Iridium disulfide

Iridium disulfide
Identifiers
CAS Number	12030-51-2;
3D model (JSmol)	Interactive image;
ChemSpider	103869853;
PubChem CID	154116933;
	InChI InChI=1S/Ir.2S Key: DUFDGYWNCWKJSM-UHFFFAOYSA-N;
	SMILES [S]=[Ir]=[S];
Properties
Chemical formula	IrS2
Molar mass	256.349
Density	9300 kg m–3
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Iridium disulfide is the binary inorganic compound with the formula IrS₂. Prepared by the direct reaction of the elements, the compound adopts the pyrite crystal structure at high pressure.^[1] At normal atmospheric pressures, an orthorhombic polymorph is observed.^[2]. The high- and low-pressure forms both feature octahedral Ir centers, but the S–S distances are pressure dependent.^[3] Although not practical, IrS₂ is a highly active catalyst for hydrodesulfurization.^[4]

References

↑ "The synthesis of iridium disulfide and nickel diarsenide having the pyrite structure". Inorganic Chemistry 7 (2): 389–390. February 1968. doi:10.1021/ic50060a047. https://htracyhall.org/ocr/HTH-Archives/Cabinet%208/Drawer%203%20(MATI%20-%20MOZ)/(Munson,%20R.A.)%20(Muntoni,%20C.)%20(Murase,%20K.)%20(linked)/(Munson,%20R.A.)%20(Muntoni,%20C.)%20(Murase,%20K.)-237_OCR.pdf. Retrieved 2019-01-19.
↑ "Properties of the transition metal dichalcogenides: the case of IrS₂ and IrSe₂". Journal of Solid State Chemistry 89 (2): 315–327. 1990. doi:10.1016/0022-4596(90)90273-Z. Bibcode: 1990JSSCh..89..315J.
↑ Mineral chemistry of metal sulfides. Cambridge Earth Science Series. Cambridge: Cambridge University Press. 1978. ISBN 0521214890.
↑ "Periodic trends in hydrodesulfurization: in support of the Sabatier principle". Applied Catalysis A: General 227 (1–2): 83–96. 8 March 2002. doi:10.1016/S0926-860X(01)00924-3.

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[Munson-1968-1] "The synthesis of iridium disulfide and nickel diarsenide having the pyrite structure". Inorganic Chemistry 7 (2): 389–390. February 1968. doi:10.1021/ic50060a047. https://htracyhall.org/ocr/HTH-Archives/Cabinet%208/Drawer%203%20(MATI%20-%20MOZ)/(Munson,%20R.A.)%20(Muntoni,%20C.)%20(Murase,%20K.)%20(linked)/(Munson,%20R.A.)%20(Muntoni,%20C.)%20(Murase,%20K.)-237_OCR.pdf. Retrieved 2019-01-19.

[Rouxel-2] "Properties of the transition metal dichalcogenides: the case of IrS₂ and IrSe₂". Journal of Solid State Chemistry 89 (2): 315–327. 1990. doi:10.1016/0022-4596(90)90273-Z. Bibcode: 1990JSSCh..89..315J.

[Vaughan-and-Craig-1978-3] Mineral chemistry of metal sulfides. Cambridge Earth Science Series. Cambridge: Cambridge University Press. 1978. ISBN 0521214890.

[Chianelli-Berhault-Raybaud-et-al-2002-4] "Periodic trends in hydrodesulfurization: in support of the Sabatier principle". Applied Catalysis A: General 227 (1–2): 83–96. 8 March 2002. doi:10.1016/S0926-860X(01)00924-3.

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Identifiers

CAS Number	12030-51-2
3D model (JSmol)	Interactive image
ChemSpider	103869853
PubChem CID	154116933
InChI InChI=1S/Ir.2S Key: DUFDGYWNCWKJSM-UHFFFAOYSA-N
SMILES [S]=[Ir]=[S]
Properties
Chemical formula	IrS₂
Molar mass	256.349
Density	9300 kg m^–3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Iridium disulfide

Topic: Chemistry

References