Nitrate chlorides are mixed anion compounds that contain both nitrate (NO3−) and chloride (Cl−) ions. Various compounds are known, including amino acid salts,[1] and also complexes from iron group, rare-earth, and actinide metals. Complexes are not usually identified as nitrate chlorides, and would be termed chlorido nitrato complexes.
Nitrate chloride compounds may be formed by mixing solutions of chloride and nitrate slats, the addition of nitric acid to a chloride salt solution, or the addition of hydrochloric acid to a nitrate solution. Most commonly water is used as a solvent, but other solvents such as methylene dichloride, methanol or ethanol can be used.
name | formula | ratio
NO3:Cl |
mw | system | space group | unit cell Å | volume | density | optical | references |
---|---|---|---|---|---|---|---|---|---|---|
Buttgenbachite | Cu19(NO3)2(OH)32Cl4 · 2H2O | 2:4 | hexagonal | P63/mmc | a = 15.75 Å, c = 9.161 Å Z=1 | 1968 | 4.538 | Blue
Uniaxial (+) nω = 1.738 nε = 1.752 birefringence: δ = 0.014 |
[2][3] | |
Lislkirchnerite | Pb6Al(OH)8Cl2(NO3)5·2H2O | 5:2 | monoclinic | P21/n | a = 10.7834(6) Å, b = 9.0584(5) Å, c = 13.6178(9) Å
β = 102.28(2)° |
1300 | [4] | |||
Sveite | KAl7(NO3)4(OH)16Cl2 · 8H2O | 4:2 | Monoclinic | a = 10.89 Å, b = 13.04 Å, c = 30.71 Å
β = 92.1° |
4,358 | white
Biaxial (+) nα = 1.501 nβ = 1.503 nγ = 1.535 2V: calculated = 30° Max Birefringence = δ = 0.034 |
[5] | |||
Pb8O3(OH)5(NO3)4Cl | 4:1 | Monoclinic | a = 14.831(3) Å, b = 7.659(2) Å, c = 10.186(2) Å
β = 108.64(3)° |
1096 | colourless | [6] |
name | formula | ratio
NO3:Cl |
mw | system | space group | unit cell Å | volume | density | comment | references |
---|---|---|---|---|---|---|---|---|---|---|
Chlorine nitrate | O2NOCl | orthorhombic | P212121 | a = 3.856 b = 6.755 c = 12.07 Z=46 | 314.5 | 2.058 | at −166 °C (related compound) | [7] | ||
anilinium chloride nitrate | (C6H8N)2ClNO3 | 1:1 | triclinic | P1 | a = 8.418 b = 9.648 c = 10.036 α = 62.993° β = 86.798° γ = 72.999° | [8] | ||||
o-Phenylenediaminium chloride nitrate | orthorhombic | Pnma | a = 7.3695 b = 8.2367 c = 14.2398 Z=4 | 864.36 | 1.596 | [9] | ||||
l-lysinium(2+) chloride nitrate | L-Lys2+·Cl−·NO3- | 1:1 | monoclinic | P21 | a 8.8022 b 7.0096 c 20.2169 β 95.226° | [10] | ||||
L-Lysine L-lysinium dichloride nitrate | 2C6H15N2O2+·H+·NO3-·2Cl- | 1:2 | 428.32 | orthorhombic | P212121 | a 4.9846 b 20.604 c 20.663 Z=4 | 2122.1 | 1.341 | colourless | [11] |
L-cysteinium sodium nitrate chloride | 1:1 | monoclinic | P21 | a=18.5, b=5.22, c=7.22 β=103.83° | 678 | transparent from 328 to 1400nm; SHG 0.51 ×KDP | [12] | |||
Bis(L-ornithinium) chloride nitrate sulfate | 2C5H14N2O22+·Cl-·NO3-·SO42- | 461.88 | monoclinic | C2 | a 13.872 b 9.578 c 9.178 β 125.35° Z=2 | 994.6 | 1.542 | [13] | ||
(μ4-octahydroxycucurbit(5)uril)-(μ2-nitrato)-aqua-di-potassium chloride nonahydrate | {[K(H2O)](NO3⊂C30H28N20O20)[K(η2-NO3)]}Cl(H3O)22+·7H2O | monoclinic | P21/c | a 13.8265 b 14.2642 c 25.143 β 92.711° Z=4 | 4953.2 | 1.806 | colourless | [14] | ||
Thecotrichite | Ca3(CH3COO)3Cl(NO3)2 • 6H2O | 2:1 | monoclinic | P21/c | a 23.5933 b 13.8459 c 6.8010 β 95.195° Z=4 | 2212.57 | anthropogenic, formed on ceramics in damp wooden cupboards;
refractive index: nx = 1.491 nz = 1.494 stable to 110°C |
[15] | ||
di-μ-hydroxido-bis[triaqua(nitrato-κ2O,O′)scandium(III)] dichloride | [Sc2(NO3)2(OH)2(H2O)6]Cl2 | 1:1 | 426.95 | triclinic | P1 | a=6.7221 b=7.6279 c=8.5181 α=100.904° β=110.125° γ=102.329° Z=1 | 383.87 | 1.847 | colourless @100K | [16] |
[Fe(Cl)4](Fe(NO3)2(OPPh2py)2 | [17] | |||||||||
[Fe(NO3)2(Cl)(OPPh2py)]· CH2Cl2 | monoclinic | P21/n | a 9.138 b 15.69 c 16.68 β 94.50° | [17] | ||||||
hexamethylphosphoric triamide | Fe(NO3)2(Cl)(HMPA)1.5 | [18] | ||||||||
hexamethylphosphoric triamide | Fe(NO3)2(Cl)(HMPA)2 | [18] | ||||||||
hexamethylphosphoric triamide | Fe(NO3)(Cl)2(HMPA)2 | monoclinic | P21/c | a 15.994 b 10.172 c 16.571 β 104.7° | [18] | |||||
pypn=N,N′-bis(2-pyridylmethyl)-1,3-propanediamine
(N,N'-bis((pyridin-2-yl)methyl)propane-1,3-diamine)-dichloro-iron(iii) nitrate |
[Fe(pypn)Cl2](NO3) | monoclinic | P21/c | a 11.848 b 12.474 c 12.301 β 94.56° | Cl in cis position | [19] | ||||
pentaamminenitrocobalt(III) chloride nitrate | [Co(NH3)5NO2](NO3)Cl | orthorhombic | Pnam | a 14.814 b 9.623 c 7.309 | @290K; photosalient (jumps under UV) | [20][21][22] | ||||
trans-Dichloro-bis(ethylenediamine)-cobalt(III) nitrate | [Co en2Cl2]NO3 | monoclinic | P21/n | a = 6.348 b = 9.304 c = 9.853 β = 101.79° | 569.6 | 1.82 | green | [23][24] | ||
cis-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate | [Co(en)2(NH3)Cl](NO3)2 | [25] | ||||||||
trans-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate | [Co(en)2(NH3)Cl](NO3)2 | [25] | ||||||||
5-nitrosalicyliddineaminato tetraamino cobalt dichloride nitrate | orange | [26] | ||||||||
cis-Chlorobis(ethylenediamine)dodecylaminecobalt(III) nitrate | cis-[Co(en)2(C12H25NH2)Cl](NO3)2 | [27] | ||||||||
bis(1,4,7-triazacyclononane) nickel(ii) nitrate chloride monohydrate | [Ni([9]aneN3)2](NO3)Cl·H2O | orthorhombic | Pna21 | a 17.584 b 8.860 c 12.141 | [28] | |||||
Bis[chlorobis(1,10-phenanthroline-N,N')(thiourea-S)nickel(II)] chloride nitrate diethanol solvate | [NiCl(C12H8N2)2(CH4N2S)]2(NO3)Cl·2C2H6O | orthorhombic | Fdd2 | a 22.813 b 29.024 c 17.113 Z=8 | 11331 | 1.467 | blue | [29] | ||
Cucurbit[8]uril (1-n-butyl-4,4'-bipyridin-1-ium 1-n-butyl-4,4'-bipyridin-1-ium-penta-aqua-nickel(ii)) clathrate chloride trinitrate undecahydrate | {[C14H17N2Ni(H2O)5]2⊂C48H48N32O16}[(C14H17N2)2⊂C48H48N32O16]Cl2(NO3)6·22H2O | triclinic | P1 | a 16.671 b 16.678 c 20.442 α 112.772° β 101.844° γ 90.102° | [30] | |||||
bis(bis(1,4,7-triazacyclonon-1-yl)pentane)-di-nickel(ii) trichloride nitrate pentadecahydrate | [Ni2(EM5)2]Cl3NO3·15H2O | orthorhombic | Pbcn | a 28.030 b 17.469 c 12.289 | [31] | |||||
bis(bis(1,4,7-triazacyclonon-1-yl)hexane)-di-nickel(ii) dichloride dinitrate hexahydrate | [Ni2(EM6)2]Cl3(NO3)2·6H2O | triclinic | P1 | a 9.529 b 9.566 c 14.684 α 81.08° β 78.84° γ 88.82° | [31] | |||||
dapsc = 2,6-diacetylpyridine-bis(semicarbazone)) | [Ni(dapsc)(H2O)2]Cl(NO3)·H2O | triclinic | P1 | a=6.9130 b=12.3410 α=114.8010 β=93.946 γ=103.7760 Z=2 | 933.10 | 1.735 | green | [32] | ||
hexakis(1H-imidazole)-nickel(ii) chloride nitrate tetrahydrate | [Ni(Im)6][(NO3)Cl(H2O)4] | hexagonal | P63m | a 9.003 c 21.034 | [33] | |||||
bis(M-2-chloro)-(nitrato-o)-(2,2 '-bipyridine-N.N ')-copper(II) | Cu(2,2 '-BP)Cl NO3 | triclinic | P1 | a = 7.515 b = 9.253 c = 10.283 α=112.181° β= 102.155° γ= 105.617° Z=2 | 597.4 | 1.769 | green; dimer | [34] | ||
bis(M-2-chloro)-(nitrato-o)-(2,2 '-4,4'-dimethylbipyridine-N.N ')-copper(II) | Cu(2, 2'-dmBP)ClNO3 | dimer | [34] | |||||||
Chloro(1,10-phenanthroline-2-carboxamide oxime)copper(II) Nitrate | [35] | |||||||||
bis(μ2-2,4,4,6,6-pentakis(2-pyridyloxy)cyclo-2,4,6-triphosphazene 2-oxide)-dichloro-nitrato-cobalt(ii)-di-copper chloride | [{(N3P3(OC5H4N)5(O)CuCl)2Co(NO3)}Cl] | orthorhombic | Fddd | a =22.639 b =28.202 c =45.260 | [36] | |||||
Copper(II)–sparteine nitrate chloride | CuII{(−)Sp}(NO3)Cl | orthorhombic | P212121 | a 16.370 b 13.334 c 7.6803 | [37] | |||||
Cucurbit[8]uril (1-n-butyl-4,4'-bipyridin-1-ium 1-n-butyl-4,4'-bipyridin-1-ium-penta-aqua-copper(ii)) clathrate dichloride dinitrate hexadecahydrate | {[C14H17N2Cu(H2O)5]2⊂C48H48N32O16}[(C14H17N2)2⊂C48H48N32O16]Cl4(NO3)4·32H2O | triclinic | P1 | a 16.607 b 17.093 c 20.509 α 66.003° β 77.568° γ 89.155° | [30] | |||||
copper(II)-di-2-pyridylamine complex chloride nitrate
(μ2-Chloro)-(nitrato-O)-(bis(2-pyridyl)amine-N,N')-copper(ii) hemihydrate |
[Cu(dipyam)Cl(NO3)].0.5H2O | monoclinic | P21/a | a 7.382 b 21.494 c 8.032 β 94.26 | [38] | |||||
tipa=tri(4-imidazolylphenyl)amine
(μ3-tris(4-(Imidazol-1-yl)phenyl)amine)-chloro-zinc nitrate dimethylformamide solvate |
[Zn(tipa)Cl]⋅NO3⋅2 DMF | orthorhombic | Pnna | a=28.470 b=27.784 c=9.255 | 7321 | 1.044 | [39] | |||
Na3Rb6(CO3)3(NO3)2Cl·(H2O)6 | 2:1 | 1029.39 | hexagonal | P63/mcm | a = 9.5732 c = 15.820 Z=2 | 1255.6 | 2.723 | UV cut off 231 nm; uniaxial; birefringence 0.14 @ 546 nm | [40] | |
KRb2(NO3)2Cl | 2:1 | 369.51 | orthorhombic | pbam | a=12.1863 b=12.4072 c=5.8203 Z=4 | 880.02 | 2.789 | transparent; birefringence = 0.084 at 1064 nm | [41] | |
[Ru(NH3)5Cl](NO3)2 | tetragonal | I4 | a = 7.5811 b = 7.5811 c = 10.535 | 605.5 | 1.896 | yellow | [42] | |||
[RuNO(NH3)3(H2O)Cl](NO3)2 | monoclinic | Cc | a = 13.7924 b = 6.9114 c = 12.3577 β = 111.863° Z = 4 | 1093.27 | 2.185 | [43] | ||||
bis((μ2-chloro)-(nitrato)-(η5-pentamethylcyclopentadienyl)-rhodium(iii)) | [Cp*Rh(η1-NO3)(μ-Cl)]2 | monoclinic | P21/n | a 8.3874 b 10.4549 c 14.8585 β 104.385° | [44] | |||||
chloro-(cyclohexylisocyano)-(η5-pentamethylcyclopentadienyl)-(triphenylphosphine)-rhodium nitrite nitrate dihydrate | {[Cp*RhCl(PPh3)(CNC6H11)]2(NO2)(NO3)}·2H2O | triclinic | P1 | a 10.319 b 10.5582 c 17.371 α 97.011° β 94.35° γ 112.154° | [44] | |||||
[Rh(NH3)5Cl](NO3)2 | tetragonal | I4 | a = 7.5858 b = 7.5858 c = 10.41357 Z=2 | 599.24 | 1.926 | yellow | [42] | |||
bis(μ2-4'-(4-pyridyl)-2,2':6',2''-terpyridine)-bis(η5-pentamethylcyclopentadienyl)-tetra-chloro-di-rhodium-nickel dinitrate methanol solvate dihydrate | {Cp*2Rh2[Ni(pyterpy)2]Cl4}(NO3)2 | monoclinic | C2/c | a 53.4454 b 8.8419 c 33.7700 β 112.029° | [45] | |||||
cis-dichlorobis(ethylenediamine)rhodium(III) nitrate | [Rh(en)2Cl2]NO3 | triclinic | P1 | a=8.619 b=6.528 c=11.687 α=I02.18 β=90.98 γ=112.46 Z=2 | 590.5 | 2.00 | yellow | [46] | ||
trans-dichlorobis(ethylenediamine)rhodium(III) nitrate | [Rh(en)2Cl2]NO3 | monoclinic | P21/n | a = 6.441 b=9.281 c=10.010 β=102.42 Z=2 | 584.4 | 2.02 | orange | [46] | ||
L=3,6,9,16,19,22-hexaazatricyclo[22.2.2.211,14]triacon-11,13,24,26(1),2 7,29-hexaene
(μ2-3,6,9,16,19,22-Hexa-azatricyclo(22.2.2.211,14)triaconta-1(26),11,13,24,27,29-hexaene)-dichloro-di-palladium(ii) dinitrate monohydrate |
[Pd2LCl2](NO3)2·H2O | monoclinic | P2/c | a 21.744 b 9.243 c 16.259 β 93.580° | [47] | |||||
en=Ethylenediamine py=pyridine | [Pd(en)(py)Cl]NO3 | monoclinic | P21/c | a = 7.990, b = 16.058, c = 9.846 β = 103.81° Z = 4 | [48] | |||||
4-Methylpyridine, | [Pd(en)(4-Me-py)Cl]NO3 | [48] | ||||||||
4-hydroxy-pyridine | [Pd(en)(4-OH-py)Cl]NO3 | [48] | ||||||||
4-NH2-py=4-aminopyridine | [Pd(en)(4-NH2-py)Cl]NO3 | [48] | ||||||||
tetrakis(μ-tris((diphenylphosphino)methyl)amine)-tetrachloro-pentadeca-silver tris(nitrate) octahydrate | [Ag15(N-triphos)4(Cl4)](NO3)3 | 3649.32 | orthorhombic | C2221 | a 18.702 b 36.975 c 28.652 Z=6 | 19813 | 1.835 | [49] | ||
bis(tetrakis(Triphenylphosphine)-silver) chloro-diphenyl-bis(nitrato-O,O')-tin diphenyl-tris(nitrato-O,O')-tin | [Ag(PPh3)4][SnPh2(NO3)2(Cl,NO3)] | triclinic | P1 | a 22.43 b 14.13 c 13.96 α 90.59° β 69.82° γ 64.58° | [50] | |||||
barium chloride nitrate | Ba(NO3)Cl | orthorhombic | Pnma | a 8.9108 b 5.2991 c 8.3414 | UV cutoff 213 nm; birefringence 0.009 @ 1064 nm | [51] | ||||
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine | [La(H2LSS)(NO3)2Cl]·2CH2Cl2 | tetragonal | P43212 | a = 18.1798 c = 16.4174 Z=4 | 5426.0 | 1.150 | [52] | |||
tris(μ2-N',N''-((5-Chloro-2-oxy-1,3-phenylene)dimethylylidene)bis(benzohydrazide))-bis(ethanol)-di-lanthanum dinitrate chloride acetone solvate dihydrate | [La2(H2L1)3(C2H5OH)2]·(Cl)·(NO3)2·((CH3)2CO)2·(H2O)2 | monoclinic | C2/c | a 21.1020 b 18.5070 c 23.1880 β 114.452° | [53] | |||||
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine | [Ce(H2LSS)(NO3)2Cl]·2CH2Cl2 | tetragonal | P43212 | a = 18.216 c = 16.483 Z=4 | 5469.6 | 1.147 | [52] | |||
Chloro-nitrato-pentakis(tetrahydrofuran)-cerium(iii) pentachloro-(tetrahydrofuran)-cerium(iv) | [CeCl(NO3)(THF)5]+[CeCl5(THF)]− | monoclinic | P2/c | a 12.138 b 11.299 c 14.066 β 104.31° | [54] | |||||
Praseodymium dichloride nitrate pentahydrate | [PrCl2(H2O)6][PrCl2(NO3)2(H2O)4] | monoclinic | P2/c | a = 12.288 b = 6.484 c = 12.660 β = 91.91° Z = 4 | green | [55] | ||||
L=N,N′‐bis (salicylidene)‐1,2‐cyclohexanediamine | [Pr(H2L)2(NO3)2Cl]·2CH2Cl2 | 941.14 | tetragonal | P43212 | a=18.0936 c=16.3490 Z=4 | 5352.3 | 1.168 | [56] | ||
LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine | [Nd(H2LSS)(NO3)2Cl]·2CH2Cl2 | tetragonal | P43212 | a = 18.1041 c = 16.4374 Z=4 | 5387.5 | 1.164 | [52] | |||
Chloro-bis(nitrato-O,O')-bis(tetramethyl (t-butyl(hydroxy)methylene)-bis(phosphonate)-O,O')-neodymium(iii) | NdCl(NO3)2{[(MeO)2PO]2C(OH)tBu}2 | monoclinic | P21/a | a 17.0961 b 9.3040 c 24.4989 β 110.244° | [57] | |||||
tri-sodium hexakis(μ-oxo)-tetraoctacontakis(μ-hydroxo)-triacontakis(μ-2-thiophenecarboxylato)-tetrakis(2-thiophenecarboxylato)-decakis(μ-glycinato)-diglycine-docosa-aqua-octatetraconta-europium(iii) nitrate hexachloride 2-thiophenecarboxylic acid pentahydrate | Na3[Eu48O6(OH)84(tca)34(gly)12(H2O)22]·2Htca·6Cl·6H2O·NO3 | 15118.80 | triclinic | P1 | a 20.720 b 23.227 c 24.562 α 88.66° β 71.76° γ 63.57° Z=1 | 9960 | 2.500 | [58] | ||
sodium tetradecakis(μ-3-hydroxy-2-(hydroxymethyl)-2-methylpropanoato)-hexakis(μ-oxo)-tetraoctacontakis(μ-hydroxo)-octadecakis(μ-2-thiophenecarboxylato)-octakis(2-thiophenecarboxylato)-tetracosa-aqua-octatetraconta-terbium(iii) nitrate octakis(chloride) | Na[Tb48O6(OH)84(fca)26(dmp)14(H2O)24]·4Hfca·NO3·8Cl | 15154.02 | monoclinic | P21/n | a 24.0145 b 32.9221 c 25.6605 β 97.521° Z=2 | 20112.9 | 2.490 | [58] | ||
L=2-methyl-8-hydroxyquinoline
tetrakis(μ-2-methylquinolin-8-olato)-(μ-chloro)-ethanol-dinitrato-di-nickel(ii)-dysprosium(iii) acetonitrile solvate |
[Ni2IIDyIII(EtOH)(L2)4(NO3)2Cl] ⋅ CH3CN | triclinic | P1 | a 11.1201 b 14.1566 c 15.448 α 78.625° β 73.918° γ 81.055° | [59] | |||||
(tetrakis(μ-(1-phenylethyl)ammoniomethylphosphonato)-chloro-nitrato-di-erbium | R- or S-[Er2(pempH)4(NO3)Cl] | orthorhombic | P21212 | a 15.986 b 32.069 c 9.1593 | quadruple stranded helix | [60] | ||||
[{trans-PtCl(NH3)2}{μ-(H2N(CH2)6NH2)}{trans-PdCl(NH3)2](NO3)Cl | yellow | [61] | ||||||||
[{trans-PtCl(NH3)2}2{trans-Pt(thiazole)2}{H2N(CH2)6NH2}2]Cl3(NO3) | [62] | |||||||||
[PtPy2(NH=CH-OH)Cl3]NO3 | orthorhombic | P212121 | a = 10.381 b = 11.776 c = 13.848 Z = 4 | 1692.9 | [63] | |||||
alpha pyridone | cis-[Pt(NH3)2(C5H4NOH)Cl](NO3) | triclinic | P1 | a=10.706 b=12.552 c=4.151 α =95.57° β=92.32° γ=99.05° Z=2 | 547.4 | 2.558 | white needles | [64] | ||
[PtIV(trans-1R,2R-diaminocyclohexane)trans-(acetate)2(9-ethylguanine)Cl]NO3 · H2O | P21 | a = 10.446 b = 22.906 c = 10.978 Z = 4 | [65] | |||||||
Chloro-(homopiperazine)-(diphenylsulfido)-platinum(ii) nitrate | [PtII(homopiperazine)(diphenylsulfide)Cl]NO3 | monoclinic | P21/c | a 17.666 b 8.812 c 12.619 β 101.02° | [66] | |||||
mmap=1-methyl-4-(methylamino)piperidine | [Pt(mmap)(CH3)2S)Cl](NO3) | white | [67] | |||||||
dhq=decahydroquinoline | [Pt(dhq)(CH3)2S)Cl](NO3) | [67] | ||||||||
[La(NO3)2(H2O)6]2[PtCl6]·2H2O | monoclinic | P21/c | a = 6.974 b = 16.545 c = 13.177 β = 93.97° Z=2 | yellow | [68] | |||||
[Pr(NO3)2(H2O)6]2[PtCl6]·2H2O | monoclinic | P21/c | a = 6.955 b = 16.525, c = 13.18.5 β = 93.93° Z=2 | yellow | [68] | |||||
[Gd(NO3)(H2O)7][PtCl6]·4H2O | monoclinic | P21/n | a = 8.3872 b = 21.3198 c = 11.4263 β = 95.670° Z=4 | yellow | [68] | |||||
[Dy(NO3)(H2O)7][PtCl6]·4H2O | monoclinic | P21/n | a = 8.3840 b = 21.3950 c = 11.4310 β = 95.698° Z=4 | yellow | [68] | |||||
Ir[NO3]2Cl[NH3]5 | tetragonal | I4 | a = 7.6061 c = 10.4039 | 601.89 | 2.410 | yellow | [42] | |||
{Cp*2Ir2[Ni(pyterpy)2]Cl4}(NO3)2 | [45] | |||||||||
Dichloro(ethylenediamine)gold(III) nitrate | [Au(NH2CH2CH2NH2)Cl2]NO3 | orthorhombic | Pbca | a = 10.338 b = 8.2105 c = 19.625 Z=8 | [69] | |||||
(2,2'-Bipyridine)dichlorogold(III) nitrate | [AuCl2(C10H8N2)]NO3 | 486.06 | monoclinic | C2/c | a 6.9240 b 14.0460 c 13.0560 β 96.562° Z=4 | 1261.44 | 2.559 | pale yellow | [70] | |
Bis(methy1 L-cysteineato)mercury(II) hydrochloride hydronitrate monohydrate | (C4H9NO2S)2ClHgNO3•H2O | [71] | ||||||||
chloronitrato-2-{2′-[(1′-methyl)benzimidazolyl]}- 4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxidemercury(II) – mercury(II)chloride | HgCl(NO3)(C15H19N4O2) · HgCl2 | triclinic | P1 | a=9.922 b=10.822 c=11.460 α=107.518° β=102.046° γ=96.639° Z=2 | 1126.5 | black | [72] | |||
caesium mercuric nitrate chloride | CsHgNO3Cl2 | 1:2 | 466.41 | hexagonal | P63/mmc | a=5.8817 c=11.3920 Z=2 | 341.30 | 4.538 | birefringent Δn = 0.145@546 nm | [73] |
4-chloropyridinium | (C5H5NCl)2[UO2Cl3(NO3)] | 1:3 | triclinic | P1 | a=6.819 b=10.781 c=14.252 α=72.890° β=80.394° γ=74.456° Z=2 | 960.3 | 2.308 | [74] | ||
4-bromopyridinium | (C5H5NBr)2[UO2Cl3(NO3)] | 1:3 | 756.41 | monoclinic | P21/m | a =9.739 b =16.484 c =12.950 β =102.360° Z=4 | 2030.8 | 2.474 | [74] | |
4-iodopyridinium | (C5H5NI)3[UO2Cl3(NO3)](NO3) | 2:3 | 559.20*2 | monoclinic | P21/c | a =7.9797 b =25.043 c =14.730 β =103.019° Z=4 | 2868.0 | 2.590 | [74] | |
pyr2phen = N,N′-bis-(pyridoxylideneiminato)2−phenylene
(N-(3-Hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-ylmethylidene)-N'-(5-(hydroxymethyl)-2-methyl-3-oxypyridin-4-ylmethylidene)-o-phenylenediamine-N,N',O,O')-chloro-dioxo-uranium nitrate dihydrate |
[UO2(H2pyr2phen)Cl]NO3 | triclinic | P1 | a 9.231 b 11.855 c 14.026 α 114.8° β 94.012° γ 97.95° | [75] | |||||
K3[(UO2)(NO3)Cl3](NO3) | monoclinic | P21 | a 7.8596 b 15.8675 c 10.6823 β 90.141° Z=4 | 1332.21 | 3.08 | [76] | ||||
Cs2(UO2)(NO3)Cl3 | 1:3 | 704.21 | monoclinic | P21/n | a=10.375 b=9.468 c=12.553 β= 110.280 Z=4 | 1156.7 | 4.04 | lemon yellow | [77] | |
bis(4-iodo-pyridinium) dinitrato-tetrachloro-plutonium(iv) | (C5H5NI)2[Pu(IV)Cl4(NO3)2] | triclinic | P1 | a =9.8096 b=10.1402 c=11.5033 73.416 82.364 87.100 Z=2 | 1086.8 | 2.811 | orange | [78] | ||
bis(pyridinium) trinitrato-trichloro-plutonium(iv) | (C5H6N)2[Pu(IV)Cl3(NO3)3] | 694.60 | monoclinic | P21/c | a 17.268 b 7.7622 c 15.112 β 97.598° Z=4 | 2007.8 | 2.298 | dark red | [78] | |
bis(4-chloro-pyridinium) dioxo-trichloro-nitrato-plutonium(vi) | (C5H5NCl)2[Pu(VI)O2Cl3(NO3)] | 671.46 | triclinic | P1 | a 6.7493 b 10.8107 c 14.171 α 73.657° β 81.412° γ 75.206° Z=2 | 956.0 | 2.333 | yellow | [78] |
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