Silver lactate
Names
Other names
silver; 1-hydroxy-1-oxopropan-2-olate
Identifiers
CAS Number
3D model (JSmol)
ChemSpider
ECHA InfoCard
100.036.221
EC Number
InChI=1S/C3H5O3.Ag/c1-2(4)3(5)6;/h2H,1H3,(H,5,6);/q-1;+1
Key: CUPCAVOUAWGFEI-UHFFFAOYSA-N
Properties
Chemical formula
CH3 CH(OH)COOAg
Molar mass
196.93 g/mol
Appearance
Gray to purple powder or flakes
Melting point
120–122 °C (248–252 °F; 393–395 K)
Boiling point
227.6 °C (441.7 °F; 500.8 K)
Solubility in water
Soluble
Hazards
GHS labelling:
Pictograms
Signal word
Warning
Hazard statements
H315 , H319 , H335
Precautionary statements
P302 , P305 , P338 , P351 , P352
NFPA 704 (fire diamond)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Silver lactate is an organic chemical compound, a salt of silver and lactic acid[ 1] with the formula CH3 CH(OH)COOAg.[ 2] [ 3]
Synthesis [ edit ]
Silver lactate can be made by the reaction of silver carbonate with lactic acid.
Physical properties [ edit ]
Silver lactate forms light gray crystals.[ 4]
Silver lactate is soluble in water, slightly soluble in ethanol.
Silver lactate forms a crystalline hydrate of composition CH3 CH(OH)COOAg•H2 O.
Silver lactate is a reagent for the precipitation of uric acid.[ 5]
Chemical properties [ edit ]
The compound reacts with triphenylphosphine gold chloride in a mixed solvent of benzene and dichloromethane to obtain colorless triphenylphosphine gold lactate.[ 6]
The compound reacts with a tetraphosphine ligand, dppbpda, to obtain a coordination polymer [(dppbpda)Ag4 (CH3 CH(OH)COO)4 ]n .[ 7]
References [ edit ]
^ Hacker, Gerhard W.; Gu, Jiang (17 April 2002). Gold and Silver Staining: Techniques in Molecular Morphology . CRC Press. p. 62. ISBN 978-1-4200-4023-4 . Retrieved 18 January 2022 .
^ "Silver Lactate" . American Elements. Retrieved 18 January 2022 .
^ "Silver lactate" . Sigma Aldrich. Retrieved 18 January 2022 .
^ Hayat, M. A. (3 August 1995). Immunogold-Silver Staining: Principles, Methods, and Applications . CRC Press. p. 30. ISBN 978-0-8493-2449-9 . Retrieved 18 January 2022 .
^ Cornell University Medical Bulletin . 1928. p. 296. Retrieved 18 January 2022 .
^ Fackler, John P.; Khan, M. Nazrul I.; King, Christopher; Staples, Richard J.; Winpenny, Richard E. P. (1 July 1991). "Decarboxylation of (triphenylphosphine)gold(I) carboxylates" . Organometallics . 10 (7): 2178– 2183. doi:10.1021/om00053a021 . ISSN 0276-7333 . Retrieved 23 January 2022 .
^ Zhang, Min; Feng, Meng-Yao; Yan, Jia-Jun; Li, Hai-Yan; Young, David James; Li, Hong-Xi; Ren, Zhi-Gang (21 June 2021). "New Silver(I)-P4 Coordination Polymers Strongly Adsorb Congo Red to Yield Composites with Enhanced Photocurrent Responses" . European Journal of Inorganic Chemistry . 2021 (23): 2262– 2265. doi:10.1002/ejic.202100228 . S2CID 235558940 . Retrieved 23 January 2022 .
Silver compounds
Silver(0,I) Silver(I)
AgBF4
AgBr
AgBrO3
AgCN
AgCNO
AgCl
AgClO
AgBrO
AgIO
AgClO2
AgClO3
AgClO4
AgF
AgI
AgIO3
AgMnO4
AgNO2
AgNO3
AgN3
Ag3 N
AgReO4
AgOCN
AgSCN
AgCF3 SO3
AgPF6
Ag2 CO3
Ag2 C2
Ag2 C2 O4
Ag2 CrO4
Ag2 Cr2 O7
Ag2 MoO4
Ag2 O
Ag2 S
Ag2 SO3
Ag2 S2 O3
Ag2 SO4
AgHSO4
Ag2 Se
Ag2 SeO3
Ag2 Te
Ag3 AsO4
Ag3 PO4
KAg(CN)2
RbAg4 I5
Ag(NH3 )2 OH
Ag2 N2 O2
Ag2 WO4 Organosilver(I) compounds
AgC2 H3 O2
AgC22 H43 O2
CH3 CH(OH)COOAg
C18 H36 AgO2
AgC4 H3 N2 NSO2 C6 H4 NH2
AgC11 H23 COO
Silver(II) Silver(III) Silver(I,III)