Lutetium(Iii) Nitrate

From Handwiki
Lutetium(III) nitrate
Names
Other names
Lutetium trinitrate, Lutetium nitrate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 233-241-7
Properties
Lu(NO3)3
Molar mass 360.98
Appearance Colorless solid
Soluble
Hazards
GHS Signal word Warning
Related compounds
Related compounds
 Terbium(III) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Lutetium(III) nitrate is an inorganic compound, a salt of lutetium and nitric acid with the chemical formula Lu(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates.[1] The compound is poisonous.[2]

Synthesis

Dissolving lutetium oxide in nitric acid:

[math]\displaystyle{ \mathsf{ Lu_2O_3 + 6HNO_3 \ \xrightarrow{90^oC}\ 2Lu(NO_3)_3 + 3H_2O } }[/math]

To obtain anhydrous nitrate, the powdered metal is added to nitrogen dioxide dissolved in ethyl acetate:

[math]\displaystyle{ \mathsf{ Lu + 3N_2O_4 \ \xrightarrow{77^oC}\ Lu(NO_3)_3 + 3NO } }[/math]

Physical properties

Lutetium(III) nitrate forms colorless hygroscopic crystals.

Soluble in water and ethanol.

Forms crystalline hydrates of the composition Lu(NO3)3•nH2O, where n = 3, 4, 5, 6.[3]

Chemical properties

The hydrated lutetium nitrate thermally decomposes to form LuONO3 and decomposes to lutetium oxide upon further heating.[4]

The compound forms ammonium hexafluoroluthenate with ammonium fluoride:

[math]\displaystyle{ \mathsf{ Lu(NO_3)_3 + 6 NH_4F \ \xrightarrow{}\ (NH_4)_3[LuF_6]\downarrow + 3NH_4NO_3 } }[/math]

Applications

Lutetium(III) nitrate is used to obtain metallic lutetium and also as a chemical reagent.

It is used as a component of materials for the production of laser crystals.

References

  1. ↑ Edelmann, Frank T.; Herrmann, Wolfgang A. (14 May 2014) (in en). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 6, 1997: Volume 6: Lanthanides and Actinides. Georg Thieme Verlag. p. 23. ISBN 978-3-13-179221-1. https://books.google.com/books?id=6IuZAwAAQBAJ&dq=Ytterbium+(III)+nitrate&pg=PA226. Retrieved 19 August 2021. 
  2. ↑ Sr, Richard J. Lewis (13 June 2008) (in en). Hazardous Chemicals Desk Reference. John Wiley & Sons. p. 847. ISBN 978-0-470-18024-2. https://books.google.com/books?id=WZeBDwAAQBAJ&dq=Lutetium(III)+nitrate&pg=PA847. Retrieved 19 August 2021. 
  3. ↑ "Lutetium(III) nitrate hydrate". Sigma Aldrich. https://www.sigmaaldrich.com/RU/ru/substance/lutetiumiiinitratehydrate36098anhydrousbasis100641165. 
  4. ↑ Melnikov, P.; Arkhangelsky, I. V.; Nascimento, V. A.; de Oliveira, L. C. S.; Guimaraes, W. R.; Zanoni, L. Z. (February 2018). "Thermal decomposition of lutetium nitrate trihydrate Lu(NO3)3·3H2O". Journal of Thermal Analysis and Calorimetry 131 (2): 1269–1276. doi:10.1007/s10973-017-6644-2. 
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)−4 C NO−3,
NH4NO3 		O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3,
Fe(NO3)2 		Co(NO3)2,
Co(NO3)3 		Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb(NO3)3 Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2 		Tl(NO3)3,
TlNO3 		Pb(NO3)2 Bi(NO3)3
BiO(NO3) 		Po At Rn
FrNO3 Ra(NO3)2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La(NO3)3 Ce(NO3)3,
Ce(NO3)4 		Pr Nd(NO3)3 Pm Sm Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy Ho Er Tm Yb Lu
Ac(NO3)3 Th(NO3)4 Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr



Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Lutetium(III)_nitrate&oldid=2964688"

Categories: [Lutetium compounds] [Nitrates]

↧ Download as ZWI file | Last modified: 09/04/2024 19:10:32 | 4 views
☰ Source: https://handwiki.org/wiki/Chemistry:Lutetium(III)_nitrate | License: CC BY-SA 3.0

✘
ZWI is not signed. [what is this?]

ZWI viewer by the EncyclosphereKSF