Titanium(Iv) Acetate

Titanium(IV) acetate
Names
	Other names Titanium tetraacetate;
Identifiers
CAS Number	13057-42-6 ;
3D model (JSmol)	Interactive image;
ChemSpider	8141204 ;
EC Number	235-944-4;
PubChem CID	59044991;
	InChI InChI=1S/4C2H4O2.Ti/c41-2(3)4;/h41H3,(H,3,4); Key: INNSZZHSFSFSGS-UHFFFAOYSA-N;
	SMILES CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Ti];
Properties
Chemical formula	Ti(C2H3O2)4
Molar mass	288.07 g/mol
Appearance	colorless
Melting point	117 °C (243 °F; 390 K)
Related compounds
Other cations	Zirconium(IV) acetate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Titanium(IV) acetate or titanium tetraacetate is a hypothetical coordination complex with the formula Ti(C₂H₃O₂)₄. It is discussed in archaic literature,^[1] well before the advent of X-ray crystallography and an appreciation of the structural trends in metal carboxylate complexes.

Preparation

Titanium(IV) acetate can be prepared by reacting tetramethyltitanium with acetic acid.^[2]

Related titanium acetates

Evidence for the composition much less the structure as a tetraacetate has not been presented.^[3] Instead a variety of titanium oxo acetates have been prepared by reactions of titanium alkoxides and acetic acid.^[4]

Uses

Species claimed to be titanium(IV) acetate have been used in the production of bismuth titanate ferroelectric thin films. Titanium(IV) acetate is used in the step of making the acetate-derived solutions. The acetate derived solutions were created by blending acetic acid and bismuth acetate together and adding titanium(IV) acetate.^[5] "Titanium(IV) acetate" is a substitute for antimony potassium tartrate(emetic tartar) when making red and brown dyes.^[6]

References

↑ Frederick Pearson Treadwell (1916) (in English). Qualitative analysis. J.Wiley & sons, Incorporated. pp. 538. https://books.google.com/books?id=svIZAAAAYAAJ. Retrieved 26 March 2021.
↑ K.-H. Thiele; M. Panse (1978). "Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. XXVII. Darstellung von Titanacetaten aus Tetramethyl- und Tetrabenzyltitan". Z. anorg. allg. Chem. 441 (1): 23-28. doi:10.1002/zaac.19784410103.
↑ Pande, K. C.; Mehrotra, R. C. (1957). "Attempted Preparation of Titanium Tetra-Acetate". Journal für praktische Chemie 5 (1–2): 101–104. doi:10.1002/prac.19570050112.
↑ Gautier-Luneau, I.; Mosset, A.; Galy, J. (1987). "Structural Characterization of a Hexanuclear Titanium Acetate Complex, Ti₆(μ₃–O)₂(μ₂–O)₂(μ₂–OC₂H₅)₂-μ-CH₃COO)₈(OC₂H₅)₆, Built Up of Two Trinuclear, oxo-Centered, Units". Zeitschrift für Kristallographie 180 (1–4): 83–95. doi:10.1524/zkri.1987.180.1-4.83. Bibcode: 1987ZK....180...83G.
↑ (in English) Scientific and Technical Aerospace Reports. NASA, Office of Scientific and Technical Information. 1995. pp. 1198. https://books.google.com/books?id=62GCbS7Mu3kC. Retrieved 26 March 2021.
↑ The Year-book for Colorists and Dyers. the New York Public Library. 1905. pp. 413. https://books.google.com/books?id=VBFSAAAAYAAJ. Retrieved 26 March 2021.

v t e Acetyl halides and salts of the acetate ion
AcOH																	He
LiOAc	Be(OAc)₂ BeAcOH											B(OAc)₃	AcOAc ROAc	NH₄OAc	AcOOH	FAc	Ne
NaOAc	Mg(OAc)₂											Al(OAc)₃ ALSOL Al(OAc)₂OH Al₂SO₄(OAc)₄	Si	P	S	ClAc	Ar
KOAc	Ca(OAc)₂	Sc(OAc)₃	Ti(OAc)₄	VO(OAc)₃	Cr(OAc)₂ Cr(OAc)₃	Mn(OAc)₂ Mn(OAc)₃	Fe(OAc)₂ Fe(OAc)₃	Co(OAc)₂, Co(OAc)₃	Ni(OAc)₂	Cu(OAc)₂	Zn(OAc)₂	Ga(OAc)₃	Ge	As(OAc)₃	Se	BrAc	Kr
RbOAc	Sr(OAc)₂	Y(OAc)₃	Zr(OAc)₄	Nb	Mo(OAc)₂	Tc	Ru(OAc)₂ Ru(OAc)₃ Ru(OAc)₄	Rh₂(OAc)₄	Pd(OAc)₂	AgOAc	Cd(OAc)₂	In	Sn(OAc)₂ Sn(OAc)₄	Sb(OAc)₃	Te	IAc	Xe
CsOAc	Ba(OAc)₂		Hf	Ta	W	Re	Os	Ir	Pt(OAc)₂	Au	Hg₂(OAc)₂, Hg(OAc)₂	TlOAc Tl(OAc)₃	Pb(OAc)₂ Pb(OAc)₄	Bi(OAc)₃	Po	At	Rn
Fr	Ra		Rf	Db	Sg	Bh	Hs	Mt	Ds	Rg	Cn	Nh	Fl	Mc	Lv	Ts	Og
		↓
		La(OAc)₃	Ce(OAc)_x	Pr	Nd	Pm	Sm(OAc)₃	Eu(OAc)₃	Gd(OAc)₃	Tb	Dy(OAc)₃	Ho(OAc)₃	Er	Tm	Yb(OAc)₃	Lu(OAc)₃
		Ac	Th	Pa	UO₂(OAc)₂	Np	Pu	Am	Cm	Bk	Cf	Es	Fm	Md	No	Lr

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Original source: https://en.wikipedia.org/wiki/Titanium(IV) acetate. Read more

[Qualitative_analysis-1] Frederick Pearson Treadwell (1916) (in English). Qualitative analysis. J.Wiley & sons, Incorporated. pp. 538. https://books.google.com/books?id=svIZAAAAYAAJ. Retrieved 26 March 2021.

[2] K.-H. Thiele; M. Panse (1978). "Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. XXVII. Darstellung von Titanacetaten aus Tetramethyl- und Tetrabenzyltitan". Z. anorg. allg. Chem. 441 (1): 23-28. doi:10.1002/zaac.19784410103.

[3] Pande, K. C.; Mehrotra, R. C. (1957). "Attempted Preparation of Titanium Tetra-Acetate". Journal für praktische Chemie 5 (1–2): 101–104. doi:10.1002/prac.19570050112.

[4] Gautier-Luneau, I.; Mosset, A.; Galy, J. (1987). "Structural Characterization of a Hexanuclear Titanium Acetate Complex, Ti₆(μ₃–O)₂(μ₂–O)₂(μ₂–OC₂H₅)₂-μ-CH₃COO)₈(OC₂H₅)₆, Built Up of Two Trinuclear, oxo-Centered, Units". Zeitschrift für Kristallographie 180 (1–4): 83–95. doi:10.1524/zkri.1987.180.1-4.83. Bibcode: 1987ZK....180...83G.

[5] (in English) Scientific and Technical Aerospace Reports. NASA, Office of Scientific and Technical Information. 1995. pp. 1198. https://books.google.com/books?id=62GCbS7Mu3kC. Retrieved 26 March 2021.

[6] The Year-book for Colorists and Dyers. the New York Public Library. 1905. pp. 413. https://books.google.com/books?id=VBFSAAAAYAAJ. Retrieved 26 March 2021.

Names
Other names Titanium tetraacetate
Identifiers
CAS Number	13057-42-6^Y
3D model (JSmol)	Interactive image
ChemSpider	8141204^Y
EC Number	235-944-4
PubChem CID	59044991
InChI InChI=1S/4C2H4O2.Ti/c41-2(3)4;/h41H3,(H,3,4); Key: INNSZZHSFSFSGS-UHFFFAOYSA-N
SMILES CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Ti]
Properties
Chemical formula	Ti(C₂H₃O₂)₄
Molar mass	288.07 g/mol
Appearance	colorless
Melting point	117 °C (243 °F; 390 K)
Related compounds
Other cations	Zirconium(IV) acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references