Manganese Trioxide Fluoride

Manganese trioxide fluoride
Identifiers
CAS Number	15586-97-7;
3D model (JSmol)	Interactive image;
ChemSpider	57450402;
	InChI InChI=1S/FH.Mn.3O/h1H;;;;/q;+1;;;/p-1 Key: JWSFKFAINKAKTR-UHFFFAOYSA-M;
	SMILES O=[Mn](F)(=O)=O;
Properties
Chemical formula	FMnO3
Molar mass	121.933 g·mol−1
Appearance	green liquid
Density	6.042 g/cm3
Melting point	−45 °C (−49 °F; 228 K)
Boiling point	decomposition above its melting point
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Manganese trioxide fluoride is an inorganic compound with the formula MnO
3F. A green diamagnetic liquid, the compound has no applications, but it is of some academic interest as a rare example of a metal trioxide fluoride.

The compound was detected in the 1880s but was only purified and crystallized much more recently.^[1] It can be prepared by fluorosulfuric acid and potassium permanganate:

KMnO
4 + 2HF → MnO
3F + KF + H
2O

MnO
3F crystallizes as a monomer, as confirmed by X-ray crystallography. The molecules are tetrahedral with Mn-O and Mn-F distances of 1.59 and 1.72 Å, respectively.

In contrast with MnO
3F, TcO
3F and ReO
3F have more complex structures as solids. The Re compound crystallizes as chains or rings consisting of fluoride-bridge octahedra. TcO
3F crystallizes as dimers with fluoride bridges.^[2] The rhenium compound also forms stable adducts with Lewis bases,^[3] whereas the MnO
3F is unstable in the presence of Lewis bases.

References

↑ Schmidbaur, Hubert; Schwarz, W. H. Eugen (2021). "Permanganyl Fluoride: A Brief History of the Molecule MnO₃F and of Those Who Cared for It". Chemistry – A European Journal 27 (23): 6848–6859. doi:10.1002/chem.202004759. PMID 33219726.
↑ Supeł, Joanna; Abram, Ulrich; Hagenbach, Adelheid; Seppelt, Konrad (2007). "Technetium Fluoride Trioxide, TcO₃F, Preparation and Properties". Inorganic Chemistry 46 (14): 5591–5595. doi:10.1021/ic070333y. PMID 17547395.
↑ Supeł, Joanna; Marx, Rupert; Seppelt, Konrad (2005). "Preparation and Structure of Rhenium Fluoride Trioxide ReO₃F, and the Polymorphism of Rhenium Trifluoride Dioxide, ReO₂F₃". Zeitschrift für anorganische und allgemeine Chemie 631 (15): 2979–2986. doi:10.1002/zaac.200500239.

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[1] Schmidbaur, Hubert; Schwarz, W. H. Eugen (2021). "Permanganyl Fluoride: A Brief History of the Molecule MnO₃F and of Those Who Cared for It". Chemistry – A European Journal 27 (23): 6848–6859. doi:10.1002/chem.202004759. PMID 33219726.

[2] Supeł, Joanna; Abram, Ulrich; Hagenbach, Adelheid; Seppelt, Konrad (2007). "Technetium Fluoride Trioxide, TcO₃F, Preparation and Properties". Inorganic Chemistry 46 (14): 5591–5595. doi:10.1021/ic070333y. PMID 17547395.

[3] Supeł, Joanna; Marx, Rupert; Seppelt, Konrad (2005). "Preparation and Structure of Rhenium Fluoride Trioxide ReO₃F, and the Polymorphism of Rhenium Trifluoride Dioxide, ReO₂F₃". Zeitschrift für anorganische und allgemeine Chemie 631 (15): 2979–2986. doi:10.1002/zaac.200500239.

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Identifiers

CAS Number	15586-97-7
3D model (JSmol)	Interactive image
ChemSpider	57450402
InChI InChI=1S/FH.Mn.3O/h1H;;;;/q;+1;;;/p-1 Key: JWSFKFAINKAKTR-UHFFFAOYSA-M
SMILES O=[Mn](F)(=O)=O
Properties
Chemical formula	FMnO₃
Molar mass	121.933 g·mol⁻¹
Appearance	green liquid
Density	6.042 g/cm³
Melting point	−45 °C (−49 °F; 228 K)
Boiling point	decomposition above its melting point
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references