Radon hexafluoride

Radon hexafluoride
Names
	IUPAC name Radon hexafluoride
Identifiers
CAS Number	80948-45-4;
3D model (JSmol)	Interactive image;
ChemSpider	29333640;
	InChI InChI=1S/F6Rn/c1-7(2,3,4,5)6 Key: AONZSGXJYUJATR-UHFFFAOYSA-N;
	SMILES F[Rn](F)(F)(F)(F)F;
Properties
Chemical formula	F6Rn
Molar mass	336 g·mol−1
Related compounds
Related compounds	Xenon hexafluoride; Krypton hexafluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Radon hexafluoride is a binary chemical compound of radon and fluorine with the chemical formula RnF₆.^[1]^[2]^[3] This is still a hypothetical compound that has not been synthesized so far.

Potential properties

The compound is calculated to be less stable than radon difluoride. Radon hexafluoride is expected to have an octahedral molecular geometry, unlike the C_3v of xenon hexafluoride.^[4]^[5]

The Rn-F bonds in radon hexafluoride is predicted to be shorter and more stable compared to Xe-F bonds in xenon hexafluoride.^[5]

References

↑ "Relativistic Research - CATCO". s3.smu.edu. https://s3.smu.edu/dedman/catco/research/relativistic-34.html.
↑ Malli, G. L. (2001-03-12). "Relativistic all-electron Dirac–Fock calculations on RnF6 and its ions" (in en). Journal of Molecular Structure: THEOCHEM 537 (1): 71–77. doi:10.1016/S0166-1280(00)00663-1. ISSN 0166-1280. https://www.sciencedirect.com/science/article/pii/S0166128000006631.
↑ Filatov, Michael; Cremer, Dieter (27 February 2003). "Bonding in radon hexafluoride: An unusual relativistic problem?" (in en). Physical Chemistry Chemical Physics 5 (6): 1103–1105. doi:10.1039/B212460M. ISSN 1463-9084. Bibcode: 2003PCCP....5.1103F. https://pubs.rsc.org/en/content/articlelanding/2003/cp/b212460m. Retrieved 28 April 2023.
↑ Seppelt, Konrad (2015-01-28). "Molecular Hexafluorides" (in en). Chemical Reviews 115 (2): 1296–1306. doi:10.1021/cr5001783. ISSN 0009-2665. PMID 25418862. https://pubs.acs.org/doi/10.1021/cr5001783.
↑ ^5.0 ^5.1 Kang, Jaeeun; Park, Ina; Shim, Ji Hoon; Kim, Duck Young; Um, Wooyong (18 February 2023). "Prediction of stable radon fluoride molecules and geometry optimization using first-principles calculations" (in en). Scientific Reports 13 (1): 2898. doi:10.1038/s41598-023-29313-5. ISSN 2045-2322. PMID 36801928. Bibcode: 2023NatSR..13.2898K.

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[1] "Relativistic Research - CATCO". s3.smu.edu. https://s3.smu.edu/dedman/catco/research/relativistic-34.html.

[2] Malli, G. L. (2001-03-12). "Relativistic all-electron Dirac–Fock calculations on RnF6 and its ions" (in en). Journal of Molecular Structure: THEOCHEM 537 (1): 71–77. doi:10.1016/S0166-1280(00)00663-1. ISSN 0166-1280. https://www.sciencedirect.com/science/article/pii/S0166128000006631.

[3] Filatov, Michael; Cremer, Dieter (27 February 2003). "Bonding in radon hexafluoride: An unusual relativistic problem?" (in en). Physical Chemistry Chemical Physics 5 (6): 1103–1105. doi:10.1039/B212460M. ISSN 1463-9084. Bibcode: 2003PCCP....5.1103F. https://pubs.rsc.org/en/content/articlelanding/2003/cp/b212460m. Retrieved 28 April 2023.

[4] Seppelt, Konrad (2015-01-28). "Molecular Hexafluorides" (in en). Chemical Reviews 115 (2): 1296–1306. doi:10.1021/cr5001783. ISSN 0009-2665. PMID 25418862. https://pubs.acs.org/doi/10.1021/cr5001783.

[Kang-5] 5.0 ^5.1 Kang, Jaeeun; Park, Ina; Shim, Ji Hoon; Kim, Duck Young; Um, Wooyong (18 February 2023). "Prediction of stable radon fluoride molecules and geometry optimization using first-principles calculations" (in en). Scientific Reports 13 (1): 2898. doi:10.1038/s41598-023-29313-5. ISSN 2045-2322. PMID 36801928. Bibcode: 2023NatSR..13.2898K.

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Radon hexafluoride

Topic: Chemistry

Potential properties

References