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    Silver lactate

    From Wikipedia - Reading time: 6 min

    Silver lactate
    Names
    Other names
    silver; 1-hydroxy-1-oxopropan-2-olate
    Identifiers
    CAS Number
    3D model (JSmol)
    ChemSpider
    ECHA InfoCard 100.036.221 Edit this at Wikidata
    EC Number
    • 239-859-3
    PubChem CID
    CompTox Dashboard (EPA)
    InChI
    • InChI=1S/C3H5O3.Ag/c1-2(4)3(5)6;/h2H,1H3,(H,5,6);/q-1;+1
      Key: CUPCAVOUAWGFEI-UHFFFAOYSA-N
    SMILES
    • [Ag+].[O-]C(C(=O)O)C
    Properties
    Chemical formula
    CH3CH(OH)COOAg
    Molar mass 196.93 g/mol
    Appearance Gray to purple powder or flakes
    Melting point 120–122 °C (248–252 °F; 393–395 K)
    Boiling point 227.6 °C (441.7 °F; 500.8 K)
    Solubility in water
    Soluble
    Hazards
    GHS labelling:
    Pictograms
    GHS07: Exclamation mark
    Signal word
    Warning
    Hazard statements
    H315, H319, H335
    Precautionary statements
    P302, P305, P338, P351, P352
    NFPA 704 (fire diamond)
    NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
    2
    0
    1
    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
    Infobox references

    Silver lactate is an organic chemical compound, a salt of silver and lactic acid[1] with the formula CH3CH(OH)COOAg.[2][3]

    Synthesis

    [edit]

    Silver lactate can be made by the reaction of silver carbonate with lactic acid.

    Physical properties

    [edit]

    Silver lactate forms light gray crystals.[4]

    Silver lactate is soluble in water, slightly soluble in ethanol.

    Silver lactate forms a crystalline hydrate of composition CH3CH(OH)COOAg•H2O.

    Silver lactate is a reagent for the precipitation of uric acid.[5]

    Chemical properties

    [edit]

    The compound reacts with triphenylphosphine gold chloride in a mixed solvent of benzene and dichloromethane to obtain colorless triphenylphosphine gold lactate.[6]

    The compound reacts with a tetraphosphine ligand, dppbpda, to obtain a coordination polymer [(dppbpda)Ag4(CH3CH(OH)COO)4]n.[7]

    References

    [edit]
    1. ^ Hacker, Gerhard W.; Gu, Jiang (17 April 2002). Gold and Silver Staining: Techniques in Molecular Morphology. CRC Press. p. 62. ISBN 978-1-4200-4023-4. Retrieved 18 January 2022.
    2. ^ "Silver Lactate". American Elements. Retrieved 18 January 2022.
    3. ^ "Silver lactate". Sigma Aldrich. Retrieved 18 January 2022.
    4. ^ Hayat, M. A. (3 August 1995). Immunogold-Silver Staining: Principles, Methods, and Applications. CRC Press. p. 30. ISBN 978-0-8493-2449-9. Retrieved 18 January 2022.
    5. ^ Cornell University Medical Bulletin. 1928. p. 296. Retrieved 18 January 2022.
    6. ^ Fackler, John P.; Khan, M. Nazrul I.; King, Christopher; Staples, Richard J.; Winpenny, Richard E. P. (1 July 1991). "Decarboxylation of (triphenylphosphine)gold(I) carboxylates". Organometallics. 10 (7): 2178–2183. doi:10.1021/om00053a021. ISSN 0276-7333. Retrieved 23 January 2022.
    7. ^ Zhang, Min; Feng, Meng-Yao; Yan, Jia-Jun; Li, Hai-Yan; Young, David James; Li, Hong-Xi; Ren, Zhi-Gang (21 June 2021). "New Silver(I)-P4 Coordination Polymers Strongly Adsorb Congo Red to Yield Composites with Enhanced Photocurrent Responses". European Journal of Inorganic Chemistry. 2021 (23): 2262–2265. doi:10.1002/ejic.202100228. S2CID 235558940. Retrieved 23 January 2022.
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    Original source: https://en.wikipedia.org/wiki/Silver lactate
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