Naphthalene-2-sulfonic acid

Naphthalene-2-sulfonic acid

Names
Preferred IUPAC name Naphthalene-2-sulfonic acid
Other names 2-Naphthalenesulfonic acid
Identifiers
CAS Number	120-18-3
3D model (JSmol)	Interactive image
Beilstein Reference	1955756
ChEMBL	ChEMBL1234624
ChemSpider	8113
EC Number	204-375-3
PubChem CID	8420
UNII	O9S4K2S25E
InChI InChI=1S/C10H8O3S/c11-14(12,13)10-6-5-8-3-1-2-4-9(8)7-10/h1-7H,(H,11,12,13) Key: KVBGVZZKJNLNJU-UHFFFAOYSA-N
SMILES C1=CC=C2C=C(C=CC2=C1)S(=O)(=O)O
Properties
Chemical formula	C10H8O3S
Molar mass	208.23 g·mol−1 (anhydrous)
Appearance	White solid
Melting point	124 °C (255 °F; 397 K) (monohydrate)
Solubility in water	good
Hazards
GHS pictograms
GHS Signal word	Danger
GHS hazard statements	H302, H314
GHS precautionary statements	P260, P264, P270, P280, P301+312, P301+330+331, P303+361+353, P304+340, P305+351+338, P310, P321, P330, P363, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Naphthalene-2-sulfonic acid is an organic compound with the formula C₁₀H₇SO₃H. A colorless, water-soluble solid, it is often available as the mono- and trihydrates C₁₀H₇SO₃H^.2H₂O. It is one of two monosulfonic acids of naphthalene, the other being naphthalene-1-sulfonic acid. The compound is mainly used in the production of dyes via nitration en route to aminonaphthalenesulfonic acids. The compound is prepared by sulfonation of naphthalene with sulfuric acid, however under equilibrating conditions that allow the 1-sulfonic acid isomer to convert to the more stable 2-sulfonic acid.^[1]

Naphthalene-2-sulfonic acid undergoes many reactions, some of which are or were of commercial interest. Fusion with sodium hydroxide followed by acidification gives 2-naphthol. It is an intermediate in the formation of 2,6-, 2,7- and 1,6-naphthalene disulfonic acids as well as 1,3,6-naphthalenetrisulfonic acid. Naphthalene-2-sulfonic acid condenses with formaldehyde to give polymeric sulfonic acids.^[1]

References

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