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Iodate nitrate

Topic: Chemistry

 From HandWiki - Reading time: 4 min

Iodate nitrates are mixed anion compounds that contain both iodate and nitrate anions.

Giant birefringence

Iodate nitrates can have high birefringence. The scandium salt has a giant birefringence of 0.348 at 546 nm. When discovered in 2021 it was a record high birefringence for oxyanion compounds, but it was exceeded by CeF2(SO4) just a month later with a value of 0.361[1] and sodium hydrogen squarate hydrate, NaHC4O4·H2O with a value of 0.52 at 1064 nm.[2] All of these are beaten by hexagonal boron nitride (h-BN) with birefringence of 0.7 in visible light.[3]

List

formula name formula

weight

system space group cell Å volume density comments ref
Al(IO3)2NO3•6H2O aluminium diiodate nitrate hexahydrate hexagonal P321 a=6.764 c=8.09 Z=1 [4]
KIO3•KNO3•2HIO3 dipotassium dihydrogen triiodate nitrate orthorhombic P212121 a=7.109 b=10.638 c=15.5 [5]
Sc(IO3)2(NO3) scandium diiodate nitrate 1370.31 trigonal R32 a=5.3536 c=23.567 Z=1 584.96 3.890 colourless; giant birefringence 0.348 at 546 nm; SHG 4.0×KDP; UV edge 298 nm; stable to 360°C [6]
In(IO3)2(NO3) indium diiodate nitrate 526.63 trigonal R32 a=5.2165 c=24.195, γ=120° Z=3 570.2 4.601 colourless [7]
[In(IO3)(OH)(H2O)](NO3) 386.75 monoclinic P21/n a=5.5756 b=16.410 c=7.734, β=109.95 Z=4 665.2 3.862 colourless [7]
La(IO3)2(NO3) lanthanum diiodate nitrate trigonal P3121 a=7.1002 c=38.177 Z=9 SHG 0.6 × KDP; band gap 4.23 eV [8]
Ce(IO3)2(NO3) cerium diiodate nitrate 551.93 trigonal P3121 a=7.0537 c=37.972 Z=9 1639.8 5.030 SHG 1 × KDP [9]
α-Th(IO3)2(NO3)(OH) triclinic P1 a=6.9581 b=7.2294 c=9.8989 α=68.896° β=88.759° γ=66.620° [10]
β-Th(IO3)2(NO3)(OH) orthorhombic Pbca a=7.1459 b=14.140 c=16.612 [10]

References

  1. ↑ Wu, Chao; Wu, Tianhui; Jiang, Xingxing; Wang, Zujian; Sha, Hongyuan; Lin, Lin; Lin, Zheshuai; Huang, Zhipeng et al. (2021-03-24). "Large Second-Harmonic Response and Giant Birefringence of CeF 2 (SO 4 ) Induced by Highly Polarizable Polyhedra" (in en). Journal of the American Chemical Society 143 (11): 4138–4142. doi:10.1021/jacs.1c00416. ISSN 0002-7863. PMID 33625206. Bibcode: 2021JAChS.143.4138W. https://pubs.acs.org/doi/10.1021/jacs.1c00416. 
  2. ↑ Zhang, Xiaodong; Cao, Dongxu; Yang, Daqing; Wang, Ying; Wu, Kui; Lee, Ming-Hsien; Zhang, Bingbing (2022-04-04). "Finding the First Squarates Nonlinear Optical Crystal NaHC 4 O 4 ·H 2 O with Strong Second Harmonic Generation and Giant Birefringence" (in en). ACS Materials Letters 4 (4): 572–576. doi:10.1021/acsmaterialslett.2c00114. ISSN 2639-4979. https://pubs.acs.org/doi/10.1021/acsmaterialslett.2c00114. 
  3. ↑ Segura, A.; Artús, L.; Cuscó, R.; Taniguchi, T.; Cassabois, G.; Gil, B. (6 February 2018). "Natural optical anisotropy of h-BN: Highest giant birefringence in a bulk crystal through the mid-infrared to ultraviolet range". Physical Review Materials 2 (2). doi:10.1103/PhysRevMaterials.2.024001. Bibcode: 2018PhRvM...2b4001S. 
  4. ↑ Cradwick, Peter D.; de Endredy, Andrew S. (1975). "Crystal structure of aluminium iodate nitrate hexahydrate" (in en). Journal of the Chemical Society, Dalton Transactions (19): 1926–1929. doi:10.1039/dt9750001926. ISSN 0300-9246. http://xlink.rsc.org/?DOI=dt9750001926. 
  5. ↑ Kalinin, V.R.; Ilyukhin, V.V.; Belov, N.V. (1978). "Crystal structure of acid mixed potassium iodate-nitrate KIO3xKNO3x2HIO3" (in Russian). Doklady Akademii Nauk SSSR 239 (6). https://inis.iaea.org/search/search.aspx?orig_q=RN:10454338. 
  6. ↑ Wu, Chao; Jiang, Xingxing; Wang, Zujian; Lin, Lin; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G. et al. (2021-02-15). "Giant Optical Anisotropy in the UV-Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )" (in en). Angewandte Chemie International Edition 60 (7): 3464–3468. doi:10.1002/anie.202012456. ISSN 1433-7851. PMID 33146456. Bibcode: 2021ACIE...60.3464W. https://onlinelibrary.wiley.com/doi/10.1002/anie.202012456. 
  7. ↑ 7.0 7.1 Huang, Yu; Jiang, Ting-kun; Yang, Bing-Ping; Hu, Chun-Li; Fang, Zhi; Mao, Jiang-Gao (2022-02-14). "Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements" (in en). Inorganic Chemistry 61 (8): 3374–3378. doi:10.1021/acs.inorgchem.2c00079. ISSN 0020-1669. PMID 35156368. https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00079. 
  8. ↑ Mao, Fei-Fei; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2017-11-20). "Acentric La 3 (IO 3 ) 8 (OH) and La(IO 3 ) 2 (NO 3 ): Partial Substitution of Iodate Anions in La(IO 3 ) 3 by Hydroxide or Nitrate Anion" (in en). Inorganic Chemistry 56 (22): 14357–14365. doi:10.1021/acs.inorgchem.7b02508. ISSN 0020-1669. PMID 29120615. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02508. 
  9. ↑ Ma, Nan; Huang, Yu; Hu, Chun-Li; Zhang, Ming-Zhi; Li, Bing-Xuan; Mao, Jiang-Gao (2023-09-07). "Ce(IO 3 ) 3 F and Ce(IO 3 ) 2 (NO 3 ): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties" (in en). Inorganic Chemistry 62 (37): 15329–15333. doi:10.1021/acs.inorgchem.3c02651. ISSN 0020-1669. PMID 37677152. https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c02651. 
  10. ↑ 10.0 10.1 Wang, Yaxing; Duan, Tao; Weng, Zhehui; Ling, Jie; Yin, Xuemiao; Chen, Lanhua; Sheng, Daopeng; Diwu, Juan et al. (2017-11-06). "Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds" (in en). Inorganic Chemistry 56 (21): 13041–13050. doi:10.1021/acs.inorgchem.7b01855. ISSN 0020-1669. PMID 28991439. https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01855. 

Template:Iodates

Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 C NO−3,
NH4NO3 		O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3,
Fe(NO3)2 		Co(NO3)2,
Co(NO3)3 		Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb(NO3)3 Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2 		Tl(NO3)3,
TlNO3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po At Rn
FrNO3 Ra(NO3)2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3,
Ce(NO3)4 		Pr Nd(NO3)3 Pm Sm Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy Ho Er Tm Yb Lu
Ac(NO3)3 Th(NO3)4 Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr



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