Silane

Silane
General
Systematic name	Silane
Other names	Silicon tetrahydride Silicon hydride Monosilane Silicane
Molecular formula	SiH4
Molar mass	32.12 g mol−1
Appearance	Colourless gas
CAS number	[7803-62-5]
Properties
Density and phase	? kg m−3 (solid) 0.7 g/ml (liquid) 1.342 g L−1 (gas)
Solubility in water	Insoluble
Melting point	88 K (−185°C)
Boiling point	161 K (−112°C)
ΔfH0solid	-1615 kJ mol−1
S0solid	283 J mol−1 K−1
Structure
Molecular shape	tetrahedral
Dipole moment	0 D
Hazards
MSDS	External MSDS
Main hazards	low toxicity, avoid exposure to skin, irritant, may cause redness and swelling
NFPA 704	4 1 3
Flash point	N/A
Autoignition temperature	294 K (21°C)
R/S statement	R: ? S: ?
UN number	2203
RTECS number	VV1400000
Supplementary data page
Structure and properties	n, εr, etc.
Thermodynamic data	Phase behaviour Solid, liquid, gas
Spectral data	UV, IR, NMR, MS
Related compounds
Related silanes	disilane trisilane tetrasilane cyclosilane
Related hydrides	methane
Related compounds	disilene
Except where noted otherwise, data are given for materials in their standard state (at 25°C, 100 kPa) Infobox disclaimer and references

Silane is a chemical compound with the chemical formula SiH₄. It is the silicon analog of methane and, like methane, it is a gas at ordinary temperatures. The name "silane" is also given to a family of compounds that are silicon analogs of alkane hydrocarbons. Silanes consist of a chain of silicon atoms covalently bound to hydrogen atoms. The general formula of a silane is Si_nH_2n+2.

Silanes are useful as coupling agents to bind glass fibers to polymers, and to couple a bio-inert layer on a titanium implant. They are also used for water repellents, sealants, masonry protection, graffiti control, semiconductor manufacturing processes, and chemical reduction reactions.

Nomenclature of different structures

There are certain rules for naming silanes. For instance, depending on the number of silicon atoms in each molecule, the word silane is preceded by a numerical prefix, such as di, tri, tetra, and so forth. Thus, Si₂H₆ is disilane, and Si₃H₈ is trisilane. SiH₄ is usually just called silane, without a prefix, but occasionally it is referred to as monosilane (to avoid confusion with larger silanes).

In an alternative system of nomenclature, silanes may be named in a manner similar to other inorganic compounds. For instance, silane is called silicon tetrahydride. However, with longer silanes, this system becomes cumbersome.

A cyclosilane is a silane with a ring structure, just as a cycloalkane is an alkane with a ring structure.

Some silanes have branched structures. The radical •SiH₃ is termed silyl, •Si₂H₅ is disilanyl, and so on. Trisilane with a silyl group attached to the middle silicon is named silyltrisilane. The nomenclature parallels that of alkyl radicals.

Silanes may also carry certain functional groups, just as alkanes do. For instance, if a hydroxyl group (OH) is attached to a silane, it is called a silanol. There is (at least in principle) a silicon analog for all carbon alkanes.

Properties

As noted above, silane (SiH₄) is a gas at room temperature. In addition, it is pyrophoric—that is, it undergoes spontaneous combustion in air, without the need for external ignition. (However, one school of thought holds that silane itself is stable and that the natural formation of larger silanes during production causes its pyrophoricity.) Above 420°C, silane decomposes into silicon and hydrogen. It can therefore be used in the chemical vapor deposition of silicon.

The family of silanes tends to be less stable than their carbon analogs because the Si-Si bond has a strength slightly lower than the C-C bond. Oxygen decomposes silanes easily, because the silicon-oxygen bond is quite stable.

Production

Industrially, silane is produced from metallurgical grade silicon in a two-step process. In the first step, powdered silicon is reacted with hydrochloric acid at about 300 °C to produce trichlorosilane, HSiCl₃, along with hydrogen gas, according to the chemical equation:

Si + 3HCl → HSiCl₃ + H₂

The trichlorosilane is then boiled on a resinous bed containing a catalyst, producing silane and silicon tetrachloride according to the chemical equation:

4HSiCl₃ → SiH₄ + 3SiCl₄

The most commonly used catalysts for this process are metal halides, particularly aluminum chloride.

Applications

Silanes are useful for several industrial and medical applications. For instance, they are used as coupling agents to adhere glass fibers to a polymer matrix, stabilizing the composite material. They can also be used to couple a bio-inert layer on a titanium implant. Other applications include water repellents, masonry protection, control of graffiti,^[1] applying polycrystalline silicon layers on silicon wafers when manufacturing semiconductors, and sealants. In addition, silane and similar compounds containing Si-H bonds are used as reducing agents in organic and organometallic chemistry.^[2]

See also

• Alkane
• Functional group
• Methane
• Silicon

Notes

References

ISBN links support NWE through referral fees

• Antonucci, J.M., et al. 2003. Chemistry of Silanes: Interfaces in Dental Polymers and Composites Polymers Division, NIST. Retrieved August 23, 2007.
• Jutzi, Peter, and Ulrich Schubert. 2003. Silicon Chemistry: From the Atom to Extended Systems. New York: Wiley. ISBN 3527306471
• Plueddemann, Edwin Paul. 1982. Silane Coupling Agents. Berlin: Springer. ISBN 0306409577