Iridium Tetrachloride
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| Properties | |
| Cl4Ir | |
| Molar mass | 334.02 g·mol−1 |
| Appearance | amorphous brown solid |
| Melting point | 763 °C (1,405 °F; 1,036 K) (decomposes)[1] |
| soluble | |
| Solubility | soluble in alcohol, dilute hydrochloric acid |
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| GHS Signal word | Warning |
| HH302Script error: No such module "Preview warning".Category:GHS errors, HH315Script error: No such module "Preview warning".Category:GHS errors, HH319Script error: No such module "Preview warning".Category:GHS errors, HH335Script error: No such module "Preview warning".Category:GHS errors | |
| PP261Script error: No such module "Preview warning".Category:GHS errors, PP264Script error: No such module "Preview warning".Category:GHS errors, PP264+P265Script error: No such module "Preview warning".Category:GHS errors, PP270Script error: No such module "Preview warning".Category:GHS errors, PP271Script error: No such module "Preview warning".Category:GHS errors, PP280Script error: No such module "Preview warning".Category:GHS errors, PP301+P317Script error: No such module "Preview warning".Category:GHS errors, PP302+P352Script error: No such module "Preview warning".Category:GHS errors, PP304+P340Script error: No such module "Preview warning".Category:GHS errors, PP305+P351+P338Script error: No such module "Preview warning".Category:GHS errors, PP319Script error: No such module "Preview warning".Category:GHS errors, PP321Script error: No such module "Preview warning".Category:GHS errors, PP330Script error: No such module "Preview warning".Category:GHS errors, PP332+P317Script error: No such module "Preview warning".Category:GHS errors, PP337+P317Script error: No such module "Preview warning".Category:GHS errors, PP362+P364Script error: No such module "Preview warning".Category:GHS errors, PP403+P233Script error: No such module "Preview warning".Category:GHS errors, PP405Script error: No such module "Preview warning".Category:GHS errors, PP501Script error: No such module "Preview warning".Category:GHS errors | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Iridium tetrachloride is an inorganic compound with the approximate formula IrCl4(H2O)n. It is a water-soluble, hygroscopic amorphous dark brown solid. A well-defined derivative is ammonium hexachloroiridate ((NH4)2IrCl6).[2] It is used to prepare catalysts, such as the Henbest Catalyst for transfer hydrogenation of cyclohexanones.[3]
References
- ↑ 1.0 1.1 PubChem. "Iridium tetrachloride" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/24815.
- ↑ Thomas R. B. Mitchell (2001). "Iridium(IV) Chloride". E-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.ri050. ISBN 0-471-93623-5.
- ↑ E. L. Eliel; T. W. Doyle; R. O. Hutchins; E. C. Gilbert (1970). "cis-4-tert-Butylecyclohexanol". Org. Synth. 50: 13. doi:10.15227/orgsyn.050.0013.
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Categories: [Iridium compounds] [Chloro complexes]
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