Lutetium(III) acetate

Lutetium acetate
	Lutetium acetate Some white lutetium acetate powder.
Names
	IUPAC names Tetra-μ2-acetatodiaquadilutetium(III); lutetium(3+);triacetate neodymium(3+) triacetate
	Other names Lutetium ethanoate; Lutetium triacetate; Lutetium(III) acetate;
Identifiers
CAS Number	18779-08-3;
3D model (JSmol)	Interactive image;
ChemSpider	146740;
ECHA InfoCard	100.038.681
EC Number	242-566-3;
PubChem CID	167747;
CompTox Dashboard (EPA)	DTXSID00890781 ;
	InChI InChI=1S/C2H4O2.Lu/c1-2(3)4;/h1H3,(H,3,4); Key: WXHWNEZDKCJUFF-UHFFFAOYSA-N;
	SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Lu+3];
Properties
Chemical formula	Lu(C2H3O2)3
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H318, H335
Precautionary statements	P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P337+P317, P362+P364, P403+P233, P405, P501
Related compounds
Other anions	Lutetium(III) oxide; Lutetium(III) hydroxide; Lutetium(III) carbonate
Other cations	Ytterbium(III) acetate; Thulium(III) acetate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lutetium(III) acetate is the acetate salt of lutetium with the chemical formula of Lu(CH₃COO)₃.

Preparation

Lutetium(III) acetate can be prepared through neutralisation, where a lutetium salt reacts with acetic acid to produce lutetium acetate and water:

Lu₂O₃ + 6 CH₃COOH → 2 Lu(CH₃COO)₃ + 3 H₂O

Lu(OH)₃ + 3 CH₃COOH → Lu(CH₃COO)₃ + 3 H₂O

Lutetium(III) acetate also can be obtained by reacting lutetium oxide with gaseous acetic acid^[1] or 50% acetic acid solution.^[2]

Properties

Lutetium(III) acetate is a water-soluble salt that forms colorless crystals. It forms crystalline hydrates in the form of Lu(CH₃COO)₃•nH₂O, where n = 1 or 4.^{[citation needed]}

Lutetium(III) acetate reacts with ammonium fluoride to produce lutetium fluoride:

Lu(CH₃COO)₃ + 3 NH₄F → LuF₃ + 3 CH₃COONH₄

The F⁻ formed by the hydrolysis of fluoroborates (such as [BMIM]BF₄)^[3] can also precipitate with Lu³⁺.^[4]

Reaction with phosphoric acid to produce lutetium phosphate:^[5]

Lu(CH₃COO)₃ + H₃PO₄ → LuPO₄ + 3 CH₃COOH

References

^ Janina Wysocka-Lisek. Study of topochemical preparation of rare earth acetates(in Polish). Biuletyn Lubelskiego Towarzystwa Naukowego, Matematyka-Fizyka-Chemia, 1981. 23 (2): 145-149.
^ Grählert, Xina; Starke, Graehlert (1992). "Preparation, thermogravimetric study and infrared spectra of rare earth acetates". Preparation, Thermogravimetric Study and Infrared Spectra of Rare Earth Acetates. 34 (2): 219–229.
^ Note: The original text is "BMIM = 1-butyl-2-methylimidazolium", which is supposed to be 1-butyl-3-methylimidazolium
^ Becerro, Ana I.; Gonzalez-Mancebo, Daniel; Ocaña, Manuel (January 2015). "Uniform, luminescent Eu:LuF3 nanoparticles". Journal of Nanoparticle Research. 17 (1): 58. Bibcode:2015JNR....17...58B. doi:10.1007/s11051-015-2874-z. hdl:10261/110370. S2CID 73703723.
^ Becerro, Ana I.; Ocaña, Manuel (2015). "Quick synthesis, functionalization and properties of uniform, luminescent LuPO 4 -based nanoparticles". RSC Advances. 5 (44): 34517–34524. Bibcode:2015RSCAd...534517B. doi:10.1039/C5RA05305F. hdl:11441/73018.

[1] Janina Wysocka-Lisek. Study of topochemical preparation of rare earth acetates(in Polish). Biuletyn Lubelskiego Towarzystwa Naukowego, Matematyka-Fizyka-Chemia, 1981. 23 (2): 145-149.

[2] Grählert, Xina; Starke, Graehlert (1992). "Preparation, thermogravimetric study and infrared spectra of rare earth acetates". Preparation, Thermogravimetric Study and Infrared Spectra of Rare Earth Acetates. 34 (2): 219–229.

[3] Note: The original text is "BMIM = 1-butyl-2-methylimidazolium", which is supposed to be 1-butyl-3-methylimidazolium

[4] Becerro, Ana I.; Gonzalez-Mancebo, Daniel; Ocaña, Manuel (January 2015). "Uniform, luminescent Eu:LuF3 nanoparticles". Journal of Nanoparticle Research. 17 (1): 58. Bibcode:2015JNR....17...58B. doi:10.1007/s11051-015-2874-z. hdl:10261/110370. S2CID 73703723.

[5] Becerro, Ana I.; Ocaña, Manuel (2015). "Quick synthesis, functionalization and properties of uniform, luminescent LuPO 4 -based nanoparticles". RSC Advances. 5 (44): 34517–34524. Bibcode:2015RSCAd...534517B. doi:10.1039/C5RA05305F. hdl:11441/73018.

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Names
Lutetium acetate Some white lutetium acetate powder.
IUPAC names Tetra-μ²-acetatodiaquadilutetium(III) lutetium(3+);triacetate neodymium(3+) triacetate
Other names Lutetium ethanoate Lutetium triacetate Lutetium(III) acetate
Identifiers
CAS Number	18779-08-3
3D model (JSmol)	Interactive image
ChemSpider	146740
ECHA InfoCard	100.038.681
EC Number	242-566-3
PubChem CID	167747
CompTox Dashboard (EPA)	DTXSID00890781
InChI InChI=1S/C2H4O2.Lu/c1-2(3)4;/h1H3,(H,3,4); Key: WXHWNEZDKCJUFF-UHFFFAOYSA-N
SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Lu+3]
Properties
Chemical formula	Lu(C₂H₃O₂)₃
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H318, H335
Precautionary statements	P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P337+P317, P362+P364, P403+P233, P405, P501
Related compounds
Other anions	Lutetium(III) oxide Lutetium(III) hydroxide Lutetium(III) carbonate
Other cations	Ytterbium(III) acetate Thulium(III) acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references