Ytterbium(Iii) Nitrate

Ytterbium(III) nitrate
Names
	Other names Ytterbium trinitrate, Ytterbium nitrate
Identifiers
CAS Number	13768-67-7 ; monohydrate: 35725-34-9;
3D model (JSmol)	Interactive image;
ChemSpider	32748884; monohydrate: 29434727;
EC Number	237-384-6;
PubChem CID	monohydrate: 91886286; pentahydrate: 16211525; hexahydrate: 203097;
	InChI InChI=1S/HNO3.Yb/c2-1(3)4;/h(H,2,3,4); Key: IKWXNJJIPMAOHU-UHFFFAOYSA-N;
	SMILES N(=O)(=O)O.[Yb];
Properties
Chemical formula	Yb(NO3)3
Molar mass	359.06
Appearance	Colorless solid
Solubility in water	Soluble
Hazards
GHS pictograms
GHS Signal word	Warning
GHS hazard statements	H272, H315, H319, H335
GHS precautionary statements	P210, P220, P221, P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P370+378, P403+233, P405, P501
Related compounds
Related compounds	Terbium(III) nitrate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Ytterbium(III) nitrate is an inorganic compound, a salt of ytterbium and nitric acid with the chemical formula Yb(NO₃)₃.^[2] The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates.^[3]^[4]

Synthesis

Reaction of ytterbium and nitric oxide in ethyl acetate:

[math]\displaystyle{ \mathsf{Yb + 3N_2O_4 \ \xrightarrow{}\ Yb(NO_3)_3 + 3NO\uparrow } }[/math]

Reaction of ytterbium hydroxide and nitric acid:

[math]\displaystyle{ \mathsf{Yb(OH)_3 + 3HNO_3 \ \xrightarrow{}\ Yb(NO_3)_3 + 3H_2O\uparrow } }[/math]

Physical properties

Ytterbium(III) nitrate forms colorless hygroscopic crystals.

Soluble in water and ethanol.

Forms crystalline hydrates of the composition [math]\ce{ Yb(NO3)3*nH2O }[/math], where n = 4, 5, 6.^[5]

Chemical properties

The hydrated ytterbium nitrate thermally decomposes to form YbONO₃ and decomposes to ytterbium oxide upon further heating.

Application

Ytterbium(III) nitrate hydrate is used for nanoscale coatings of carbon composites.^[6]

Also used to obtain metallic ytterbium and as a chemical reagent.

Used as a component for the production of ceramics and glass.

References

↑ Macintyre, Jane E. (23 July 1992) (in en). Dictionary of Inorganic Compounds. CRC Press. p. 3621. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&dq=Ytterbium+(III)+nitrate&pg=PA3621. Retrieved 19 August 2021.
↑ Лидин, Ростислав; Молочко, Вадим; Андреева, Лариса (2 February 2019) (in ru). Константы неорганических веществ. Справочник. Litres. p. 69. ISBN 978-5-04-077039-7. https://books.google.com/books?id=-cQ0DwAAQBAJ&dq=нитрат+иттербия&pg=PA69. Retrieved 19 August 2021.
↑ "Ytterbium(III) nitrate pentahydrate". Sigma Aldrich. https://www.sigmaaldrich.com/RU/ru/product/aldrich/209147.
↑ Edelmann, Frank T.; Herrmann, Wolfgang A. (14 May 2014) (in en). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 6, 1997: Volume 6: Lanthanides and Actinides. Georg Thieme Verlag. p. 23. ISBN 978-3-13-179221-1. https://books.google.com/books?id=6IuZAwAAQBAJ&dq=Ytterbium+(III)+nitrate&pg=PA226. Retrieved 19 August 2021.
↑ "Ytterbium(III) nitrate pentahydrate" (in en). pubchem.ncbi.nlm.nih.gov. https://pubchem.ncbi.nlm.nih.gov/compound/Ytterbium_III_-nitrate-pentahydrate.
↑ "12901 Ytterbium(III) nitrate hydrate, 99.9% (REO)". Alfa Aesar. https://www.alfa.com/en/catalog/012901/.

Salts and covalent derivatives of the nitrate ion

HNO₃

He

LiNO₃

Be(NO₃)₂

B(NO₃)−4

C

NO−3,
NH₄NO₃

O

FNO₃

Ne

NaNO₃

Mg(NO₃)₂

Al(NO₃)₃

Si

P

S

ClONO₂

Ar

KNO₃

Ca(NO₃)₂

Sc(NO₃)₃

Ti(NO₃)₄

VO(NO₃)₃

Cr(NO₃)₃

Mn(NO₃)₂

Fe(NO₃)₃,
Fe(NO₃)₂

Co(NO₃)₂,
Co(NO₃)₃

Ni(NO₃)₂

Cu(NO₃)₂

Zn(NO₃)₂

Ga(NO₃)₃

Ge

As

Se

Br

Kr

RbNO₃

Sr(NO₃)₂

Y(NO₃)₃

Zr(NO₃)₄

Nb

Mo

Tc

Ru

Rh

Pd(NO₃)₂

AgNO₃

Cd(NO₃)₂

In

Sn

Sb(NO₃)₃

Te

I

Xe(NO₃)₂

CsNO₃

Ba(NO₃)₂

Hf

Ta

W

Re

Os

Ir

Pt

Au

Hg₂(NO₃)₂,
Hg(NO₃)₂

Tl(NO₃)₃,
TlNO₃

Pb(NO₃)₂

Bi(NO₃)₃
BiO(NO₃)

Po

At

Rn

FrNO₃

Ra(NO₃)₂

Rf

Db

Sg

Bh

Hs

Mt

Ds

Rg

Cn

Nh

Fl

Mc

Lv

Ts

Og

↓

La(NO₃)₃

Ce(NO₃)₃,
Ce(NO₃)₄

Pr

Nd(NO₃)₃

Pm

Sm

Eu(NO₃)₃

Gd(NO₃)₃

Tb(NO₃)₃

Dy

Ho

Er

Tm

Yb

Lu

Ac(NO₃)₃

Th(NO₃)₄

Pa

UO₂(NO₃)₂

Np

Pu

Am

Cm

Bk

Cf

Es

Fm

Md

No

Lr

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Original source: https://en.wikipedia.org/wiki/Ytterbium(III) nitrate. Read more

[1] Macintyre, Jane E. (23 July 1992) (in en). Dictionary of Inorganic Compounds. CRC Press. p. 3621. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&dq=Ytterbium+(III)+nitrate&pg=PA3621. Retrieved 19 August 2021.

[2] Лидин, Ростислав; Молочко, Вадим; Андреева, Лариса (2 February 2019) (in ru). Константы неорганических веществ. Справочник. Litres. p. 69. ISBN 978-5-04-077039-7. https://books.google.com/books?id=-cQ0DwAAQBAJ&dq=нитрат+иттербия&pg=PA69. Retrieved 19 August 2021.

[3] "Ytterbium(III) nitrate pentahydrate". Sigma Aldrich. https://www.sigmaaldrich.com/RU/ru/product/aldrich/209147.

[4] Edelmann, Frank T.; Herrmann, Wolfgang A. (14 May 2014) (in en). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 6, 1997: Volume 6: Lanthanides and Actinides. Georg Thieme Verlag. p. 23. ISBN 978-3-13-179221-1. https://books.google.com/books?id=6IuZAwAAQBAJ&dq=Ytterbium+(III)+nitrate&pg=PA226. Retrieved 19 August 2021.

[5] "Ytterbium(III) nitrate pentahydrate" (in en). pubchem.ncbi.nlm.nih.gov. https://pubchem.ncbi.nlm.nih.gov/compound/Ytterbium_III_-nitrate-pentahydrate.

[6] "12901 Ytterbium(III) nitrate hydrate, 99.9% (REO)". Alfa Aesar. https://www.alfa.com/en/catalog/012901/.

v t e Ytterbium compounds
Yb(II)	YbCl₂
Yb(III)	YbBr₃ YbCl₃ YbF₃ Yb₂O₃ Yb₂(SO₄)₃
Other	YbRh₂Si₂