Lanthanum decahydride is a polyhydride or superhydride compound of lanthanum and hydrogen (LaH10) that has shown evidence of being a high-temperature superconductor. It was the first metal superhydride to be theoretically predicted[3][4], synthesized [5], and experimentally confirmed[6] to superconduct at near room-temperatures. It has a superconducting transition temperature TC around 250 K (−23 °C; −10 °F) at a pressure of 150 gigapascals (22×10^6 psi), and its synthesis required pressures above approximately 160 gigapascals (23×10^6 psi).[7][8]
Synopsis
Since its discovery, the superconducting properties of LaH10 and other lanthanum-based superhydrides have been experimentally confirmed in multiple independent experiments[9][10][11][12]. The compound exhibits a Meissner effect below the superconducting transition temperature.[13] A cubic form can be synthesized at 1,000 K (730 °C; 1,340 °F),[7] and a hexagonal crystal structure can be formed at room temperature.[14] Further reports indicate Tc is increased with nitrogen doping [15], and decreased with the introduction of magnetic impurities [16].
The cubic form has each lanthanum atom surrounded by 32 hydrogen atoms, which form the vertices of an 18-faced shape called a chamfered cube.[17]
A similar compound, lanthanum boron octahydride, was computationally predicted to be a superconductor at 126 K (−147 °C; −233 °F) and pressure 50 gigapascals (7.3×10^6 psi).[18]
↑ 7.07.1Drozdov, A. P.; Kong, P. P.; Minkov, V. S.; Besedin, S. P.; Kuzovnikov, M. A.; Mozaffari, S.; Balicas, L.; Balakirev, F. F. et al. (2019). "Superconductivity at 250 K in lanthanum hydride under high pressures". Nature569 (7757): 528–531. doi:10.1038/s41586-019-1201-8. PMID31118520. Bibcode: 2019Natur.569..528D.
↑Eremets, M. I.; Minkov, V. S.; Drozdov, A. P.; Kong, P. P.; Ksenofontov, V.; Shylin, S. I.; Bud'ko, S. L.; Prozorov, R. et al. (10 January 2022). "High‑Temperature Superconductivity in Hydrides: Experimental Evidence and Details". Journal of Superconductivity and Novel Magnetism35 (4): 965–977. doi:10.1007/s10948-022-06148-1.
↑Geballe, Zachary M.; Liu, Hanyu; Mishra, Ajay K.; Ahart, Muhtar; Somayazulu, Maddury; Meng, Yue; Baldini, Maria; Hemley, Russell J. (15 January 2018). "Synthesis and Stability of Lanthanum Superhydrides". Angewandte Chemie International Edition57 (3): 688–692. doi:10.1002/anie.201709970. PMID29193506.