From Citizendium 
A molten salt reactor (MSR) is a class of nuclear fission reactor[1] in which the primary coolant and/or the fuel is a molten salt mixture.[2] Molten salt reactors have two advantages over Pressurized Water Reactors: 1) they operate at a much higher temperature and are thus more efficient, and 2) they operate at low pressure, reducing the risk of a massive steam explosion. The radioactive fuels are dissolved in the molten salt, and are chemically bound to the salt if it leaks from the reactor, or is dumped to drain tanks in an emergency. MSRs can be designed to eliminate the possibility of a meltdown. If the molten salt ever gets too hot, a plug at the bottom of the reactor melts, and the fuel is drained. No operator intervention is required. The reactors are "walk-away safe".
Only two molten salt reactors have ever operated, both research reactors in the United States of America. The 1950's Aircraft Reactor Experiment[3] was primarily motivated by the compact size that the technique offers, while the 1960's Molten-Salt Reactor Experiment aimed to prove the concept of a nuclear power plant which implements a thorium fuel cycle in a breeder reactor. Increased research into Generation IV reactor designs began to renew interest in the technology, with multiple nations having projects and, as of September 2021, China is on the verge of starting its TMSR-LF1 thorium MSR.[4]
Molten salt reactors are considered safer than conventional reactors because they operate with fuel already in a molten state, and in event of an emergency, the fuel mixture is designed to drain from the core where it will solidify, preventing the type of nuclear meltdown and associated hydrogen explosions (like what happened in the Fukushima nuclear disaster) that are at risk in conventional (solid-fuel) reactors.
A further key characteristic of molten salt reactors is operating temperatures of around 700C, significantly higher than traditional light-water reactors at around 300C, providing greater electricity-generation efficiency, the possibility of grid-storage facilities, economical hydrogen production, and, in some cases, process-heat opportunities. Relevant design challenges include the corrosivity of hot salts and the changing chemical composition of the salt as it is transmuted by the neutron flux in the reactor core.
MSRs offer multiple advantages over conventional nuclear power plants, although for historical reasons they have not been deployed.
MSRs, especially those with the fuel dissolved in the salt, differ considerably from conventional reactors. Reactor core pressure can be low and the temperature much higher. In this respect an MSR is more similar to a liquid metal cooled reactor than to a conventional light water cooled reactor. MSRs are often planned as breeding reactors with a closed fuel cycle—as opposed to the once-through fuel currently used in U.S. nuclear reactors.
Safety concepts rely on a negative temperature coefficient of reactivity and a large possible temperature rise to limit reactivity excursions. As an additional method for shutdown, a separate, passively cooled container below the reactor can be included. In case of problems, and for regular maintenance, the fuel is drained from the reactor. This stops the nuclear reaction and acts as a second cooling system. Neutron-producing accelerators have been proposed for some super-safe subcritical experimental designs.[5]
The temperatures of some proposed designs are high enough to produce process heat for hydrogen production or other chemical reactions. Because of this, they are included in the GEN-IV roadmap for further study.[6]
MSRs offer many potential advantages over current light water reactors:[7]
Molten salt reactors can be cooled in various ways, including using molten salts.
Molten-salt-cooled solid-fuel reactors are variously called "molten salt reactor system" in the Generation IV proposal, molten salt converter reactors (MSCR), advanced high-temperature reactors (AHTRs), or fluoride high-temperature reactors (FHR, preferred DOE designation).[13]
A fluoride high-temperature reactor cannot reprocess fuel easily and has fuel rods that need to be fabricated and validated, requiring up to twenty years from project inception. It retains the safety and cost advantages of a low-pressure, high-temperature coolant, also shared by liquid metal cooled reactors. Notably, steam is not created in the core (as is present in BWRs), and no large, expensive steel pressure vessel (as required for pressurized water reactors). Since it can operate at high temperatures, the conversion of the heat to electricity can use an efficient, lightweight Brayton cycle gas turbine.
Much of the current research on FHRs is focused on small, compact heat exchangers that reduce molten salt volumes and associated costs.[14]
Molten salts can be highly corrosive and corrosivity increases with temperature. For the primary cooling loop, a material is needed that can withstand corrosion at high temperatures and intense radiation. Experiments show that Hastelloy-N and similar alloys are suited to these tasks at operating temperatures up to about 700 °C. However, operating experience is limited. Still higher operating temperatures are desirable—at 850 °C thermochemical production of hydrogen becomes possible. Materials for this temperature range have not been validated, though carbon composites, molybdenum alloys (e.g. TZM), carbides, and refractory metal based or ODS alloys might be feasible.
A workaround suggested by a private researcher is to use the new beta-titanium Au alloys as this would also allow extreme temperature operation as well as increasing the safety margin.

The salt mixtures are chosen to make the reactor safer and more practical.
Fluorine has only one stable isotope (F-19), and does not easily become radioactive under neutron bombardment. Compared to chlorine and other halides, fluorine also absorbs fewer neutrons and slows ("moderates") neutrons better. Low-valence fluorides boil at high temperatures, though many pentafluorides and hexafluorides boil at low temperatures. They must be very hot before they break down into their constituent elements. Such molten salts are "chemically stable" when maintained well below their boiling points. Fluoride salts dissolve poorly in water, and do not form burnable hydrogen.
Chlorine has two stable isotopes ( Template:Chem/link
and
Template:Chem/link ), as well as a slow-decaying isotope between them which facilitates neutron absorption by Template:Chem/link .
Chlorides permit fast breeder reactors to be constructed. Much less research has been done on reactor designs using chloride salts. Chlorine, unlike fluorine, must be purified to isolate the heavier stable isotope, chlorine-37, thus reducing production of sulfur tetrachloride that occurs when chlorine-35 absorbs a neutron to become chlorine-36, then degrades by beta decay to sulfur-36.
Lithium must be in the form of purified Lithium, because Lithium effectively captures neutrons and produces tritium. Even if pure 7Li is used, salts containing lithium cause significant tritium production, comparable with heavy water reactors.
Reactor salts are usually close to eutectic mixtures to reduce their melting point. A low melting point simplifies melting the salt at startup and reduces the risk of the salt freezing as it is cooled in the heat exchanger.
Due to the high "redox window" of fused fluoride salts, the redox potential of the fused salt system can be changed. Fluorine-lithium-beryllium ("FLiBe") can be used with beryllium additions to lower the redox potential and nearly eliminate corrosion. However, since beryllium is extremely toxic, special precautions must be engineered into the design to prevent its release into the environment. Many other salts can cause plumbing corrosion, especially if the reactor is hot enough to make highly reactive hydrogen.
To date, most research has focused on FLiBe, because lithium and beryllium are reasonably effective moderators and form a eutectic salt mixture with a lower melting point than each of the constituent salts. Beryllium also performs neutron doubling, improving the neutron economy. This process occurs when the beryllium nucleus emits two neutrons after absorbing a single neutron. For the fuel carrying salts, generally 1% or 2% (by mole) of UF4 is added. Thorium and plutonium fluorides have also been used.
Techniques for preparing and handling molten salt were first developed at ORNL.[15] The purpose of salt purification is to eliminate oxides, sulfur and metal impurities. Oxides could result in the deposition of solid particles in reactor operation. Sulfur must be removed because of its corrosive attack on nickel-based alloys at operational temperature. Structural metal such as chromium, nickel, and iron must be removed for corrosion control.
A water content reduction purification stage using HF and helium sweep gas was specified to run at 400 °C. Oxide and sulfur contamination in the salt mixtures were removed using gas sparging of HF – H2 mixture, with the salt heated to 600 °C.[15][[]] Structural metal contamination in the salt mixtures were removed using hydrogen gas sparging, at 700 °C.[15][[]] Solid ammonium hydrofluoride was proposed as a safer alternative for oxide removal.[16]
The possibility of online processing can be an MSR advantage. Continuous processing would reduce the inventory of fission products, control corrosion and improve neutron economy by removing fission products with high neutron absorption cross-section, especially xenon. This makes the MSR particularly suited to the neutron-poor thorium fuel cycle. Online fuel processing can introduce risks of fuel processing accidents,[17][[]] which can trigger release of radio isotopes.
In some thorium breeding scenarios, the intermediate product protactinium Template:Chem/link
would be removed from the reactor and allowed to decay into highly pure Uranium, an attractive bomb-making material. More modern designs propose to use a lower specific power or a separate thorium breeding blanket. This dilutes the protactinium to such an extent that few protactinium atoms absorb a second neutron or, via a (n, 2n) reaction (in which an incident neutron is not absorbed but instead knocks a neutron out of the nucleus), generate
Template:Chem/link . Because Template:Chem/link
has a short half-life and its decay chain contains hard gamma emitters, it makes the isotopic mix of uranium less attractive for bomb-making. This benefit would come with the added expense of a larger fissile inventory or a 2-fluid design with a large quantity of blanket salt.
The necessary fuel salt reprocessing technology has been demonstrated, but only at laboratory scale. A prerequisite to full-scale commercial reactor design is the R&D to engineer an economically competitive fuel salt cleaning system.

Reprocessing refers to the chemical separation of fissionable uranium and plutonium from spent fuel.[18] Such recovery could increase the risk of nuclear proliferation. In the United States the regulatory regime has varied dramatically across administrations.[18]
A systematic literature review from 2020 concludes that there is very limited information on economics and finance of MSRs, with low quality of the information and that cost estimations are uncertain.[19]
In the specific case of the stable salt reactor (SSR) where the radioactive fuel is contained as a molten salt within fuel pins and the primary circuit is not radioactive, operating costs are likely to be lower.[20]Template:Verify sourceTemplate:Additional citation needed
While many design variants have been proposed, there are three main categories regarding the role of molten salt:
| Category | Examples |
|---|---|
| Molten salt fuel - circulating | ARETemplate:• AWBTemplate:• CMSRTemplate:• DMSRTemplate:• EVOLTemplate:• LFTRTemplate:• IMSRTemplate:• MSFRTemplate:• MSRETemplate:• DFRTemplate:• TMSR-500Template:• TMSR-LF |
| Molten salt fuel - static | SSR |
| Molten salt coolant only | FHRTemplate:• TMSR-SF |
The use of molten salt as fuel and as coolant are independent design choices - the original circulating-fuel-salt MSRE and the more recent static-fuel-salt SSR use salt as fuel and salt as coolant; the DFR uses salt as fuel but metal as coolant; and the FHR has solid fuel but salt as coolant.
MSRs can be burners or breeders. They can be fast or thermal or epithermal. Thermal reactors typically employ a moderator (usually graphite) to slow the neutrons down and moderate temperature. They can accept a variety of fuels (low-enriched uranium, thorium, depleted uranium, waste products)[21] and coolants (fluoride, chloride, lithium, beryllium, mixed). Fuel cycle can be either closed or once-through.[22] They can be monolithic or modular, large or small. The reactor can adopt a loop, modular or integral configuration. Variations include:
The molten salt fast reactor (MSFR) is a proposed design with the fuel dissolved in a fluoride salt coolant. The MSFR is one of the two variants of MSRs selected by the Generation IV International Forum (GIF) for further development, the other being the FHR or AHTR.[2] The MSFR is based on a fast neutron spectrum and is believed to be a long-term substitute to solid-fueled fast reactors. They have been studied for almost a decade, mainly by calculations and determination of basic physical and chemical properties in the European Union and Russian Federation.[23] A MSFR is regarded sustainable because there are no fuel shortages. Operation of a MSFR does in theory not generate or require large amounts of transuranic (TRU) elements. When steady state is achieved in a MSFR, there is no longer a need for uranium enrichment facilities.[24]
MSFRs may be breeder reactors. They operate without a moderator in the core such as graphite, so graphite life-span is no longer a problem. This results in a breeder reactor with a fast neutron spectrum that operates in the Thorium fuel cycle. MSFRs contain relatively small initial inventories of 233U. MSFRs run on liquid fuel with no solid matter inside the core. This leads to the possibility of reaching specific power that is much higher than reactors using solid fuel. The heat produced goes directly into the heat transfer fluid. In the MSFR, a small amount of molten salt is set aside to be processed for fission product removal and then returned to the reactor. This gives MSFRs the capability of reprocessing the fuel without stopping the reactor. This is very different compared to solid-fueled reactors because they have separate facilities to produce the solid fuel and process spent nuclear fuel. The MSFR can operate using a large variety of fuel compositions due to its on-line fuel control and flexible fuel processing.[25]
The standard MSFR would be a 3000 MWth reactor that has a total fuel salt volume of 18 m3 with a mean fuel temperature of 750 oC. The core's shape is a compact cylinder with a height to diameter ratio of 1 where liquid fluoride fuel salt flows from the bottom to the top. The return circulation of the salt, from top to bottom, is broken up into 16 groups of pumps and heat exchangers located around the core. The fuel salt takes approximately 3 to 4 seconds to complete a full cycle. At any given time during operation, half of the total fuel salt volume is in the core and the rest is in the external fuel circuit (salt collectors, salt-bubble separators, fuel heat exchangers, pumps, salt injectors and pipes).[25] MSFRs contain an emergency draining system that is triggered and achieved by redundant and reliable devices such as detection and opening technology. During operation, the fuel salt circulation speed can be adjusted by controlling the power of the pumps in each sector. The intermediate fluid circulation speed can be adjusted by controlling the power of the intermediate circuit pumps. The temperature of the intermediate fluid in the intermediate exchangers can be managed through the use of a double bypass. This allows the temperature of the intermediate fluid at the conversion exchanger inlet to be held constant while its temperature is increased in a controlled way at the inlet of the intermediate exchangers. The temperature of the core can be adjusted by varying the proportion of bubbles injected in the core since it reduces the salt density. As a result, it reduces the mean temperature of the fuel salt. Usually the fuel salt temperature can be brought down by 100 oC using a 3% proportion of bubbles. MSFRs have two draining modes, controlled routine draining and emergency draining. During controlled routine draining, fuel salt is transferred to actively cooled storage tanks. The fuel temperature can be lowered before draining, this may slow down the process. This type of draining could be done every 1 to 5 years when the sectors are replaced. Emergency draining is done when an irregularity occurs during operation. The fuel salt can be drained directly into the emergency draining tank either by active devices or by passive means. The draining must be fast to limit the fuel salt heating in a loss of heat removal event.
The fluoride salt-cooled high-temperature reactor (FHR), also called advanced high temperature reactor (AHTR),[26] is also a proposed Generation IV molten salt reactor variant regarded promising for the long-term future.[2] The FHR/AHTR reactor uses a solid-fuel system along with a molten fluoride salt as coolant.
One version of the Very-high-temperature reactor (VHTR) under study was the liquid-salt very-high-temperature reactor (LS-VHTR). It uses liquid salt as a coolant in the primary loop, rather than a single helium loop. It relies on "TRISO" fuel dispersed in graphite. Early AHTR research focused on graphite in the form of graphite rods that would be inserted in hexagonal moderating graphite blocks, but current studies focus primarily on pebble-type fuel.Template:Citation needed The LS-VHTR can work at very high temperatures (the boiling point of most molten salt candidates is >1400 °C); low-pressure cooling that can be used to match hydrogen production facility conditions (most thermochemical cycles require temperatures in excess of 750 °C); better electric conversion efficiency than a helium-cooled VHTR operating in similar conditions; passive safety systems and better retention of fission products in the event of an accident.Template:Citation needed
Reactors containing molten thorium salt, called liquid fluoride thorium reactors (LFTR), would tap the thorium fuel cycle. Private companies from Japan, Russia, Australia and the United States, and the Chinese government, have expressed interest in developing this technology.[27][28][29]
Advocates estimate that five hundred metric tons of thorium could supply U.S. energy needs for one year.[30] The U.S. Geological Survey estimates that the largest-known U.S. thorium deposit, the Lemhi Pass district on the Montana-Idaho (U.S. state) border, contains thorium reserves of 64,000 metric tons.[31]
Traditionally, these reactors were known as molten salt breeder reactors (MSBRs) or thorium molten salt reactors (TMSRs), but the name LFTR was promoted as a rebrand in the early 2000s by Kirk Sorensen.
The stable salt reactor is a relatively recent concept which holds the molten salt fuel statically in traditional LWR fuel pins. Pumping of the fuel salt, and all the corrosion/deposition/maintenance/containment issues arising from circulating a highly radioactive, hot and chemically complex fluid, are no longer required. The fuel pins are immersed in a separate, non-fissionable fluoride salt which acts as primary coolant.
A prototypical example of a dual fluid reactor is the lead-cooled, salt-fueled reactor.
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