Neodymium Bismuthide

Neodymium bismuthide
Names
	Other names Neodymium(III) bismuthide
Identifiers
CAS Number	12233-02-2 ;
3D model (JSmol)	Interactive image;
ChemSpider	65322177;
PubChem CID	44153527;
	InChI InChI=1S/Bi.Nd Key: VNARRZRNLSEBPY-UHFFFAOYSA-N;
	SMILES [Nd].[Bi];
Properties
Chemical formula	BiNd
Molar mass	352.22 g/mol
Density	8.8 g/cm3
Melting point	1775°C; 1900°C
Critical point (T, P)	-111 kJ/mol
Structure
Crystal structure	cubic
Space group	Fm3m
Lattice constant	a = 6.4222 Å
Formula units (Z)	4
Related compounds
Other anions	Neodymium(III) nitride; Neodymium(III) arsenide; Neodymium(III) phosphide; Neodymium(III) antimonide; Neodymium(III) oxide
Other cations	PrBi
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Neodymium bismuthide or Bismuth-Neodymium^[4] is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.

Preparation

Neodymium bismuthide can be prepared by reacting a stoichiometric amount of neodymium and bismuth at 1900°C:^{[citation needed]}

Nd + Bi → NdBi

Physical properties

Neodymium bismuthide forms cubic crystals of the space group Fm3m, with cell parameters a = 0.64222 nm, Z = 4 with a structure like sodium chloride.^[5] The compound melts at 1900°C.^[2] At a temperature of 24 K, an antiferromagnetic transition occurs in the compound.^[6]

References

↑ Abulkhaev V.D. (2001). "Phase digram of the neodymium-bismuth system". Zhurnal Neorganicheskoj Khimii 46 (4): 659-662. ISSN 0044-457X. https://inis.iaea.org/search/search.aspx?orig_q=RN:33016098.
↑ ^2.0 ^2.1 Alloy Phase Diagrams. 3. 1992. ISBN 0-87170-381-5.
↑ A. Borsese; R. Capelli; S. Delfino; R. Ferro (1974). "The heat of formation of neodymium-bismuth alloys". Thermochimica Acta 8 (4): 393-397. doi:10.1016/0040-6031(74)85107-5.
↑ Okamoto, H. (2002-03-01). "Bi-Nd (Bismuth-Neodymium)" (in en). Journal of Phase Equilibria 23 (2): 191. doi:10.1361/1054971023604224. ISSN 1054-9714. https://doi.org/10.1361/1054971023604224.
↑ Ed. N. P. Lyakisheva (1996). State Diagrams of Binary Metal Systems. 1. Engineering. p. 992. ISBN 5-217-02688-X.
↑ P. Schobinger-Papamantellos, P. Fischer, O. Vogt, E. Kaldis (1973). "Magnetic ordering of neodymium monopnictides determined by neutron diffraction". J. Phys. C: Solid State Phys. 6 (4): 725-737. doi:10.1088/0022-3719/6/4/020. Bibcode: 1973JPhC....6..725S.

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[1] Abulkhaev V.D. (2001). "Phase digram of the neodymium-bismuth system". Zhurnal Neorganicheskoj Khimii 46 (4): 659-662. ISSN 0044-457X. https://inis.iaea.org/search/search.aspx?orig_q=RN:33016098.

[Diagrams-2] 2.0 ^2.1 Alloy Phase Diagrams. 3. 1992. ISBN 0-87170-381-5.

[3] A. Borsese; R. Capelli; S. Delfino; R. Ferro (1974). "The heat of formation of neodymium-bismuth alloys". Thermochimica Acta 8 (4): 393-397. doi:10.1016/0040-6031(74)85107-5.

[4] Okamoto, H. (2002-03-01). "Bi-Nd (Bismuth-Neodymium)" (in en). Journal of Phase Equilibria 23 (2): 191. doi:10.1361/1054971023604224. ISSN 1054-9714. https://doi.org/10.1361/1054971023604224.

[Lyakisheva-5] Ed. N. P. Lyakisheva (1996). State Diagrams of Binary Metal Systems. 1. Engineering. p. 992. ISBN 5-217-02688-X.

[6] P. Schobinger-Papamantellos, P. Fischer, O. Vogt, E. Kaldis (1973). "Magnetic ordering of neodymium monopnictides determined by neutron diffraction". J. Phys. C: Solid State Phys. 6 (4): 725-737. doi:10.1088/0022-3719/6/4/020. Bibcode: 1973JPhC....6..725S.