Magnesium ozonide

Magnesium ozonide
Identifiers
CAS Number	63172-13-4 (MgO3) ; (Mg(O3)2): 1252008-65-3 ;
3D model (JSmol)	Interactive image; Interactive image; (Mg(O3)2): Interactive image;
PubChem CID	18673469; (Mg(O3)2): 161960612;
	InChI InChI=1S/Mg.H2O3/c;1-3-2/h;1-2H/q+2;/p-2 Key: LMFHOIDEQKLFKI-UHFFFAOYSA-L; InChI=1S/Mg.HO3/c;1-3-2/h;1H/q+1;/p-1 Key: RBFCWJLHCQDAGO-UHFFFAOYSA-M; (Mg(O3)2): InChI=1S/Mg.H2O6/c;1-3-5-6-4-2/h;1-2H/q+2;/p-2 Key: YNAZEDCTBGQCLV-UHFFFAOYSA-L;
	SMILES [O-]O[O-].[Mg+2]; [Mg+].[O-]O[O]; (Mg(O3)2): [O-]OOOO[O-].[Mg+2];
Properties
Chemical formula	MgO3
Molar mass	72.302 g·mol−1
Appearance	White solid
Related compounds
Other cations	Potassium ozonide, Ammonium ozonide
Related compounds	Magnesium oxide
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Magnesium ozonide is a compound with the formula Mg O₃. Much like other ozonides, it is only stable at low temperatures.^[1] Unlike other ozonide compounds, magnesium ozonide is white rather than the typical red colour.^[2]

Preparation

Magnesium ozonide can be made by passing a dilute mixture of ozone in liquid nitrogen and over magnesium at -259 °C:^[1]

O
3 + Mg → MgO
3

Magnesium bisozonide

Magnesium is also known to form bisozonide complexes, containing Mg(O₃)₂ complexed with argon or carbon monoxide, in an argon matrix.^[3]

References

↑ ^1.0 ^1.1 Andrews, Lester; Prochaska, Eleanor S.; Ault, Bruce S. (1978-07-15). "Matrix reactions of magnesium atoms with ozone. Infrared spectra of MgO, MgO₂, and MgO₃ in solid nitrogen" (in en). The Journal of Chemical Physics 69 (2): 556–563. doi:10.1063/1.436646. ISSN 0021-9606. Bibcode: 1978JChPh..69..556A.
↑ Vol’nov, Il’ya Ivanovich (1966). Petrocelli, A. W.. ed (in en). Peroxides, Superoxides, and Ozonides of Alkali and Alkaline Earth Metals. Boston, MA: Springer US. doi:10.1007/978-1-4684-8252-2. ISBN 978-1-4684-8254-6. http://link.springer.com/10.1007/978-1-4684-8252-2.
↑ Wang, Guanjun; Gong, Yu; Zhang, Qingqing; Zhou, Mingfei (2010). "Formation and Characterization of Magnesium Bisozonide and Carbonyl Complexes in Solid Argon". Journal of Physical Chemistry A 114 (40): 10803–10809. doi:10.1021/jp107434f. PMID 20857987. Bibcode: 2010JPCA..11410803W.

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[:0-1] 1.0 ^1.1 Andrews, Lester; Prochaska, Eleanor S.; Ault, Bruce S. (1978-07-15). "Matrix reactions of magnesium atoms with ozone. Infrared spectra of MgO, MgO₂, and MgO₃ in solid nitrogen" (in en). The Journal of Chemical Physics 69 (2): 556–563. doi:10.1063/1.436646. ISSN 0021-9606. Bibcode: 1978JChPh..69..556A.

[2] Vol’nov, Il’ya Ivanovich (1966). Petrocelli, A. W.. ed (in en). Peroxides, Superoxides, and Ozonides of Alkali and Alkaline Earth Metals. Boston, MA: Springer US. doi:10.1007/978-1-4684-8252-2. ISBN 978-1-4684-8254-6. http://link.springer.com/10.1007/978-1-4684-8252-2.

[3] Wang, Guanjun; Gong, Yu; Zhang, Qingqing; Zhou, Mingfei (2010). "Formation and Characterization of Magnesium Bisozonide and Carbonyl Complexes in Solid Argon". Journal of Physical Chemistry A 114 (40): 10803–10809. doi:10.1021/jp107434f. PMID 20857987. Bibcode: 2010JPCA..11410803W.

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Identifiers

CAS Number	63172-13-4 (MgO₃)^Y (Mg(O₃)₂): 1252008-65-3^Y
3D model (JSmol)	Interactive image Interactive image (Mg(O₃)₂): Interactive image
PubChem CID	18673469 (Mg(O₃)₂): 161960612
InChI InChI=1S/Mg.H2O3/c;1-3-2/h;1-2H/q+2;/p-2 Key: LMFHOIDEQKLFKI-UHFFFAOYSA-L InChI=1S/Mg.HO3/c;1-3-2/h;1H/q+1;/p-1 Key: RBFCWJLHCQDAGO-UHFFFAOYSA-M (Mg(O₃)₂): InChI=1S/Mg.H2O6/c;1-3-5-6-4-2/h;1-2H/q+2;/p-2 Key: YNAZEDCTBGQCLV-UHFFFAOYSA-L
SMILES [O-]O[O-].[Mg+2] [Mg+].[O-]O[O] (Mg(O₃)₂): [O-]OOOO[O-].[Mg+2]
Properties
Chemical formula	MgO₃
Molar mass	72.302 g·mol⁻¹
Appearance	White solid
Related compounds
Other cations	Potassium ozonide, Ammonium ozonide
Related compounds	Magnesium oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Magnesium ozonide

Topic: Chemistry

Preparation

Magnesium bisozonide

References