Disaccharide
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A disaccharide is a sugar (a carbohydrate) composed of two monosaccharides.[1]
'Disaccharide' is one of the four chemical groupings of carbohydrates (monosaccharide, disaccharide, oligosaccharide, and polysaccharide).
Formation[edit | edit source]
It is formed when two sugars are joined together and a molecule of water is removed. For example; milk sugar (lactose) is made from glucose and galactose whereas cane sugar (sucrose) is made from glucose and fructose.
The two monosaccharides are bonded via a dehydration reaction (also called a condensation reaction or dehydration synthesis) that leads to the loss of a molecule of water and formation of a glycosidic bond.
Properties[edit | edit source]
The glycosidic bond can be formed between any hydroxyl group on the component monosaccharide. So, even if both component sugars are the same (e.g., glucose), different bond combinations (regiochemistry) and stereochemistry (alpha- or beta-) result in disaccharides that are diastereoisomers with different chemical and physical properties.
Depending on the monosaccharide constituents, disaccharides are sometimes crystalline, sometimes water-soluble, and sometimes sweet-tasting and sticky-feeling.
Common disaccharides[edit | edit source]
| Disaccharide | Unit 1 | Unit 2 | Bond | Disaccharidase |
| Sucrose (table sugar, cane sugar, saccharose, or beet sugar) | glucose | fructose | α(1→2) | sucrase |
| Lactose (milk sugar) | galactose | glucose | β(1→4) | lactase |
| Maltose | glucose | glucose | α(1→4) | maltase |
| Trehalose | glucose | glucose | α(1→1)α | trehalase |
| Cellobiose | glucose | glucose | β(1→4) | cellobiase |
Maltose and cellobiose are hydrolysis products of the polysaccharides, starch and cellulose, respectively.
Less common disaccharides include: Gentiobiose, that consists of two glucose monomers with an β(1→6) linkage; Isomaltose, that consists of two glucose monomers with an α(1→6) linkage; Kojibiose, that consists of two glucose monomers with an α(1→2) linkage [2]; Laminaribiose, that consists of two glucose monomers with a β(1→3) linkage; Mannobiose, that consists of two mannose monomers with either an α(1→2), α(1→3), α(1→4), or an α(1→6) linkage; Melibiose, that consists of a glucose monomer and a galactose monomer with an α(1→6) linkage; Nigerose, that consists of two glucose monomers with an α(1→3) linkage; Rutinose, that consists of a rhamnose monomer and a glucose monomer with an α(1→6) linkage; and Xylobiose, that consists of two xylopyranose monomers with a β(1→4) linkage.
References[edit | edit source]
- ↑ Template:GoldBookRef
- ↑ Matsuda, K. (1957). "Kojibiose (2-O-alpha-D-Glucopyranosyl-D-Glucose): Isolation and Structure: Chemical Synthesis". Nature. 180: 985. doi:10.1038/180985a0. Unknown parameter
|month=ignored (help)
External links[edit | edit source]
- Disaccharides at the US National Library of Medicine Medical Subject Headings (MeSH)
ar:سكريات ثنائية
bg:Дизахарид
de:Zweifachzucker
et:Disahhariidid
eo:Disakarido
eu:Disakarido
it:Disaccaridi
he:דו-סוכר
la:Disaccharides
lt:Disacharidas
mk:Дисахарид
ms:Disakarida
nl:Disacharide
no:Disakkarid
simple:Disaccharide
fi:Disakkaridi
sv:Disackarider
th:ไดแซ็กคาไรด์
uk:Дисахариди
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