Vanadium–gallium

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Short description: Superconducting alloy

Vanadium–gallium (V3Ga) is a superconducting alloy of vanadium and gallium. It is often used for the high field insert coils of superconducting electromagnets.[clarification needed][citation needed]

Vanadium–gallium tape is used in the highest field magnets (magnetic fields of 17.5 T). The structure of the superconducting A15 phase of V
3
Ga
is similar to that of the more common Nb
3
Sn
.[1]

In conditions where the magnetic field is higher than 8 T and the temperature is higher than 4.2 K, Nb
3
Sn
and V
3
Ga
see use.

The main property of V
3
Ga
that makes it so useful is that it can be used in magnetic fields up to about 18 T, while Nb
3
Sn
can only be used in fields up to about 15 T.[2]

The high field characteristics can be improved by doping with high-Z elements such as Nb, Ta, Sn, Pt and Pb.[3]

Physical Properties

Molecular Weight 222.55 g/mol
Melting Point 1720 °C
Highest magnetic field 18 T

[4]

V
3
Ga
has an A15 phase, which makes it extremely brittle. One must be extremely cautious not to over-bend the wire when handling it. [2]

Superconducting properties

  • Critical temperature (Tc): ~14.2 K[5]
  • Upper critical field (Hc2): over 19 T.

Fabrication of superconductive wires or tapes

V
3
Ga
wires can be formed using solid-state precipitation.[6]

History

References

  1. Markiewicz, W.; Mains, E.; Vankeuren, R.; Wilcox, R.; Rosner, C.; Inoue, H.; Hayashi, C.; Tachikawa, K. (1977). "A 17.5 Tesla superconducting concentric Nb3Sn and V3Ga magnet system". IEEE Transactions on Magnetics 13 (1): 35–37. doi:10.1109/TMAG.1977.1059431. Bibcode1977ITM....13...35M. 
  2. 2.0 2.1 Ekin, Jack W. (1983). "Superconductors". in Reed, Richard P.; Clark, Alan F.. Materials at Low Temperatures. Russell, OH: American Society for Metals. pp. 465–513. ISBN 978-1-62708-348-5. 
  3. Tedrow, P. M.; Meservy, R. (1984), "Improvement in magnetic field properties of vanadium–gallium superconductors by enhancement of spin-orbit scattering", MIT Report, Bibcode1984mit..reptR....T 
  4. "Vanadium Gallide". https://www.americanelements.com/vanadium-gallide-12024-15-6. 
  5. Decker, D. L. Laquer, H. L. (1969), "Magnetization Studies on Superconducting Vanadium‐Gallium", Journal of Applied Physics 40 (7): 2817–2822, doi:10.1063/1.1658081, Bibcode1969JAP....40.2817D, https://ieeexplore.ieee.org/document/5095068 
  6. Hong, Minghwei (1980), A15 superconductors through direct "solid-state" precipitation: V3Ga AND Nb3Al, http://www.escholarship.org/uc/item/995579gc 





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