Thallium(Iii) Acetate

Thallium(III) acetate
Names
	IUPAC name Thallium(III) acetate
Identifiers
CAS Number	2570-63-0 ;
3D model (JSmol)	Interactive image;
ChemSpider	10667701;
EC Number	219-913-2;
PubChem CID	16685266;
UNII	24Z9A6MS8G;
	InChI InChI=1S/3C2H4O2.Tl/c31-2(3)4;/h31H3,(H,3,4);/q;;;+3/p-3 Key: SMRRYUGQTFYZGD-UHFFFAOYSA-K;
	SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Tl+3];
Properties
Chemical formula	Tl(C2H3O2)3
Molar mass	381.52
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Thallium(III) acetate is the acetate salt of thallium, with the chemical formula Tl(CH₃COO)₃. As a selective culture medium in microbiology,^[1] thallium acetate is toxic,^[2] but it can also be used as a hair loss agent. A dose of 8 mg/kg will cause acute poisoning, and the minimum lethal dose for adults is 12 mg/kg.^[3]

Preparation

Thallium acetate can be obtained by reacting 80% acetic acid with thallium(III) oxide, and the product crystallizes in acetic anhydride.^[4]

Properties

Anhydrous thallium(III) acetate crystallises in the monoclinic system with space group C2/c. The unit cell dimensions are a = 15.54 Å b = 8.630 Å and c = 7.848 Å with β = 113.92°. There are four formula per unit cell. and density is 2.57. Three acetate ions are chellated to each thallium ion.^[5]

Thallium(III) acetate monohydrate also crystallises in the monoclinic system with space group C2/c, a = 9.311 Å, b = 14.341 Å, c = 9.198 Å, β = 119.69 °. Unit cell volume is V = 1067.0 Å³ Z = 4, density is 2.49.^[6]

References

↑ Bulich, Anthony A.; Hartman, Paul A. (Nov 1969). "Evaluation of Thallium Acetate-Citrate Medium for Isolation of Enterococci". Applied Microbiology 18 (5): 944–945. doi:10.1128/am.18.5.944-945.1969. ISSN 0003-6919. PMID 5370465. PMC 378124. http://dx.doi.org/10.1128/am.18.5.944-945.1969.
↑ World Health Organization (2008). Anthrax in humans and animals. World Health Organization. pp. 139–. ISBN 978-92-4-154753-6. https://books.google.com/books?id=EKYihvnaA7oC&pg=PA139. Retrieved 23 February 2011.
↑ "铊、玻璃和人——从两桩铊中毒事件说起". 中国科学院上海硅酸盐研究所. http://119.78.242.243:8080/kexie/news.asp?id=144. Retrieved 2015-05-20.
↑ Kolling, Orland W.; Mawdsley, Elizabeth A. (1971). "Anhydrous Thallium(III) Acetate". Transactions of the Kansas Academy of Science 74 (1): 38. doi:10.2307/3627666. https://www.jstor.org/stable/3627666.
↑ Faggiani, R.; Brown, I. D. (1 September 1978). "Thallium(III) triacetate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 34 (9): 2845–2846. doi:10.1107/S0567740878009358. Bibcode: 1978AcCrB..34.2845F.
↑ Faggiani, R.; Brown, I. D. (15 September 1982). "Thallium triacetate monohydrate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 38 (9): 2473–2475. doi:10.1107/S0567740882009091. Bibcode: 1982AcCrB..38.2473F.

v t e Acetyl halides and salts of the acetate ion
AcOH																	He
LiOAc	Be(OAc)₂ BeAcOH											B(OAc)₃	AcOAc ROAc	NH₄OAc	AcOOH	FAc	Ne
NaOAc	Mg(OAc)₂											Al(OAc)₃ ALSOL Al(OAc)₂OH Al₂SO₄(OAc)₄	Si	P	S	ClAc	Ar
KOAc	Ca(OAc)₂	Sc(OAc)₃	Ti(OAc)₄	VO(OAc)₃	Cr(OAc)₂ Cr(OAc)₃	Mn(OAc)₂ Mn(OAc)₃	Fe(OAc)₂ Fe(OAc)₃	Co(OAc)₂, Co(OAc)₃	Ni(OAc)₂	Cu(OAc)₂	Zn(OAc)₂	Ga(OAc)₃	Ge	As(OAc)₃	Se	BrAc	Kr
RbOAc	Sr(OAc)₂	Y(OAc)₃	Zr(OAc)₄	Nb	Mo(OAc)₂	Tc	Ru(OAc)₂ Ru(OAc)₃ Ru(OAc)₄	Rh₂(OAc)₄	Pd(OAc)₂	AgOAc	Cd(OAc)₂	In	Sn(OAc)₂ Sn(OAc)₄	Sb(OAc)₃	Te	IAc	Xe
CsOAc	Ba(OAc)₂		Hf	Ta	W	Re	Os	Ir	Pt(OAc)₂	Au	Hg₂(OAc)₂, Hg(OAc)₂	TlOAc Tl(OAc)₃	Pb(OAc)₂ Pb(OAc)₄	Bi(OAc)₃	Po	At	Rn
Fr	Ra		Rf	Db	Sg	Bh	Hs	Mt	Ds	Rg	Cn	Nh	Fl	Mc	Lv	Ts	Og
		↓
		La(OAc)₃	Ce(OAc)_x	Pr	Nd	Pm	Sm(OAc)₃	Eu(OAc)₃	Gd(OAc)₃	Tb	Dy(OAc)₃	Ho(OAc)₃	Er	Tm	Yb(OAc)₃	Lu(OAc)₃
		Ac	Th	Pa	UO₂(OAc)₂	Np	Pu	Am	Cm	Bk	Cf	Es	Fm	Md	No	Lr

0.00

(0 votes)

Original source: https://en.wikipedia.org/wiki/Thallium(III) acetate. Read more

[1] Bulich, Anthony A.; Hartman, Paul A. (Nov 1969). "Evaluation of Thallium Acetate-Citrate Medium for Isolation of Enterococci". Applied Microbiology 18 (5): 944–945. doi:10.1128/am.18.5.944-945.1969. ISSN 0003-6919. PMID 5370465. PMC 378124. http://dx.doi.org/10.1128/am.18.5.944-945.1969.

[Organization2008-2] World Health Organization (2008). Anthrax in humans and animals. World Health Organization. pp. 139–. ISBN 978-92-4-154753-6. https://books.google.com/books?id=EKYihvnaA7oC&pg=PA139. Retrieved 23 February 2011.

[3] "铊、玻璃和人——从两桩铊中毒事件说起". 中国科学院上海硅酸盐研究所. http://119.78.242.243:8080/kexie/news.asp?id=144. Retrieved 2015-05-20.

[4] Kolling, Orland W.; Mawdsley, Elizabeth A. (1971). "Anhydrous Thallium(III) Acetate". Transactions of the Kansas Academy of Science 74 (1): 38. doi:10.2307/3627666. https://www.jstor.org/stable/3627666.

[5] Faggiani, R.; Brown, I. D. (1 September 1978). "Thallium(III) triacetate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 34 (9): 2845–2846. doi:10.1107/S0567740878009358. Bibcode: 1978AcCrB..34.2845F.

[6] Faggiani, R.; Brown, I. D. (15 September 1982). "Thallium triacetate monohydrate". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry 38 (9): 2473–2475. doi:10.1107/S0567740882009091. Bibcode: 1982AcCrB..38.2473F.

[1]

[2]

[3]

[4]

[5]

[6]