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    Aluminium formate

    From Wikipedia - Reading time: 4 min
    Aluminium formate
    Names
    IUPAC name
    Aluminium triformate
    Identifiers
    CAS Number
    3D model (JSmol)
    ChemSpider
    ECHA InfoCard 100.028.089 Edit this at Wikidata
    PubChem CID
    UNII
    CompTox Dashboard (EPA)
    InChI
    • InChI=1S/3CH2O2.Al/c3*2-1-3;/h3*1H,(H,2,3);/q;;;+3/p-3
      Key: MJWPFSQVORELDX-UHFFFAOYSA-K
    • InChI=1/3CH2O2.Al/c3*2-1-3;/h3*1H,(H,2,3);/q;;;+3/p-3
      Key: MJWPFSQVORELDX-DFZHHIFOAF
    SMILES
    • [Al+3].[O-]C=O.[O-]C=O.[O-]C=O
    Properties
    Chemical formula
    		 C3H3AlO6
    Molar mass 162.033 g·mol−1
    Appearance White powder
    Solubility in water
    		 Insoluble
    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
    Infobox references

    Aluminium formate is the aluminium salt of formic acid, with the chemical formula Al(HCOO)3. It can be produced via the reaction of aluminium soaps and formic acid.[1] Reaction between formic acid and aluminium hydroxide yields Al(HCOO)3(CO2)0.75(H2O)0.25(HCOOH)0.25. Upon activation at 180 °C, guest molecules are removed to obtain Al(HCOO)3.[2]

    References

    [edit]
    1. ^ Oskar, Jochem. "ALUMINIUM FORMATE AND PROCESS OF MAKING THE SAME". United States Patent Office. Retrieved 2012-06-29.[dead link]
    2. ^ Evans H A, Mullangi D, Deng Z, et al. Aluminium formate, Al(HCOO)3: An earth-abundant, scalable, and highly selective material for CO2 capture. Science Advances, 2022, 8(44): eade1473. doi:10.1126/sciadv.ade1473

    Further reading

    [edit]
    • Hannelore, Rauh; Wilhelm Knoche (2010-06-10). "A kinetic study of the formation of aluminium formate in aqueous solution". Berichte der Bunsengesellschaft für physikalische Chemie. 83 (5): 518–521. doi:10.1002/bbpc.19790830513.
    • Xue, Moxi; Gao, Baoyu; Li, Ruihua; Sun, Jianzhang (2018). "Aluminium formate (AF): Synthesis, characterization and application in dye wastewater treatment". Journal of Environmental Sciences. 74: 95–106. doi:10.1016/j.jes.2018.02.013. PMID 30340679. S2CID 53010618.


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