj/c9nj00899c.

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[2]

v t e Deuterated NMR Solvents
Deuterated	Deuterated acetone - (CD₃)₂C=O Deuterated benzene - C₆D₆ Deuterated chloroform - CDCl₃ Deuterated dichloromethane - CD₂Cl₂ Deuterated DMF - (CD₃)₂NCOD Deuterated DMSO - (CD₃)₂S=O Deuterated ethanol - C₂D₅OD Deuterated methanol - CD₃OD Deuterated THF - (C₄D₈)O Deuterated water - D₂O
Reference 1H and 13C chemical shifts

Deuterated DMF

Topic: Chemistry

References