Ibn al-Durayhim: gave detailed descriptions of eight cipher systems that discussed substitution ciphers, leading to the earliest suggestion of a "tableau" of the kind that two centuries later became known as the "Vigenère table".
Ahmad al-Qalqashandi: Author of Subh al-a 'sha, a fourteen volume encyclopedia in Arabic, which included a section on cryptology. The list of ciphers in this work included both substitution and transposition, and for the first time, a cipher with multiple substitutions for each plaintext letter.
Étienne Bazeries, French, military, considered one of the greatest natural cryptanalysts. Best known for developing the "Bazeries Cylinder" and his influential 1901 text Les Chiffres secrets dévoilés ("Secret ciphers unveiled").
Julius Caesar, Roman general/politician, has the Caesar cipher named after him, and a lost work on cryptography by Probus (probably Valerius Probus) is claimed to have covered his use of military cryptography in some detail. It is likely that he did not invent the cipher named after him, as other substitution ciphers were in use well before his time.
Edgar Allan Poe, author of the book, A Few Words on Secret Writing, an essay on cryptanalysis, and The Gold Bug, a short story featuring the use of letter frequencies in the solution of a cryptogram.
Marian Rejewski, Poland, Biuro Szyfrów, a Polish mathematician and cryptologist who, in 1932, solved the Enigma machine with plugboard, the main cipher device then in use by Germany. The first to break the cipher in history.