Telluride Iodide

Short description: Class of chemical compounds

The telluride iodides are chemical compounds that contain both telluride ions (Te²⁻) and iodide ions (I⁻). They are in the class of mixed anion compounds or chalcogenide halides.^[1]

Tellurium does not normally bond with iodine, but can form many different units with bonds to other tellurium atoms.

List

name	formula	system	space group	unit cell	volume	density	properties	ref
Copper telluride iodide	CuTeI	tetrahedral	I4₁/amd	a = 17.170, c = 4.876, and Z = 16			Cu⁺¹ ion conductor; metallic grey	^[2]^[3]
	(CuI)₃Cu₂TeS₃		P3₁21					^[1]
gallium telluride iodide	GaTeI	orthorhombic					band gap 2.55	^[1]
	Ge_40.0Te_5.3I₈	cubic	Pm3n	a=10.815 Z = 1	1265.0	6.023	band gap 0.8 eV; clathrate	^[4]
α-Arsenic telluride iodide	AsTeI	monoclinic	P2₁	a=8.965 b=4.042 c=10.341 β=90.75 Z=4		5.84	melt 281°C black	^[5]
β-Arsenic telluride iodide	AsTeI	cubic	Fm3m	a=5.791 Z=2		5.63	black metallic	^[5]
	As₄Te₅I₂	monoclinic		a=14.58 b=4.00 c=12.26 β=95.0 Z=2		5.51	melt 303 °C metallic	^[5]
triniobium telluride heptaiodide	Nb₃TeI₇							^[1]
	NbTe₄I		P2₁/c	a=7.695 b=15.393 c=13.438 β=100.84 Z=8	1563.2	6.205	black metallic	^[6]
diniobium hexatelluride iodide	Nb₂Te₆I		P2₁/c	a=9.197 b=13.387 c=9.651 β=112.36	1093.8	6.548		^[1]^[7]
	Nb₄Te₁₂I	monoclinic	C12/c1	a=21.957 b=6.147 c=19.925 β=122.40 Z=4	2270.6	5.8	black	^[8]
	Nb₄Te₁₇I₄	monoclinic	C2/c	a = 16.199 b = 8.128 c = 27.355 β = 110.84°, Z = 4			black metallic	^[9]
	Mo₃Te_l0I_l0							^[1]
	[Mo₃Se7(TeI₃)I₂]I	monoclinic	P2₃/n	a=10.4969 b=13.029 c=16.567 β =102.921° Z=4	2208.3	5.202		^[1]^[10]
	[Mo₃Te₇(TeI₃)₃]₂(I)(TeI₃)	triclinic	P1	a=11.2148 b=11.6550 c=16.6798 α=92.124 β=102.223 γ=117.427 Z=	1868.4	5.374		^[1]^[10]
Palladium telluride iodide	PdTeI			a=7.821 c=5.659			brass yellow	^[11]^[12]
	Ag₂₃Te₁₂I	orthorhombic	Pnnm				honeycomb Te	^[1]
	Ag₁₉Te₆Br_5.4I_1.6	orthorhombic	Pnma				electric conductor	^[1]
indium telluride iodide	InTeI	monoclinic	P21/c					^[13]
Antimony telluride iodide	SbTeI	triclinic	P1					^[1]
	(Sb₂Te₂)I[AlI₄]	monoclinic	P2₁/n					^[1]
	La₂TeI₂	rhombohedral	R3m	a = 4.5074 c = 32.528 Z = 3			metallic	^[1]^[14]
	Er_17.3Te₂₄I₈		Fd3m	a=12.020				^[15]
	Ta₃TeI₇	hexagonal	P6₃mc					^[1]
	[TaTe₄]₄[PtI₆]I₂	triclinic	P1	a=16.831 b=17.740 c=19.018 α=93.57 β=94.08 γ=102.09 Z=1	977.65			^[16]
	TaTe₄I	triclinic	P1	a=6.679 b=7.787 c=8.581 α=112.76 β=102.60 γ=101.25 Z=2	381.8	7.118	black	^[6]
	W₂Cl₁₂Te₆I₂							^[17]
Gold telluride iodide	AuITe	monoclinic		a=7.317 b=7.626 c=7.249 β=106.33		7.73	semiconductor band gap 0.9 grey melt 360°C	^[18]
Gold telluride diiodide	AuITe₂	orthorhombic	Pmmb	a = 4.056 Å, b = 12.579 Å, c = 4.741 Å, Z = 2	241.9	7.989	silvery white conductor melt 440°C	^[19]
	Hg₃Te₂I₂						greyish red	^[1]
	Hg₃Te₂BrI	monoclinic	C2	18.376 b=9.587 c=10.575 β=100.11°				^[20]
	Hg₃TeI₄	cubic	F43m	a=6.244 Z=(80% partial occupancy)	243.4	7.03	decompose 273°C dark ruby red	^[21]
Bismuth telluride iodide	BiTeI		P3m1 / Pnma				over 3.9 GPa Weyl semimetal; under semimetal	^[1]
	ThTe₂I₂	monoclinic	C2/m	a = 7.642 b = 14.336 c = 7.727 and β = 111.27° Z = 4				^[22]
	[Ta₇(Se₂)₁₄][U₂I₁₀]₂	orthorhombic	Cccm	a = 21.5134 b = 22.1619 and c = 16.7834 Z=4				^[23]

References

↑ ^1.00 ^1.01 ^1.02 ^1.03 ^1.04 ^1.05 ^1.06 ^1.07 ^1.08 ^1.09 ^1.10 ^1.11 ^1.12 ^1.13 ^1.14 ^1.15 Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews 347: 23–47. doi:10.1016/j.ccr.2017.06.010.
↑ Carkner, Philip M.; Haendler, Helmut M. (June 1976). "The crystal structure of copper bromide telluride" (in en). Journal of Solid State Chemistry 18 (2): 183–189. doi:10.1016/0022-4596(76)90094-3. Bibcode: 1976JSSCh..18..183C.
↑ Fenner, J.; Rabenau, A. (September 1976). "Über Tellurhalogenide des Kupfers mit hoher Ionen-Teilleitfähigkeit Die Kristallstruktur von CuTeJ" (in de). Zeitschrift für anorganische und allgemeine Chemie 426 (1): 7–14. doi:10.1002/zaac.19764260103. ISSN 0044-2313.
↑ Kovnir, Kirill A.; Abramchuk, Nikolay S.; Zaikina, Julia V.; Baitinger, Michael; Burkhardt, Ulrich; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I. et al. (2006-05-01). "Ge 40.0 Te 5.3 I 8 : synthesis, crystal structure, and properties of a new clathrate-I compound" (in en). Zeitschrift für Kristallographie - Crystalline Materials 221 (5–7): 527–532. doi:10.1524/zkri.2006.221.5-7.527. ISSN 2196-7105. Bibcode: 2006ZK....221..527K. https://www.degruyter.com/document/doi/10.1524/zkri.2006.221.5-7.527/html.
↑ ^5.0 ^5.1 ^5.2 Kniep, Rüdiger; Reski, Horst Dieter (February 1981). "Chalcogenide Iodides of Arsenic" (in en). Angewandte Chemie International Edition in English 20 (2): 212–214. doi:10.1002/anie.198102121. ISSN 0570-0833.
↑ ^6.0 ^6.1 Tremel, Wolfgang (October 1992). "NbTe4I und TaTe4I, zwei neue Tellurid-Iodide mit Kettenstruktur" (in de). Chemische Berichte 125 (10): 2165–2170. doi:10.1002/cber.19921251002.
↑ Tremel, Wolfgang (March 1992). "Niobium telluride iodide, Nb2Te6I, a pseudo-two-dimensional compound with a new mode of transition-metal bonding for a dichalcogen group" (in en). Inorganic Chemistry 31 (5): 755–760. doi:10.1021/ic00031a012. ISSN 0020-1669.
↑ Deng, S.; Zhuang, H.; Lu, C.; Huang, Jinshun; Huang, Jingling (1993-06-15). "A new type of one-dimensional compound: structure of Nb4(Te2)4Te4I". Acta Crystallographica Section C Crystal Structure Communications 49 (6): 1135–1137. doi:10.1107/S010827019201285X. Bibcode: 1993AcCrC..49.1135D. http://scripts.iucr.org/cgi-bin/paper?S010827019201285X.
↑ Tremel, Wolfgang (January 1994). "Nb4Te17I4, a New Pseudo One-Dimensional Solid-State Polytelluride" (in de). Chemische Berichte 127 (1): 11–14. doi:10.1002/cber.19941270103.
↑ ^10.0 ^10.1 Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †" (in en). Inorganic Chemistry 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.
↑ Güler-Kılıç, Sümeyra; Kılıç, Çetin (2015-06-08). "Crystal and electronic structure of BiTeI, AuTeI, and PdTeI compounds: A dispersion-corrected density-functional study" (in en). Physical Review B 91 (24): 245204. doi:10.1103/PhysRevB.91.245204. ISSN 1098-0121. Bibcode: 2015PhRvB..91x5204G.
↑ Thiele, Gerhard; Köhler-Degner, Maria; Wittmann, Kurt; Zoubek, Gerd (November 1978). "PdTeI and Pd2SeI3 - The First Chalcogenide Halides of a Platinum Metal" (in en). Angewandte Chemie International Edition in English 17 (11): 852–853. doi:10.1002/anie.197808521. ISSN 0570-0833.
↑ Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials 18 (10): 2538–2544. doi:10.1021/cm060226m.
↑ Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (December 2006). "La 2 TeI 2 : A New Layered Telluride Iodide with Unusual Electrical Properties" (in en). Inorganic Chemistry 45 (26): 10728–10733. doi:10.1021/ic061675r. ISSN 0020-1669. PMID 17173429.
↑ Stöwe, K (August 1998). "Nonstoichiometry in Er–Te Binary and Er–Te–I Ternary Systems" (in en). Journal of Solid State Chemistry 139 (1): 57–65. doi:10.1006/jssc.1998.7807.
↑ Tremel, Wolfgang; Stork, Karl-Ludwig (1993-09-01). "[TaTe4]4[PtI6]I2, ein neues quaternäres Tellurid-Iodid mit Kettenstruktur / [TaTe4]4[PtI6]I2, A New Quaternary Telluride-Iodide with Chain Structure". Zeitschrift für Naturforschung B 48 (9): 1155–1160. doi:10.1515/znb-1993-0901. ISSN 1865-7117.
↑ Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides" (in en). Angewandte Chemie International Edition in English 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.
↑ Rabenau, A.; Rau, H.; Rosenstein, G. (August 1970). "Telluride halides of gold" (in en). Journal of the Less Common Metals 21 (4): 395–401. doi:10.1016/0022-5088(70)90043-3.
↑ Haendler, H.M.; Mootz, D.; Rabenau, A.; Rosenstein, G. (June 1974). "The crystal structures of AuTe2Cl and AuTe2I" (in en). Journal of Solid State Chemistry 10 (2): 175–181. doi:10.1016/0022-4596(74)90024-3. Bibcode: 1974JSSCh..10..175H.
↑ Minets, Yu.V; Voroshilov, Yu.V; Pan’ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2" (in en). Journal of Alloys and Compounds 367 (1–2): 109–114. doi:10.1016/j.jallcom.2003.08.020.
↑ Wiedemeier, Heribert; Hutchins, Mark A.; Grin, Yuri; Feldmann, Claus; von Schnering, Hans Georg (November 1997). "The Synthesis and Crystal Structure of Hg3TeI4" (in en). Zeitschrift für anorganische und allgemeine Chemie 623 (11): 1843–1846. doi:10.1002/zaac.19976231129. ISSN 0044-2313.
↑ Rocker, Frank; Tremel, Wolfgang (2001). 3.0.CO;2-J">"Synthesis and Structure of ThTe2I2" (in en). Zeitschrift für anorganische und allgemeine Chemie 627 (6): 1305–1308. doi:3.0.CO;2-J">10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J. ISSN 1521-3749. 3.0.CO;2-J">https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J.
↑ Wells, Daniel M.; Ibers, James A. (March 2010). "The [U 2 I 10 ] 2- Anion: Synthesis and Structure of [Ta 7 (Se 2 ) 14 ][U 2 I 10 ] 2" (in en). Zeitschrift für anorganische und allgemeine Chemie 636 (3–4): 440–442. doi:10.1002/zaac.200900416.

HI																	He
LiI	BeI₂											BI₃	CI₄	NI₃	I₂O₄, I₂O₅, I₄O₉	IF, IF₃, IF₅, IF₇	Ne
NaI	MgI₂											AlI₃	SiI₄	PI₃, P₂I₄	S	ICl, ICl₃	Ar
KI	CaI₂	Sc	TiI₄	VI₃	CrI₃	MnI₂	FeI₂	CoI₂	NiI₂	CuI	ZnI₂	Ga₂I₆	GeI₂, GeI₄	AsI₃	Se	IBr	Kr
RbI	SrI₂	YI₃	ZrI₄	NbI₅	Mo	Tc	Ru	Rh	Pd	AgI	CdI₂	InI₃	SnI₄, SnI₂	SbI₃	TeI₄	I	Xe
CsI	BaI₂		HfI₄	TaI₅	W	Re	Os	Ir	Pt	AuI	Hg₂I₂, HgI₂	TlI	PbI₂	BiI₃	Po	AtI	Rn
Fr	RaI₂		Rf	Db	Sg	Bh	Hs	Mt	Ds	Rg	Cn	Nh	Fl	Mc	Lv	Ts	Og
		↓
		La	Ce	Pr	Nd	Pm	SmI₂	Eu	Gd	TbI₃	Dy	Ho	Er	Tm	Yb	Lu
		Ac	ThI₄	Pa	UI₃, UI₄	Np	Pu	Am	Cm	Bk	Cf	EsI₃	Fm	Md	No	Lr

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Original source: https://en.wikipedia.org/wiki/Telluride iodide. Read more

[mch-1] 1.00 ^1.01 ^1.02 ^1.03 ^1.04 ^1.05 ^1.06 ^1.07 ^1.08 ^1.09 ^1.10 ^1.11 ^1.12 ^1.13 ^1.14 ^1.15 Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews 347: 23–47. doi:10.1016/j.ccr.2017.06.010.

[:0-2] Carkner, Philip M.; Haendler, Helmut M. (June 1976). "The crystal structure of copper bromide telluride" (in en). Journal of Solid State Chemistry 18 (2): 183–189. doi:10.1016/0022-4596(76)90094-3. Bibcode: 1976JSSCh..18..183C.

[3] Fenner, J.; Rabenau, A. (September 1976). "Über Tellurhalogenide des Kupfers mit hoher Ionen-Teilleitfähigkeit Die Kristallstruktur von CuTeJ" (in de). Zeitschrift für anorganische und allgemeine Chemie 426 (1): 7–14. doi:10.1002/zaac.19764260103. ISSN 0044-2313.

[4] Kovnir, Kirill A.; Abramchuk, Nikolay S.; Zaikina, Julia V.; Baitinger, Michael; Burkhardt, Ulrich; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I. et al. (2006-05-01). "Ge 40.0 Te 5.3 I 8 : synthesis, crystal structure, and properties of a new clathrate-I compound" (in en). Zeitschrift für Kristallographie - Crystalline Materials 221 (5–7): 527–532. doi:10.1524/zkri.2006.221.5-7.527. ISSN 2196-7105. Bibcode: 2006ZK....221..527K. https://www.degruyter.com/document/doi/10.1524/zkri.2006.221.5-7.527/html.

[:1-5] 5.0 ^5.1 ^5.2 Kniep, Rüdiger; Reski, Horst Dieter (February 1981). "Chalcogenide Iodides of Arsenic" (in en). Angewandte Chemie International Edition in English 20 (2): 212–214. doi:10.1002/anie.198102121. ISSN 0570-0833.

[:3-6] 6.0 ^6.1 Tremel, Wolfgang (October 1992). "NbTe4I und TaTe4I, zwei neue Tellurid-Iodide mit Kettenstruktur" (in de). Chemische Berichte 125 (10): 2165–2170. doi:10.1002/cber.19921251002.

[7] Tremel, Wolfgang (March 1992). "Niobium telluride iodide, Nb2Te6I, a pseudo-two-dimensional compound with a new mode of transition-metal bonding for a dichalcogen group" (in en). Inorganic Chemistry 31 (5): 755–760. doi:10.1021/ic00031a012. ISSN 0020-1669.

[8] Deng, S.; Zhuang, H.; Lu, C.; Huang, Jinshun; Huang, Jingling (1993-06-15). "A new type of one-dimensional compound: structure of Nb4(Te2)4Te4I". Acta Crystallographica Section C Crystal Structure Communications 49 (6): 1135–1137. doi:10.1107/S010827019201285X. Bibcode: 1993AcCrC..49.1135D. http://scripts.iucr.org/cgi-bin/paper?S010827019201285X.

[9] Tremel, Wolfgang (January 1994). "Nb4Te17I4, a New Pseudo One-Dimensional Solid-State Polytelluride" (in de). Chemische Berichte 127 (1): 11–14. doi:10.1002/cber.19941270103.

[:2-10] 10.0 ^10.1 Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †" (in en). Inorganic Chemistry 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.

[11] Güler-Kılıç, Sümeyra; Kılıç, Çetin (2015-06-08). "Crystal and electronic structure of BiTeI, AuTeI, and PdTeI compounds: A dispersion-corrected density-functional study" (in en). Physical Review B 91 (24): 245204. doi:10.1103/PhysRevB.91.245204. ISSN 1098-0121. Bibcode: 2015PhRvB..91x5204G.

[12] Thiele, Gerhard; Köhler-Degner, Maria; Wittmann, Kurt; Zoubek, Gerd (November 1978). "PdTeI and Pd2SeI3 - The First Chalcogenide Halides of a Platinum Metal" (in en). Angewandte Chemie International Edition in English 17 (11): 852–853. doi:10.1002/anie.197808521. ISSN 0570-0833.

[13] Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials 18 (10): 2538–2544. doi:10.1021/cm060226m.

[14] Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (December 2006). "La 2 TeI 2 : A New Layered Telluride Iodide with Unusual Electrical Properties" (in en). Inorganic Chemistry 45 (26): 10728–10733. doi:10.1021/ic061675r. ISSN 0020-1669. PMID 17173429.

[15] Stöwe, K (August 1998). "Nonstoichiometry in Er–Te Binary and Er–Te–I Ternary Systems" (in en). Journal of Solid State Chemistry 139 (1): 57–65. doi:10.1006/jssc.1998.7807.

[16] Tremel, Wolfgang; Stork, Karl-Ludwig (1993-09-01). "[TaTe4]4[PtI6]I2, ein neues quaternäres Tellurid-Iodid mit Kettenstruktur / [TaTe4]4[PtI6]I2, A New Quaternary Telluride-Iodide with Chain Structure". Zeitschrift für Naturforschung B 48 (9): 1155–1160. doi:10.1515/znb-1993-0901. ISSN 1865-7117.

[17] Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides" (in en). Angewandte Chemie International Edition in English 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.

[18] Rabenau, A.; Rau, H.; Rosenstein, G. (August 1970). "Telluride halides of gold" (in en). Journal of the Less Common Metals 21 (4): 395–401. doi:10.1016/0022-5088(70)90043-3.

[19] Haendler, H.M.; Mootz, D.; Rabenau, A.; Rosenstein, G. (June 1974). "The crystal structures of AuTe2Cl and AuTe2I" (in en). Journal of Solid State Chemistry 10 (2): 175–181. doi:10.1016/0022-4596(74)90024-3. Bibcode: 1974JSSCh..10..175H.

[20] Minets, Yu.V; Voroshilov, Yu.V; Pan’ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2" (in en). Journal of Alloys and Compounds 367 (1–2): 109–114. doi:10.1016/j.jallcom.2003.08.020.

[21] Wiedemeier, Heribert; Hutchins, Mark A.; Grin, Yuri; Feldmann, Claus; von Schnering, Hans Georg (November 1997). "The Synthesis and Crystal Structure of Hg3TeI4" (in en). Zeitschrift für anorganische und allgemeine Chemie 623 (11): 1843–1846. doi:10.1002/zaac.19976231129. ISSN 0044-2313.

[22] Rocker, Frank; Tremel, Wolfgang (2001). 3.0.CO;2-J">"Synthesis and Structure of ThTe2I2" (in en). Zeitschrift für anorganische und allgemeine Chemie 627 (6): 1305–1308. doi:3.0.CO;2-J">10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J. ISSN 1521-3749. 3.0.CO;2-J">https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J.

[23] Wells, Daniel M.; Ibers, James A. (March 2010). "The [U 2 I 10 ] 2- Anion: Synthesis and Structure of [Ta 7 (Se 2 ) 14 ][U 2 I 10 ] 2" (in en). Zeitschrift für anorganische und allgemeine Chemie 636 (3–4): 440–442. doi:10.1002/zaac.200900416.