Dibromine Monoxide

Dibromine monoxide
Names
	IUPAC name Dibromine monoxide
	Systematic IUPAC name Bromohypobromite
	Other names Dibromine oxide, bromine monoxide
Identifiers
CAS Number	21308-80-5 ;
3D model (JSmol)	Interactive image;
ChemSpider	10686917;
PubChem CID	14513628;
	InChI InChI=1S/Br2O/c1-3-2 Key: HJCMMOODWZOXML-UHFFFAOYSA-N;
	SMILES O(Br)Br;
Properties
Chemical formula	Br2O
Molar mass	175.807 g/mol
Appearance	dark brown solid
Melting point	decomposes around −17.5°C
Related compounds
Related compounds	Water; Oxygen difluoride; Dichlorine monoxide; Diiodine monoxide;
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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	Infobox references

Dibromine monoxide is the chemical compound composed of bromine and oxygen with the formula Br₂O. It is a dark brown solid which is stable below −40 °C and is used in bromination reactions.^[1] It is similar to dichlorine monoxide, the monoxide of its halogen neighbor one period higher on the periodic table. The molecule is bent, with C_2v molecular symmetry. The Br−O bond length is 1.85 Å and the Br−O−Br bond angle is 112°,^[2]^[3] similar to dichlorine monoxide.

Reactions

Dibromine monoxide can be prepared by reacting bromine vapor or a solution of bromine in carbon tetrachloride with mercury(II) oxide at low temperatures:^[1]^[3]

2 Br₂ + 2 HgO → HgBr₂·HgO + Br₂O

It can also be formed by thermal decomposition of bromine dioxide^[2] or by passing an electrical current through a 1:5 mixture of bromine and oxygen gases.^[3]

References

↑ ^1.0 ^1.1 ^1.2 Perry, Dale L.; Phillips, Sidney L. (1995), Handbook of Inorganic Compounds, CRC Press, pp. 74, ISBN 0-8493-8671-3, https://books.google.com/books?id=0fT4wfhF1AsC&q="Bromine+dioxide"&pg=PA74, retrieved 25 August 2015
↑ ^2.0 ^2.1 Levason, William; Ogden, J. Steven; Spicer, Mark D.; Young, Nigel A. (January 1990). "Characterization of dibromine monoxide (Br2O) by bromine K-edge EXAFS and IR spectroscopy". Journal of the American Chemical Society 112 (3): 1019–1022. doi:10.1021/ja00159a019.
↑ ^3.0 ^3.1 ^3.2 Wiberg, Egon (2001). Wiberg, Nils. ed. Inorganic chemistry (1st ed.). San Diego, Calif.: Academic Press. pp. 464. ISBN 9780123526519.

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[handin-1] 1.0 ^1.1 ^1.2 Perry, Dale L.; Phillips, Sidney L. (1995), Handbook of Inorganic Compounds, CRC Press, pp. 74, ISBN 0-8493-8671-3, https://books.google.com/books?id=0fT4wfhF1AsC&q="Bromine+dioxide"&pg=PA74, retrieved 25 August 2015

[JACS-2] 2.0 ^2.1 Levason, William; Ogden, J. Steven; Spicer, Mark D.; Young, Nigel A. (January 1990). "Characterization of dibromine monoxide (Br2O) by bromine K-edge EXAFS and IR spectroscopy". Journal of the American Chemical Society 112 (3): 1019–1022. doi:10.1021/ja00159a019.

[inorg-3] 3.0 ^3.1 ^3.2 Wiberg, Egon (2001). Wiberg, Nils. ed. Inorganic chemistry (1st ed.). San Diego, Calif.: Academic Press. pp. 464. ISBN 9780123526519.