Neodymium Nickelate

Neodymium nickelate
Names
	Other names Neodymium(III) nickelate
Identifiers
CAS Number	11132-41-5 ;
3D model (JSmol)	Interactive image;
	InChI InChI=1S/Nd.Ni.3O/q2+3;3-2 Key: QDQFJKLUAHCIBS-UHFFFAOYSA-N;
	SMILES [Nd+3].[Ni+3].[O-2].[O-2].[O-2];
Properties
Chemical formula	NdNiO3
Molar mass	250.932 g·mol−1
Hazards
GHS pictograms
GHS Signal word	Danger
GHS hazard statements	H317, H350, H372
GHS precautionary statements	P261, P280, P263, P405, P501
Related compounds
Other anions	Neodymium(III) oxide; Neodymium(III) acetate; Neodymium(III) hydride
Other cations	europium nickelate; lanthanum nickelate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Neodymium nickelate is a nickelate of neodymium with a chemical formula NdNiO₃. In this compound, the neodymium atom is in the +3 oxidation state.

Preparation

Neodymium nickelate can be prepared by dissolving neodymium(III) oxide and nickel(II) oxide in nitric acid, followed by heating the mixture in an oxygen atmosphere.^[2]

It can also be prepared by pyrolyzing a mixture of nickel nitrate and neodymium nitrate.^[2]^[3]

It decomposes in high temperature (950 °C) by nitrogen:^[2]

4 NdNiO₃ → 2 Nd₂NiO₄ + 2 NiO + O₂

It can also be reduced to the monovalent nickel compound NdNiO₂ by sodium hydride at 160°C.^[4]

Physical properties

Neodymium nickelate shows metal-insulator transition (MIT) under low temperature.^[5]^[6] The temperature at which it transforms (T_MIT) is 400K,^[7] which is higher than praseodymium nickelate (200K) but lower than samarium nickelate (460K).^[5]^[7]^[8] It transforms from antiferromagnetism to paramagnetism. It has demonstrated to be a first-order phase transition (this applies for praseodymium nickelate as well).^[5] The temperature (T_N) can be changed by varying the NiO₆ octahedral distortion.^[5]^[6] It is the only lathanide nickelate to have the same T_MIT as T_N.^[5]

Uses

In a 2010 study, it was found that neodymium nickelate as an anode material provided 1.7 times the current density of typical LSM anodes when integrated into a commercial SOEC and operated at 700 °C, and approximately 4 times the current density when operated at 800 °C. The increased performance is postulated to be due to higher "overstoichiometry" of oxygen in the neodymium nickelate, making it a successful conductor of both ions and electrons.^[9]

Neodymium nickelate can also be used in electrocatalysts, synapse transistors, photovoltaics, memory resistors, biosensors, and electric-field sensors.^[5]

References

↑ "Safety Data Sheet Neodymium Nickel Oxide". LTS Research Laboratories, Inc.. 13 July 2015. https://www.ltschem.com/msds/NdNiO3.pdf.
↑ ^2.0 ^2.1 ^2.2 Vassiliou, John K.; Hornbostel, Marc; Ziebarth, Robin; Disalvo, F.J. (1989). "Synthesis and properties of NdNiO3 prepared by low-temperature methods". Journal of Solid State Chemistry (Elsevier BV) 81 (2): 208–216. doi:10.1016/0022-4596(89)90008-x. ISSN 0022-4596. Bibcode: 1989JSSCh..81..208V.
↑ M.T. Escote, A.M.L. da Silva, J.R. Matos, R.F. Jardim (May 2000). "General Properties of Polycrystalline LnNiO3 (Ln=Pr, Nd, Sm) Compounds Prepared through Different Precursors" (in en). Journal of Solid State Chemistry 151 (2): 298–307. doi:10.1006/jssc.2000.8657. Bibcode: 2000JSSCh.151..298E. https://linkinghub.elsevier.com/retrieve/pii/S0022459600986572. Retrieved 2022-03-18.
↑ M.A. Hayward, M.J. Rosseinsky (June 2003). "Synthesis of the infinite layer Ni(I) phase NdNiO2+x by low temperature reduction of NdNiO3 with sodium hydride" (in en). Solid State Sciences 5 (6): 839–850. doi:10.1016/S1293-2558(03)00111-0. Bibcode: 2003SSSci...5..839H. https://linkinghub.elsevier.com/retrieve/pii/S1293255803001110. Retrieved 2022-03-18.
↑ ^5.0 ^5.1 ^5.2 ^5.3 ^5.4 ^5.5 Hongwei Yang, Zhiwei Wen, Jun Shu, Yajing Cui, Yongliang Chen, Yong Zhao, Structural, electrical, and magnetic properties of bulk Nd1-xSrxNiO3 (x = 0–0.3), Solid State Communications, Volume 336, 2021, 114420, ISSN 0038-1098, https://doi.org/10.1016/j.ssc.2021.114420.
↑ ^6.0 ^6.1 Subir Roy, Rajesh Katoch, R.B. Gangineni, S. Angappane, Investigation of metal-insulator transition temperature and magnetic properties of NdNiO3 nanoparticles, Journal of Solid State Chemistry, Volume 294, 2021, 121865, ISSN 0022-4596, https://doi.org/10.1016/j.jssc.2020.121865.
↑ ^7.0 ^7.1 Lafez, P.; Ruello, P.; Edely, M. (2008). "Electrical and Infrared Properties of RF Sputtering of Rare Earth Nickelate (RNiO₃) Thin Films with Metal Insulator-Transitions". in Lamont, Paul W. (in en). Leading-Edge Materials Science Research. Nova Publishers. pp. 277–310. ISBN 9781600217982. https://books.google.com/books?id=3-3FL5ii01YC&pg=PA277. Retrieved 21 April 2016.
↑ Jorgensen, Finn. The Complete Handbook of Magnetic Recording; McGraw-Hill, 1996.
↑ Chauveau, F., Mougin, J., Bassat, J. M., Mauvy, F., & Grenier, J. C. (2010). A new anode material for solid oxide electrolyser: The neodymium nickelate. Journal of Power Sources, 195, 744–749. doi:10.1016/j.jpowsour.2009.08.003

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Original source: https://en.wikipedia.org/wiki/Neodymium nickelate. Read more

[1] "Safety Data Sheet Neodymium Nickel Oxide". LTS Research Laboratories, Inc.. 13 July 2015. https://www.ltschem.com/msds/NdNiO3.pdf.

[john-2] 2.0 ^2.1 ^2.2 Vassiliou, John K.; Hornbostel, Marc; Ziebarth, Robin; Disalvo, F.J. (1989). "Synthesis and properties of NdNiO3 prepared by low-temperature methods". Journal of Solid State Chemistry (Elsevier BV) 81 (2): 208–216. doi:10.1016/0022-4596(89)90008-x. ISSN 0022-4596. Bibcode: 1989JSSCh..81..208V.

[3] M.T. Escote, A.M.L. da Silva, J.R. Matos, R.F. Jardim (May 2000). "General Properties of Polycrystalline LnNiO3 (Ln=Pr, Nd, Sm) Compounds Prepared through Different Precursors" (in en). Journal of Solid State Chemistry 151 (2): 298–307. doi:10.1006/jssc.2000.8657. Bibcode: 2000JSSCh.151..298E. https://linkinghub.elsevier.com/retrieve/pii/S0022459600986572. Retrieved 2022-03-18.

[4] M.A. Hayward, M.J. Rosseinsky (June 2003). "Synthesis of the infinite layer Ni(I) phase NdNiO2+x by low temperature reduction of NdNiO3 with sodium hydride" (in en). Solid State Sciences 5 (6): 839–850. doi:10.1016/S1293-2558(03)00111-0. Bibcode: 2003SSSci...5..839H. https://linkinghub.elsevier.com/retrieve/pii/S1293255803001110. Retrieved 2022-03-18.

[Magnetism_of_Neodymium_Nickelate-5] 5.0 ^5.1 ^5.2 ^5.3 ^5.4 ^5.5 Hongwei Yang, Zhiwei Wen, Jun Shu, Yajing Cui, Yongliang Chen, Yong Zhao, Structural, electrical, and magnetic properties of bulk Nd1-xSrxNiO3 (x = 0–0.3), Solid State Communications, Volume 336, 2021, 114420, ISSN 0038-1098, https://doi.org/10.1016/j.ssc.2021.114420.

[nanoparticles-6] 6.0 ^6.1 Subir Roy, Rajesh Katoch, R.B. Gangineni, S. Angappane, Investigation of metal-insulator transition temperature and magnetic properties of NdNiO3 nanoparticles, Journal of Solid State Chemistry, Volume 294, 2021, 121865, ISSN 0022-4596, https://doi.org/10.1016/j.jssc.2020.121865.

[mit-7] 7.0 ^7.1 Lafez, P.; Ruello, P.; Edely, M. (2008). "Electrical and Infrared Properties of RF Sputtering of Rare Earth Nickelate (RNiO₃) Thin Films with Metal Insulator-Transitions". in Lamont, Paul W. (in en). Leading-Edge Materials Science Research. Nova Publishers. pp. 277–310. ISBN 9781600217982. https://books.google.com/books?id=3-3FL5ii01YC&pg=PA277. Retrieved 21 April 2016.

[8] Jorgensen, Finn. The Complete Handbook of Magnetic Recording; McGraw-Hill, 1996.

[9] Chauveau, F., Mougin, J., Bassat, J. M., Mauvy, F., & Grenier, J. C. (2010). A new anode material for solid oxide electrolyser: The neodymium nickelate. Journal of Power Sources, 195, 744–749. doi:10.1016/j.jpowsour.2009.08.003

v t e Nickel compounds
Nickel(0)	Ni(CO)₄ Ni(COD)₂
Nickel(II)	NiBr₂ NiCO₃ NiCl₂ NiCrO₄ NiF₂ NiI₂ Ni(NO₂)₂ Ni(NO₃)₂ NiO Ni(OH)₂ Ni₃(PO₄)₂ NiS NiSO₄ NiTiO₃ Ni(acac)₂ $x$ Ni(NO₂)₆ $x$ NiF₄ $x$ NiCl₄ $x$ NiBr₄ $x$ NiI₄
Nickel(III)	Ni₂O₃ NiOOH
Nickel(IV)	K₂NiF₆ MNiO_$x$

Neodymium Nickelate

Contents

Preparation

Physical properties

Uses

See also

References