Palladium(II,IV) fluoride

Palladium(II,IV) fluoride
Names
	Other names palladium(II) hexafluoropalladate(IV)
Identifiers
CAS Number	12021-58-8 ;
3D model (JSmol)	Interactive image;
PubChem CID	57434144;
CompTox Dashboard (EPA)	DTXSID101045628 ;
	InChI InChI=1S/6FH.2Pd/h6*1H;;/q;;;;;;+2;+4/p-6 Key: LRWQWDMZTSEXJX-UHFFFAOYSA-H;
	SMILES [Pd+2].[F-][Pd+4]([F-])([F-])([F-])([F-])[F-];
Properties
Chemical formula	F3Pd
Molar mass	163.42 g·mol−1
Appearance	black solid
Magnetic susceptibility (χ)	+1760.0·10−6 cm3/mol
Structure
Crystal structure	rhombohedral
Coordination geometry	octahedral
Related compounds
Other cations	Nickel(III) fluoride
Related compounds	Palladium(II) fluoride; Palladium(IV) fluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Palladium(II,IV) fluoride, also known as palladium trifluoride, is a chemical compound of palladium and fluorine. It has the empirical formula PdF₃, but is better described as the mixed-valence compound palladium(II) hexafluoropalladate(IV), Pd^II[Pd^IVF₆], and is often written as Pd[PdF₆] or Pd₂F₆.^[1]^[2]

Synthesis

Pd[PdF₆] is the most stable product of the reaction of fluorine and metallic palladium.^[1]

2 Pd + 3 F₂ → Pd[PdF₆]

Structure and properties

Pd[PdF₆] is paramagnetic, and both Pd(II) and Pd(IV) occupy octahedral sites in the crystal structure.^[2]^[3] The Pd^II-F distance is 2.17 Å, whereas the Pd^IV-F distance is 1.90 Å.^[4]

Coordination environments of Pd^II and Pd^IV, showing different distances to F atoms

References

^ ^a ^b Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1152–1153. ISBN 978-0-08-037941-8.
^ ^a ^b Housecroft, C. E.; Sharpe, A. G. (2008). Inorganic Chemistry (3rd ed.). Prentice Hall. p. 788. ISBN 978-0-13-175553-6.
^ Hepworth, M. A.; Jack, K. H.; Peacock, R. D.; Westland, G. J. (1957). "The crystal structures of the trifluorides of iron, cobalt, ruthenium, rhodium, palladium and iridium". Acta Crystallogr. 10: 63–69. doi:10.1107/S0365110X57000158.
^ Tressaud, A.; Bartlett, N. (2001). "Preparation, Magnetic Properties, and Pressure-Induced Transitions of Some M^IIM^IVF₆ (M^II=Ni, Pd, Cu; M^IV=Pd, Pt, Sn) Complex Fluorides". J. Solid State Chem. 162 (2): 333–340. Bibcode:2001JSSCh.162..333T. doi:10.1006/jssc.2001.9331.

[G&E-1152-1153-1] Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1152–1153. ISBN 978-0-08-037941-8.

[Housecroft-788-2] Housecroft, C. E.; Sharpe, A. G. (2008). Inorganic Chemistry (3rd ed.). Prentice Hall. p. 788. ISBN 978-0-13-175553-6.

[Jack-3] Hepworth, M. A.; Jack, K. H.; Peacock, R. D.; Westland, G. J. (1957). "The crystal structures of the trifluorides of iron, cobalt, ruthenium, rhodium, palladium and iridium". Acta Crystallogr. 10: 63–69. doi:10.1107/S0365110X57000158.

[Tressaud-4] Tressaud, A.; Bartlett, N. (2001). "Preparation, Magnetic Properties, and Pressure-Induced Transitions of Some M^IIM^IVF₆ (M^II=Ni, Pd, Cu; M^IV=Pd, Pt, Sn) Complex Fluorides". J. Solid State Chem. 162 (2): 333–340. Bibcode:2001JSSCh.162..333T. doi:10.1006/jssc.2001.9331.

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[2]

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Palladium(II,IV) fluoride

Synthesis

Structure and properties

See also

References