Neodymium tantalate

Neodymium tantalate
	; The structure of Neodymium tanatalate. Atoms are: O(red), Ta(blue) and Nd(green)
Identifiers
CAS Number	12344-26-2 ;
3D model (JSmol)	Interactive image;
PubChem CID	157362626;
	InChI InChI=1S/Nd.4O.Ta/q+3;4*-2;+5 Key: BIUUBSDKMPQKED-UHFFFAOYSA-N;
	SMILES [O-2].[O-2].[O-2].[O-2].[Nd+3].[Ta+5];
Properties
Chemical formula	NdTaO4
Molar mass	389.19
Appearance	gray-purple solid
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Neodymium tantalate is an inorganic compound with the chemical formula NdTaO₄. It is prepared by reacting neodymium oxide and tantalum pentoxide at 1200 °C.^[1] It reacts with a mixture of tantalum pentoxide and chlorine gas at high temperature to obtain Nd₂Ta₂O₇Cl₂.^[2] It is ammonolyzed at high temperature to obtain oxynitrides of Nd-Ta.^[3]

Properties

Neodymium tantalate forms violet crystals of the monoclinic system, with space group I2/a, unit cell dimensions a = 0.55153 nm, b = 1.12388 nm, c = 0.51184 nm, β = 95.731°, with formulas per unit cell Z = 4.^[4]

There is a metastable high-pressure phase of the monoclinic system, space group P2₁/c, cell parameters a = 0.75920 nm, b = 0.54673 nm, c = 0.77022 nm, β = 100.032°, Z = 4.^[5]

References

↑ ^1.0 ^1.1 Krylov, E. I.; Strelina, M. M. Praseodymium and neodymium orthotantalates. Zhurnal Neorganicheskoi Khimii, 1961. 6: 235-235. ISSN 0044-457X.
↑ U. Schaffrath, R. Gruehn (1988-12-01). "Nd7,33Ta8O28CI6 — ein Zwischenprodukt des thermischen Abbaus von Nd₂Ta₂O₇Cl₂: Präparation, Struktur und magnetische Eigenschaften / Nd_7,33Ta₈O₂₈Cl₆ — an Intermediate Product of the Thermal Decomposition of Nd₂Ta₂O₇Cl₂: Preparation, Crystal Structure and Magnetic Properties". Zeitschrift für Naturforschung B 43 (12): 1567–1574. doi:10.1515/znb-1988-1208. ISSN 1865-7117.
↑ Pascal Maillard, Franck Tessier, Emmanuelle Orhan, François Cheviré, Roger Marchand (January 2005). "Thermal Ammonolysis Study of the Rare-Earth Tantalates RTaO₄" (in en). Chemistry of Materials 17 (1): 152–156. doi:10.1021/cm040131p. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm040131p. Retrieved 2021-06-06.
↑ Kaijie Ning, Qingli Zhang, Deming Zhang, Jintai Fan, Dunlu Sun, Xiaofei Wang, Yin Hang (2014). "Crystal growth, characterization of NdTaO₄: A new promising stoichiometric neodymium laser material". Journal of Crystal Growth 388: 83–86. doi:10.1016/j.jcrysgro.2013.10.030. Bibcode: 2014JCrGr.388...83N.
↑ Titov Yu. A., Sych A. M., Sokolov A. N., Kapshuk A. A., Markiv V. Ya., Belyavina N. M. (2000). Crystal structure of the high-pressure modification of NdTaO₄. 311 (Journal of alloys and compounds ed.). pp. 252–255. http://cat.inist.fr/?aModele=afficheN&cpsidt=1506065.

External links

Patrick N. Walsh, Harold W. Goldstein, David White (May 1960). "Vaporization of Rare-Earth Oxides" (in en). Journal of the American Ceramic Society 43 (5): 229–233. doi:10.1111/j.1151-2916.1960.tb14589.x. ISSN 0002-7820. http://doi.wiley.com/10.1111/j.1151-2916.1960.tb14589.x. Retrieved 2021-06-06.

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Original source: https://en.wikipedia.org/wiki/Neodymium tantalate. Read more

[Krylov-1] 1.0 ^1.1 Krylov, E. I.; Strelina, M. M. Praseodymium and neodymium orthotantalates. Zhurnal Neorganicheskoi Khimii, 1961. 6: 235-235. ISSN 0044-457X.

[2] U. Schaffrath, R. Gruehn (1988-12-01). "Nd7,33Ta8O28CI6 — ein Zwischenprodukt des thermischen Abbaus von Nd₂Ta₂O₇Cl₂: Präparation, Struktur und magnetische Eigenschaften / Nd_7,33Ta₈O₂₈Cl₆ — an Intermediate Product of the Thermal Decomposition of Nd₂Ta₂O₇Cl₂: Preparation, Crystal Structure and Magnetic Properties". Zeitschrift für Naturforschung B 43 (12): 1567–1574. doi:10.1515/znb-1988-1208. ISSN 1865-7117.

[3] Pascal Maillard, Franck Tessier, Emmanuelle Orhan, François Cheviré, Roger Marchand (January 2005). "Thermal Ammonolysis Study of the Rare-Earth Tantalates RTaO₄" (in en). Chemistry of Materials 17 (1): 152–156. doi:10.1021/cm040131p. ISSN 0897-4756. https://pubs.acs.org/doi/10.1021/cm040131p. Retrieved 2021-06-06.

[4] Kaijie Ning, Qingli Zhang, Deming Zhang, Jintai Fan, Dunlu Sun, Xiaofei Wang, Yin Hang (2014). "Crystal growth, characterization of NdTaO₄: A new promising stoichiometric neodymium laser material". Journal of Crystal Growth 388: 83–86. doi:10.1016/j.jcrysgro.2013.10.030. Bibcode: 2014JCrGr.388...83N.

[5] Titov Yu. A., Sych A. M., Sokolov A. N., Kapshuk A. A., Markiv V. Ya., Belyavina N. M. (2000). Crystal structure of the high-pressure modification of NdTaO₄. 311 (Journal of alloys and compounds ed.). pp. 252–255. http://cat.inist.fr/?aModele=afficheN&cpsidt=1506065.

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Neodymium tantalate

Topic: Chemistry

Contents

Properties

See also

References

External links

Identifiers
The structure of Neodymium tanatalate. Atoms are: O(red), Ta(blue) and Nd(green)
CAS Number	12344-26-2^Y
3D model (JSmol)	Interactive image
PubChem CID	157362626
InChI InChI=1S/Nd.4O.Ta/q+3;4*-2;+5 Key: BIUUBSDKMPQKED-UHFFFAOYSA-N
SMILES [O-2].[O-2].[O-2].[O-2].[Nd+3].[Ta+5]
Properties
Chemical formula	NdTaO₄
Molar mass	389.19
Appearance	gray-purple solid^[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references