Borate Nitrate

Borate nitrates are mixed anion compounds containing separate borate and nitrate anions. They are distinct from the boronitrates where the borate is linked to a nitrate via a common oxygen atom.

List

	chem	mw	crystal system	space group	unit cell Å	volume	density	comment	references
	Na₃(NO₃)[B₆O₁₀]								^[1]
	K₃B₆O₁₀NO₃								^[2]
	K₃Na[B₆O₉(OH)₃]NO₃			Pnnm	a=13.208, b=9.107, c=12.325 Z=4				^[3]
	Co₃B₇O₁₃NO₃								^[4]
	[Co(H₂O)₆](NO₃)₂·[Co{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O								^[5]
	[Ni(H₂O)₆](NO₃)₂·[Ni{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O								^[5]
	Ni₃B₇O₁₃NO₃								^[4]
	K₇Ni[B₁₈O₂₄(OH)₉](NO₃)₆· (H₃BO₃)	1497.96	trigonal	R3	a=12.2229 c=54.784 Z=6	7088	2.11	green	^[6]
	Cu₃B₇O₁₃NO₃								^[4]
	Zn₃B₇O₁₃NO₃								^[4]
	[Zn(H₂O)₆](NO₃)₂·[Zn{B₃O₃(OH)₄}₂(H₂O)₄]·2H₂O		monoclinic	P2₁/c	a = 11.282, b = 6.5374, c = 17.668, β = 100.981°				^[5]
	Rb₃(NO₃)[B₆O₁₀]								^[2]
	Cd₃B₇O₁₃NO₃								^[4]
	La[B₅O₈(OH)]NO₃
	La[B₅O₈(OH)]NO₃·2H₂O		monoclinic	P2₁/n	a=6.540, b=15.550, c=10.672, β=90.44° and Z=4				^[7]
cerium(III) aquahydroxidooctaoxidopentaborate nitrate dihydrate	Ce[B₅O₈(OH)(H₂O)]NO₃·2H₂O	455.24	monoclinic	P2₁/n	a=6.444 b=15.572 c=10.745 β=90.395 Z=4	1078.2	2.904	colourless	^[8]
	Pr[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O		monoclinic	P2₁/n	a=6.419, b=15.518, c=10.684, with β=90.54° Z=4	1064.3			^[9]
	Pr₇(BO₃)₃(NO₃)N₃O		hexagonal	P6₃	a=10.6834 c=6.6752 Z=2		6.457	green; contains N(OBO₃)₃ clusters, oxide and nitride	^[10]
	Nd₇(BO₃)₃(NO₃)N₃O		hexagonal	P6₃	a=10.6446 c=6.6339 Z=2		6.664	purplish-blue;contains N(OBO₃)₃ clusters oxide, and nitride;SHG	^[10]
	Nd[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O			P2₁/n	a = 6.4285, b = 15.5258, c = 10.7052, β = 90.39°	1068.44			^[11]
	Sm[B₅O₈(OH)(H₂O)_x]NO₃·2H₂O			P2₁/n	a = 6.4409, b = 15.4199, c = 10.5097, β = 90.33°	1043.79			^[11]
	Lu₂B₂O₅(NO₃)₂·2H₂O		triclinic	P1	a=7.8952, b=9.8862, c=14.6033, α=90.83, β=101.75, γ=110.02° Z=4				^[6]^[12]
	Pb₂(BO₃)(NO₃)	535.20	hexagonal	P6₃mc	a=5.0731 c=13.040 Z=2	290.64	6.116	colourless SHG 9×KDP	^[13]
	[Pb₃(B₃O₇)](NO₃)	828.01		Pnma	a=10.3481 b=7.8908 c=11.2123 Z=4	914.54	6.007	colourless	^[14]

References

↑ Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10NO3 (x=0.5, 0.6, 0.7)"]. Zeitschrift für Naturforschung B 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. http://www.degruyter.com/view/j/znb.2017.72.issue-3/znb-2016-0242/znb-2016-0242.xml.
↑ ^2.0 ^2.1 Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate‐nitrates with noncentrosymmetric structures" (in en). European Journal of Inorganic Chemistry 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.202001167.
↑ Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3" (in en). Journal of Solid State Chemistry 221: 66–72. doi:10.1016/j.jssc.2014.09.016. Bibcode: 2015JSSCh.221...66O.
↑ ^4.0 ^4.1 ^4.2 ^4.3 ^4.4 Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F" (in en). Journal of Solid State Chemistry 10 (4): 302–311. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596. Bibcode: 1974JSSCh..10..302B. https://dx.doi.org/10.1016/0022-4596(74)90039-5.
↑ ^5.0 ^5.1 ^5.2 Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6(NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant"] (in en). Journal of Cluster Science 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-020-01806-7.
↑ ^6.0 ^6.1 Zoller, Michael; Wurst, Klaus; Huppertz, Hubert (2019-10-25). "Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)". Zeitschrift für Naturforschung B 74 (10): 757–764. doi:10.1515/znb-2019-0126. ISSN 1865-7117. CC-BY can use images
↑ Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao (October 2013). "Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks" (in en). Journal of Solid State Chemistry 206: 91–98. doi:10.1016/j.jssc.2013.07.032. Bibcode: 2013JSSCh.206...91Z.
↑ Sun, Wei; Zhu, Teng-Teng; Zhao, Biao-Chun; Huang, Ya-Xi; Mi, Jin-Xiao (2012-05-15). "Redetermination of Ce[B 5 O 8 (OH)(H 2 O)NO 3 ·2H 2 O"]. Acta Crystallographica Section E 68 (5): i33–i34. doi:10.1107/S1600536812016169. ISSN 1600-5368. PMID 22590053. PMC 3344287. http://scripts.iucr.org/cgi-bin/paper?S1600536812016169.
↑ Ortner, Teresa S.; Huppertz, Hubert (2017-09-26). "Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87NO3·2H2O"]. Zeitschrift für Naturforschung B 72 (9): 677–685. doi:10.1515/znb-2017-0121. ISSN 1865-7117. http://www.degruyter.com/view/j/znb.2017.72.issue-9/znb-2017-0121/znb-2017-0121.xml.
↑ ^10.0 ^10.1 Katrych, Sergiy; Arakcheeva, Alla; Sienkiewicz, Andrzej; Forró, László; Ivšić, Trpimir (2020-12-15). "High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation" (in en). Inorganic Chemistry 60 (1): 286–291. doi:10.1021/acs.inorgchem.0c02909. ISSN 0020-1669. PMID 33320648. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02909.
↑ ^11.0 ^11.1 Ortner, Teresa S.; Wurst, Klaus; Joachim, Bastian; Huppertz, Hubert (August 2016). "Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]: Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]"] (in en). European Journal of Inorganic Chemistry 2016 (22): 3659–3665. doi:10.1002/ejic.201600480. http://doi.wiley.com/10.1002/ejic.201600480.
↑ Ortner, Teresa S.; Wurst, Klaus; Hejny, Clivia; Huppertz, Hubert (January 2016). "Hydrothermal synthesis and characterization of the lutetium borate–nitrate Lu2B2O5(NO3)2·2H2O" (in en). Journal of Solid State Chemistry 233: 329–334. doi:10.1016/j.jssc.2015.11.005. Bibcode: 2016JSSCh.233..329O.
↑ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015-03-16). "A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units" (in en). Angewandte Chemie 127 (12): 3750–3753. doi:10.1002/ange.201412344. Bibcode: 2015AngCh.127.3750S. http://doi.wiley.com/10.1002/ange.201412344.
↑ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2013-08-05). "Pb 2 B 3 O 5.5 (OH) 2 and [Pb 3 (B 3 O 7 )(NO 3 ): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems"] (in en). Inorganic Chemistry 52 (15): 8979–8986. doi:10.1021/ic401175r. ISSN 0020-1669. PMID 23834222. https://pubs.acs.org/doi/10.1021/ic401175r.

Salts and covalent derivatives of the nitrate ion

HNO₃

He

LiNO₃

Be(NO₃)₂

B(NO₃)−4

C

NO−3,
NH₄NO₃

O

FNO₃

Ne

NaNO₃

Mg(NO₃)₂

Al(NO₃)₃

Si

P

S

ClONO₂

Ar

KNO₃

Ca(NO₃)₂

Sc(NO₃)₃

Ti(NO₃)₄

VO(NO₃)₃

Cr(NO₃)₃

Mn(NO₃)₂

Fe(NO₃)₃,
Fe(NO₃)₂

Co(NO₃)₂,
Co(NO₃)₃

Ni(NO₃)₂

Cu(NO₃)₂

Zn(NO₃)₂

Ga(NO₃)₃

Ge

As

Se

Br

Kr

RbNO₃

Sr(NO₃)₂

Y(NO₃)₃

Zr(NO₃)₄

Nb

Mo

Tc

Ru

Rh

Pd(NO₃)₂

AgNO₃

Cd(NO₃)₂

In

Sn

Sb(NO₃)₃

Te

I

Xe(NO₃)₂

CsNO₃

Ba(NO₃)₂

Hf

Ta

W

Re

Os

Ir

Pt

Au

Hg₂(NO₃)₂,
Hg(NO₃)₂

Tl(NO₃)₃,
TlNO₃

Pb(NO₃)₂

Bi(NO₃)₃
BiO(NO₃)

Po

At

Rn

FrNO₃

Ra(NO₃)₂

Rf

Db

Sg

Bh

Hs

Mt

Ds

Rg

Cn

Nh

Fl

Mc

Lv

Ts

Og

↓

La(NO₃)₃

Ce(NO₃)₃,
Ce(NO₃)₄

Pr

Nd(NO₃)₃

Pm

Sm

Eu(NO₃)₃

Gd(NO₃)₃

Tb(NO₃)₃

Dy

Ho

Er

Tm

Yb

Lu

Ac(NO₃)₃

Th(NO₃)₄

Pa

UO₂(NO₃)₂

Np

Pu

Am

Cm

Bk

Cf

Es

Fm

Md

No

Lr

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Borate nitrate. Read more

[1] Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10NO3 (x=0.5, 0.6, 0.7)"]. Zeitschrift für Naturforschung B 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. http://www.degruyter.com/view/j/znb.2017.72.issue-3/znb-2016-0242/znb-2016-0242.xml.

[:5-2] 2.0 ^2.1 Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate‐nitrates with noncentrosymmetric structures" (in en). European Journal of Inorganic Chemistry 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.202001167.

[3] Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3" (in en). Journal of Solid State Chemistry 221: 66–72. doi:10.1016/j.jssc.2014.09.016. Bibcode: 2015JSSCh.221...66O.

[:0-4] 4.0 ^4.1 ^4.2 ^4.3 ^4.4 Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F" (in en). Journal of Solid State Chemistry 10 (4): 302–311. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596. Bibcode: 1974JSSCh..10..302B. https://dx.doi.org/10.1016/0022-4596(74)90039-5.

[:3-5] 5.0 ^5.1 ^5.2 Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6(NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant"] (in en). Journal of Cluster Science 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-020-01806-7.

[:1-6] 6.0 ^6.1 Zoller, Michael; Wurst, Klaus; Huppertz, Hubert (2019-10-25). "Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)". Zeitschrift für Naturforschung B 74 (10): 757–764. doi:10.1515/znb-2019-0126. ISSN 1865-7117. CC-BY can use images

[7] Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao (October 2013). "Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks" (in en). Journal of Solid State Chemistry 206: 91–98. doi:10.1016/j.jssc.2013.07.032. Bibcode: 2013JSSCh.206...91Z.

[8] Sun, Wei; Zhu, Teng-Teng; Zhao, Biao-Chun; Huang, Ya-Xi; Mi, Jin-Xiao (2012-05-15). "Redetermination of Ce[B 5 O 8 (OH)(H 2 O)NO 3 ·2H 2 O"]. Acta Crystallographica Section E 68 (5): i33–i34. doi:10.1107/S1600536812016169. ISSN 1600-5368. PMID 22590053. PMC 3344287. http://scripts.iucr.org/cgi-bin/paper?S1600536812016169.

[9] Ortner, Teresa S.; Huppertz, Hubert (2017-09-26). "Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87NO3·2H2O"]. Zeitschrift für Naturforschung B 72 (9): 677–685. doi:10.1515/znb-2017-0121. ISSN 1865-7117. http://www.degruyter.com/view/j/znb.2017.72.issue-9/znb-2017-0121/znb-2017-0121.xml.

[:4-10] 10.0 ^10.1 Katrych, Sergiy; Arakcheeva, Alla; Sienkiewicz, Andrzej; Forró, László; Ivšić, Trpimir (2020-12-15). "High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation" (in en). Inorganic Chemistry 60 (1): 286–291. doi:10.1021/acs.inorgchem.0c02909. ISSN 0020-1669. PMID 33320648. https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02909.

[:2-11] 11.0 ^11.1 Ortner, Teresa S.; Wurst, Klaus; Joachim, Bastian; Huppertz, Hubert (August 2016). "Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]: Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]"] (in en). European Journal of Inorganic Chemistry 2016 (22): 3659–3665. doi:10.1002/ejic.201600480. http://doi.wiley.com/10.1002/ejic.201600480.

[12] Ortner, Teresa S.; Wurst, Klaus; Hejny, Clivia; Huppertz, Hubert (January 2016). "Hydrothermal synthesis and characterization of the lutetium borate–nitrate Lu2B2O5(NO3)2·2H2O" (in en). Journal of Solid State Chemistry 233: 329–334. doi:10.1016/j.jssc.2015.11.005. Bibcode: 2016JSSCh.233..329O.

[13] Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015-03-16). "A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units" (in en). Angewandte Chemie 127 (12): 3750–3753. doi:10.1002/ange.201412344. Bibcode: 2015AngCh.127.3750S. http://doi.wiley.com/10.1002/ange.201412344.

[14] Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2013-08-05). "Pb 2 B 3 O 5.5 (OH) 2 and [Pb 3 (B 3 O 7 )(NO 3 ): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems"] (in en). Inorganic Chemistry 52 (15): 8979–8986. doi:10.1021/ic401175r. ISSN 0020-1669. PMID 23834222. https://pubs.acs.org/doi/10.1021/ic401175r.