Antimonide Iodide

Short description: Class of chemical compounds

Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I⁻) and antimonide (Sb³⁻). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.

List

formula	system	space group	unit cell Å	volume	density	comment	ref
Ge₃₈Sb₈I₈	cubic	Pm3n	a=10.8892			clathrate; band gap 1.16 eV; thermal conductivity 7 mWcm⁻¹K⁻¹	^[1]
Cd₄Sb₂I₃	cubic	Pa3	a=13.48				^[2]
Sn₃₈Sb₈I₈	cubic	Pm3n	a=12.0447			clathrate; band gap 0.80 eV; thermal conductivity 12mWcm⁻¹K⁻¹	^[1]
La₂SbI₂	rhombohedral		a=4.530 c=32.80				^[3]
Hg₅Sb₂I₆	orthorhombic	Pc2₁n	a=8.108, b=10.702, c=21.295	1847.7	7.217	Dark red	^[4]
(Hg₆Sb₄)(CdI₆)	rhombohedral	R3c	a = 13.3818, α = 90.93°,	2395.3	7.111	black	^[5]
(Hg₆Sb₄)(CdI₆)Hg_0.6	cubic	Pa3	a=13.234	2317.7	7.604	black; band gap 1.23; air stable	^[6]
[Hg₆Sb₄I₃](SnI₃)Hg_0.16	cubic	P2₁3	a=13.285 Z=4				^[7]

References

↑ ^1.0 ^1.1 Kishimoto, Kengo; Arimura, Shuntaro; Koyanagi, Tsuyoshi (2006-05-29). "Preparation and thermoelectric properties of sintered iodine-containing clathrate compounds Ge38Sb8I8 and Sn38Sb8I8" (in en). Applied Physics Letters 88 (22): 222115. doi:10.1063/1.2209207. ISSN 0003-6951. Bibcode: 2006ApPhL..88v2115K. http://aip.scitation.org/doi/10.1063/1.2209207.
↑ Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe" (in en). Solid State Communications 255-256: 5–10. doi:10.1016/j.ssc.2017.03.001. Bibcode: 2017SSCom.255....5R. https://linkinghub.elsevier.com/retrieve/pii/S0038109817300765.
↑ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds" (in en). Zeitschrift für Naturforschung B 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-2007-1105/html.
↑ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (February 1994). "Synthesis and Crystal Structure of Hg5Sb2I6" (in de). Zeitschrift für anorganische und allgemeine Chemie 620 (2): 389–392. doi:10.1002/zaac.19946200232. ISSN 0044-2313.
↑ Zou, Jian-Ping; Li, Yan; Zhang; Guo; Liu, Xi; Wang, Ming-Sheng; Cai, Li-Zhen; Lu, Ying-Bing et al. (2007-09-01). "Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg 6 Sb 4 )(CdI 6 )" (in en). Inorganic Chemistry 46 (18): 7321–7325. doi:10.1021/ic0624165. ISSN 0020-1669. PMID 17665902. https://pubs.acs.org/doi/10.1021/ic0624165.
↑ Zou, Jian‐Ping; Li, Yan; Fu, Ming‐Lai; Guo, Guo‐Cong; Xu, Gang; Liu, Xue‐Hui; Zhou, Wei‐Wei; Huang, Jin‐Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 (MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)"] (in en). European Journal of Inorganic Chemistry 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200600894.
↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.

HI																	He
LiI	BeI₂											BI₃	CI₄	NI₃	I₂O₄, I₂O₅, I₄O₉	IF, IF₃, IF₅, IF₇	Ne
NaI	MgI₂											AlI₃	SiI₄	PI₃, P₂I₄	S	ICl, ICl₃	Ar
KI	CaI₂	Sc	TiI₄	VI₃	CrI₃	MnI₂	FeI₂	CoI₂	NiI₂	CuI	ZnI₂	Ga₂I₆	GeI₂, GeI₄	AsI₃	Se	IBr	Kr
RbI	SrI₂	YI₃	ZrI₄	NbI₅	Mo	Tc	Ru	Rh	Pd	AgI	CdI₂	InI₃	SnI₄, SnI₂	SbI₃	TeI₄	I	Xe
CsI	BaI₂		HfI₄	TaI₅	W	Re	Os	Ir	Pt	AuI	Hg₂I₂, HgI₂	TlI	PbI₂	BiI₃	Po	AtI	Rn
Fr	RaI₂		Rf	Db	Sg	Bh	Hs	Mt	Ds	Rg	Cn	Nh	Fl	Mc	Lv	Ts	Og
		↓
		La	Ce	Pr	Nd	Pm	SmI₂	Eu	Gd	TbI₃	Dy	Ho	Er	Tm	Yb	Lu
		Ac	ThI₄	Pa	UI₃, UI₄	Np	Pu	Am	Cm	Bk	Cf	EsI₃	Fm	Md	No	Lr

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Original source: https://en.wikipedia.org/wiki/Antimonide iodide. Read more

[:22-1] 1.0 ^1.1 Kishimoto, Kengo; Arimura, Shuntaro; Koyanagi, Tsuyoshi (2006-05-29). "Preparation and thermoelectric properties of sintered iodine-containing clathrate compounds Ge38Sb8I8 and Sn38Sb8I8" (in en). Applied Physics Letters 88 (22): 222115. doi:10.1063/1.2209207. ISSN 0003-6951. Bibcode: 2006ApPhL..88v2115K. http://aip.scitation.org/doi/10.1063/1.2209207.

[2] Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe" (in en). Solid State Communications 255-256: 5–10. doi:10.1016/j.ssc.2017.03.001. Bibcode: 2017SSCom.255....5R. https://linkinghub.elsevier.com/retrieve/pii/S0038109817300765.

[3] Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds" (in en). Zeitschrift für Naturforschung B 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-2007-1105/html.

[4] Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (February 1994). "Synthesis and Crystal Structure of Hg5Sb2I6" (in de). Zeitschrift für anorganische und allgemeine Chemie 620 (2): 389–392. doi:10.1002/zaac.19946200232. ISSN 0044-2313.

[5] Zou, Jian-Ping; Li, Yan; Zhang; Guo; Liu, Xi; Wang, Ming-Sheng; Cai, Li-Zhen; Lu, Ying-Bing et al. (2007-09-01). "Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg 6 Sb 4 )(CdI 6 )" (in en). Inorganic Chemistry 46 (18): 7321–7325. doi:10.1021/ic0624165. ISSN 0020-1669. PMID 17665902. https://pubs.acs.org/doi/10.1021/ic0624165.

[6] Zou, Jian‐Ping; Li, Yan; Fu, Ming‐Lai; Guo, Guo‐Cong; Xu, Gang; Liu, Xue‐Hui; Zhou, Wei‐Wei; Huang, Jin‐Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 (MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)"] (in en). European Journal of Inorganic Chemistry 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200600894.

[7] Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.

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